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Study of the sensor response of spun metal phthalocyanine films to volatile organic vapors using surface plasmon resonance. / Evyapan, Murat; Kadem, Burak; Basova, Tamara V. et al.

In: Sensors and Actuators, B: Chemical, Vol. 236, 29.11.2016, p. 605-613.

Research output: Contribution to journal › Article › peer-review

Harvard

Evyapan, M, Kadem, B, Basova, TV, Yushina, IV & Hassan, AK 2016, 'Study of the sensor response of spun metal phthalocyanine films to volatile organic vapors using surface plasmon resonance', Sensors and Actuators, B: Chemical, vol. 236, pp. 605-613. https://doi.org/10.1016/j.snb.2016.05.070

APA

Evyapan, M., Kadem, B., Basova, T. V., Yushina, I. V., & Hassan, A. K. (2016). Study of the sensor response of spun metal phthalocyanine films to volatile organic vapors using surface plasmon resonance. Sensors and Actuators, B: Chemical, 236, 605-613. https://doi.org/10.1016/j.snb.2016.05.070

Vancouver

Evyapan M, Kadem B, Basova TV, Yushina IV, Hassan AK. Study of the sensor response of spun metal phthalocyanine films to volatile organic vapors using surface plasmon resonance. Sensors and Actuators, B: Chemical. 2016 Nov 29;236:605-613. doi: 10.1016/j.snb.2016.05.070

Author

Evyapan, Murat ; Kadem, Burak ; Basova, Tamara V. et al. / Study of the sensor response of spun metal phthalocyanine films to volatile organic vapors using surface plasmon resonance. In: Sensors and Actuators, B: Chemical. 2016 ; Vol. 236. pp. 605-613.

BibTeX

@article{d9956991138f4d63b0515e705b029212,
title = "Study of the sensor response of spun metal phthalocyanine films to volatile organic vapors using surface plasmon resonance",
abstract = "In this work, thin films of chloroaluminium phthalocyanine (ClAlPc), fluoroaluminium phthalocyanine (FAlPc) and fluorochromium phthalocyanine (FCrPc), which are insoluble in conventional solvents, were deposited by spin coating of their solutions in trifluoroacetic acid. The sensing response of these films versus acetic acid, three alcohols (methanol, ethanol, butanol) and three amines (methylamine, dimethylamine, trimethylamine) have been investigated using surface plasmon resonance as the sensing method. It has been shown that the sensor response of the investigated films decreases in the following order: acetic acid > alcohols > amines. The optical changes as monitored by SPR method have been used in conjunction with Fick's second law of diffusion to determine the diffusion coefficients of analyte vapor during the films{\textquoteright} swelling process. The obtained results showed that the diffusion coefficients and the swelling characteristics of the films are dependent on the functional group of the phthalocyanine molecule and the molecular size of the analyte.",
keywords = "Metal phthalocyanines, SPR technique, Swelling, Vapor diffusion",
author = "Murat Evyapan and Burak Kadem and Basova, {Tamara V.} and Yushina, {Irina V.} and Hassan, {Aseel K.}",
year = "2016",
month = nov,
day = "29",
doi = "10.1016/j.snb.2016.05.070",
language = "English",
volume = "236",
pages = "605--613",
journal = "Sensors and Actuators, B: Chemical",
issn = "0925-4005",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Study of the sensor response of spun metal phthalocyanine films to volatile organic vapors using surface plasmon resonance

AU - Evyapan, Murat

AU - Kadem, Burak

AU - Basova, Tamara V.

AU - Yushina, Irina V.

AU - Hassan, Aseel K.

PY - 2016/11/29

Y1 - 2016/11/29

N2 - In this work, thin films of chloroaluminium phthalocyanine (ClAlPc), fluoroaluminium phthalocyanine (FAlPc) and fluorochromium phthalocyanine (FCrPc), which are insoluble in conventional solvents, were deposited by spin coating of their solutions in trifluoroacetic acid. The sensing response of these films versus acetic acid, three alcohols (methanol, ethanol, butanol) and three amines (methylamine, dimethylamine, trimethylamine) have been investigated using surface plasmon resonance as the sensing method. It has been shown that the sensor response of the investigated films decreases in the following order: acetic acid > alcohols > amines. The optical changes as monitored by SPR method have been used in conjunction with Fick's second law of diffusion to determine the diffusion coefficients of analyte vapor during the films’ swelling process. The obtained results showed that the diffusion coefficients and the swelling characteristics of the films are dependent on the functional group of the phthalocyanine molecule and the molecular size of the analyte.

AB - In this work, thin films of chloroaluminium phthalocyanine (ClAlPc), fluoroaluminium phthalocyanine (FAlPc) and fluorochromium phthalocyanine (FCrPc), which are insoluble in conventional solvents, were deposited by spin coating of their solutions in trifluoroacetic acid. The sensing response of these films versus acetic acid, three alcohols (methanol, ethanol, butanol) and three amines (methylamine, dimethylamine, trimethylamine) have been investigated using surface plasmon resonance as the sensing method. It has been shown that the sensor response of the investigated films decreases in the following order: acetic acid > alcohols > amines. The optical changes as monitored by SPR method have been used in conjunction with Fick's second law of diffusion to determine the diffusion coefficients of analyte vapor during the films’ swelling process. The obtained results showed that the diffusion coefficients and the swelling characteristics of the films are dependent on the functional group of the phthalocyanine molecule and the molecular size of the analyte.

KW - Metal phthalocyanines

KW - SPR technique

KW - Swelling

KW - Vapor diffusion

UR - http://www.scopus.com/inward/record.url?scp=84976438387&partnerID=8YFLogxK

U2 - 10.1016/j.snb.2016.05.070

DO - 10.1016/j.snb.2016.05.070

M3 - Article

AN - SCOPUS:84976438387

VL - 236

SP - 605

EP - 613

JO - Sensors and Actuators, B: Chemical

JF - Sensors and Actuators, B: Chemical

SN - 0925-4005

ER -

ID: 25437370