Research output: Contribution to journal › Article › peer-review
Sulfur-selenium isomorphous substitution and polymorphism in the Ag2(S,Se) series. / Seryotkin, Yurii V.; Palyanova, Galina A.; Kokh, Konstantin A.
In: Journal of Alloys and Compounds, Vol. 639, 05.08.2015, p. 89-93.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Sulfur-selenium isomorphous substitution and polymorphism in the Ag2(S,Se) series
AU - Seryotkin, Yurii V.
AU - Palyanova, Galina A.
AU - Kokh, Konstantin A.
PY - 2015/8/5
Y1 - 2015/8/5
N2 - Ag2S-Ag2Se chalcogenides have been synthesized by heating stoichiometric mixtures of elementary substances in vacuum sealed quartz vessels. Optical microscopy, scanning electron microscopy, X-ray powder diffraction with high-temperature experiments and X-ray single-crystal method were applied to study synthesized silver sulfoselenides. The synthesized silver sulfoselenides are homogeneous under optical and scanning electron microscope. At room temperature, two Ag2S1-xSex polymorphs - monoclinic and orthorhombic - coexist in the interval of 0.6 < x < 0.8. Compositional gap between two solid solutions is absent. At higher temperature, an intermediate monoclinic phase was observed in the range of Ag2S0.25Se0.75-Ag2S0.175Se0.825.
AB - Ag2S-Ag2Se chalcogenides have been synthesized by heating stoichiometric mixtures of elementary substances in vacuum sealed quartz vessels. Optical microscopy, scanning electron microscopy, X-ray powder diffraction with high-temperature experiments and X-ray single-crystal method were applied to study synthesized silver sulfoselenides. The synthesized silver sulfoselenides are homogeneous under optical and scanning electron microscope. At room temperature, two Ag2S1-xSex polymorphs - monoclinic and orthorhombic - coexist in the interval of 0.6 < x < 0.8. Compositional gap between two solid solutions is absent. At higher temperature, an intermediate monoclinic phase was observed in the range of Ag2S0.25Se0.75-Ag2S0.175Se0.825.
KW - Isomorphism
KW - Phase transformations
KW - Polymorphism
KW - Solid-solutions Ag(SSe)
KW - Structure features
UR - http://www.scopus.com/inward/record.url?scp=84925854755&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2015.03.112
DO - 10.1016/j.jallcom.2015.03.112
M3 - Article
AN - SCOPUS:84925854755
VL - 639
SP - 89
EP - 93
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
SN - 0925-8388
ER -
ID: 25754204