Research output: Contribution to journal › Article › peer-review
Sulphidation of Au-Ag alloys in the presence of pyrite (experimental data). / Palyanova, Galina; Kokh, Konstantin; Seryotkin, Yurii.
In: Corrosion Science, Vol. 121, 01.06.2017, p. 126-132.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Sulphidation of Au-Ag alloys in the presence of pyrite (experimental data)
AU - Palyanova, Galina
AU - Kokh, Konstantin
AU - Seryotkin, Yurii
N1 - Publisher Copyright: © 2017 Elsevier Ltd
PY - 2017/6/1
Y1 - 2017/6/1
N2 - Dry annealing of Au-Ag alloys (Au, Au0.56Ag0.44, Au0.35Ag0.65, Au0.19Ag0.81 and Ag), together with pyrite as a source of sulphur, at 450 °C was used to study the mechanisms of corrosion and transition of metal forms of noble metals to sulphide forms. In the experiment with Ag plates the silver completely sulphidates to form acanthite Ag2S and pyrite desulphidates to form pyrrhotite Fe1-yS. In the experiments with the Au-Ag plates there also formation of an uytenbogaardtite phase and ennobling of Au-Ag alloys take place. Gold in the absence of silver stabilizes pyrite and prevents its transition to pyrrhotite.
AB - Dry annealing of Au-Ag alloys (Au, Au0.56Ag0.44, Au0.35Ag0.65, Au0.19Ag0.81 and Ag), together with pyrite as a source of sulphur, at 450 °C was used to study the mechanisms of corrosion and transition of metal forms of noble metals to sulphide forms. In the experiment with Ag plates the silver completely sulphidates to form acanthite Ag2S and pyrite desulphidates to form pyrrhotite Fe1-yS. In the experiments with the Au-Ag plates there also formation of an uytenbogaardtite phase and ennobling of Au-Ag alloys take place. Gold in the absence of silver stabilizes pyrite and prevents its transition to pyrrhotite.
KW - A. Alloy
KW - A. Silver
KW - B. EPMA
KW - B. X-ray diffraction
KW - C. Sulphidation
KW - GOLD
KW - MINERALS
KW - X-ray diffraction
KW - SULFUR
KW - DEPOSIT
KW - GENESIS
KW - PYRRHOTITE
KW - Alloy
KW - Silver
KW - ORES
KW - SILVER SULFIDES
KW - MINERALIZATION
KW - CONSTRAINTS
KW - Sulphidation
KW - EPMA
UR - http://www.scopus.com/inward/record.url?scp=85017338822&partnerID=8YFLogxK
U2 - 10.1016/j.corsci.2017.03.020
DO - 10.1016/j.corsci.2017.03.020
M3 - Article
AN - SCOPUS:85017338822
VL - 121
SP - 126
EP - 132
JO - Corrosion Science
JF - Corrosion Science
SN - 0010-938X
ER -
ID: 9021672