Studying the Effect of Promotion with Copper on the Activity of the Ni/Al2O3 Catalyst in the Process of Ester Hydrotreatment

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Studying the Effect of Promotion with Copper on the Activity of the Ni/Al₂O₃ Catalyst in the Process of Ester Hydrotreatment. / Kukushkin, R. G.; Eletskii, P. M.; Bulavchenko, O. A. et al.

In: Catalysis in Industry, Vol. 11, No. 3, 01.07.2019, p. 198-207.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{8080dea9a22342bfaf96691851def728,

title = "Studying the Effect of Promotion with Copper on the Activity of the Ni/Al2O3 Catalyst in the Process of Ester Hydrotreatment",

abstract = "A study is made of the effect of the composition of the active component of copper-doped nickel catalysts on their activity and selectivity in the hydrodeoxygenation (HDO) of model compounds of vegetable oils (esters) to remove oxygen atoms from them with the formation of alkanes. It is shown that the Ni/Al2O3 and Ni–Cu/Al2O3 catalysts are active in this process. With them, the hydrodeoxygenation of methyl ester of hexadecanoic acid mixed with ethyl ester of decanoic acid results in the formation of С6−С16 alkanes and oxygen-containing products, while methane and ethane can be found in the gas phase. When the Ni : Cu ratio in the catalysts is lowered, the conversion of esters and the capability of these catalysts for C–C bond hydrogenolysis are reduced. This means the introduction of copper can promote retention of the carbon skeleton of alkanes obtained as a result of hydrodeoxygenation, along with the amount of methane. According to X-ray diffraction data, introducing copper into the Ni/Al2O3 catalyst results in the formation of Ni1 – xCux solid solutions. According to X-ray photoelectron spectroscopy data, lowering the content of copper in the Ni–Cu/Al2O3 catalyst raises the Ni : Cu ratio on a sample{\textquoteright}s surface.",

keywords = "biofuel, hydrocarbon fuel, hydrodeoxygenation, vegetable oils, COMBUSTION, SULFIDED NIMO/GAMMA-AL2O3, ALIPHATIC ESTERS, OIL, X-RAY PHOTOELECTRON, HYDRODEOXYGENATION, NICKEL, REDUCTION, FUEL, OXIDES",

author = "Kukushkin, {R. G.} and Eletskii, {P. M.} and Bulavchenko, {O. A.} and Saraev, {A. A.} and Yakovlev, {V. A.}",

year = "2019",

month = jul,

day = "1",

doi = "10.1134/S2070050419030061",

language = "English",

volume = "11",

pages = "198--207",

journal = "Catalysis in Industry",

issn = "2070-0504",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "3",

}

RIS

TY - JOUR

T1 - Studying the Effect of Promotion with Copper on the Activity of the Ni/Al2O3 Catalyst in the Process of Ester Hydrotreatment

AU - Kukushkin, R. G.

AU - Eletskii, P. M.

AU - Bulavchenko, O. A.

AU - Saraev, A. A.

AU - Yakovlev, V. A.

PY - 2019/7/1

Y1 - 2019/7/1

N2 - A study is made of the effect of the composition of the active component of copper-doped nickel catalysts on their activity and selectivity in the hydrodeoxygenation (HDO) of model compounds of vegetable oils (esters) to remove oxygen atoms from them with the formation of alkanes. It is shown that the Ni/Al2O3 and Ni–Cu/Al2O3 catalysts are active in this process. With them, the hydrodeoxygenation of methyl ester of hexadecanoic acid mixed with ethyl ester of decanoic acid results in the formation of С6−С16 alkanes and oxygen-containing products, while methane and ethane can be found in the gas phase. When the Ni : Cu ratio in the catalysts is lowered, the conversion of esters and the capability of these catalysts for C–C bond hydrogenolysis are reduced. This means the introduction of copper can promote retention of the carbon skeleton of alkanes obtained as a result of hydrodeoxygenation, along with the amount of methane. According to X-ray diffraction data, introducing copper into the Ni/Al2O3 catalyst results in the formation of Ni1 – xCux solid solutions. According to X-ray photoelectron spectroscopy data, lowering the content of copper in the Ni–Cu/Al2O3 catalyst raises the Ni : Cu ratio on a sample’s surface.

AB - A study is made of the effect of the composition of the active component of copper-doped nickel catalysts on their activity and selectivity in the hydrodeoxygenation (HDO) of model compounds of vegetable oils (esters) to remove oxygen atoms from them with the formation of alkanes. It is shown that the Ni/Al2O3 and Ni–Cu/Al2O3 catalysts are active in this process. With them, the hydrodeoxygenation of methyl ester of hexadecanoic acid mixed with ethyl ester of decanoic acid results in the formation of С6−С16 alkanes and oxygen-containing products, while methane and ethane can be found in the gas phase. When the Ni : Cu ratio in the catalysts is lowered, the conversion of esters and the capability of these catalysts for C–C bond hydrogenolysis are reduced. This means the introduction of copper can promote retention of the carbon skeleton of alkanes obtained as a result of hydrodeoxygenation, along with the amount of methane. According to X-ray diffraction data, introducing copper into the Ni/Al2O3 catalyst results in the formation of Ni1 – xCux solid solutions. According to X-ray photoelectron spectroscopy data, lowering the content of copper in the Ni–Cu/Al2O3 catalyst raises the Ni : Cu ratio on a sample’s surface.

KW - biofuel

KW - hydrocarbon fuel

KW - hydrodeoxygenation

KW - vegetable oils

KW - COMBUSTION

KW - SULFIDED NIMO/GAMMA-AL2O3

KW - ALIPHATIC ESTERS

KW - OIL

KW - X-RAY PHOTOELECTRON

KW - HYDRODEOXYGENATION

KW - NICKEL

KW - REDUCTION

KW - FUEL

KW - OXIDES

UR - http://www.scopus.com/inward/record.url?scp=85073071123&partnerID=8YFLogxK

U2 - 10.1134/S2070050419030061

DO - 10.1134/S2070050419030061

M3 - Article

AN - SCOPUS:85073071123

VL - 11

SP - 198

EP - 207

JO - Catalysis in Industry

JF - Catalysis in Industry

SN - 2070-0504

IS - 3

ER -

ID: 21856665