Study of the Reactions of Fullerene С60 with the Palladium-Containing Clusters of Molybdenum {Mo3PdS4} by Spectroscopic and Calculation Methods

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Study of the Reactions of Fullerene С₆₀ with the Palladium-Containing Clusters of Molybdenum {Mo₃PdS₄} by Spectroscopic and Calculation Methods. / Laricheva, Yu A.; Shmelev, N. Yu; Gushchin, A. L. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 47, No. 3, 03.2021, p. 196-203.

Research output: Contribution to journal › Article › peer-review

Author

Laricheva, Yu A. ; Shmelev, N. Yu ; Gushchin, A. L. et al. / Study of the Reactions of Fullerene С₆₀ with the Palladium-Containing Clusters of Molybdenum {Mo₃PdS₄} by Spectroscopic and Calculation Methods. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021 ; Vol. 47, No. 3. pp. 196-203.

BibTeX

@article{13271b3aa39944ccaed26b6e97f28381,

title = "Study of the Reactions of Fullerene С60 with the Palladium-Containing Clusters of Molybdenum {Mo3PdS4} by Spectroscopic and Calculation Methods",

abstract = "The fabrication of hybrid materials combining the physicochemical properties of various classes is a complicated but promising trend for the development of the modern science. The formation of new hybrid cluster cations [Mo3Pd(C60)S4Cl3(R2Bipy)3]+ and [{Mo3PdS4Cl3(R2Bipy)3}2(C60)]2+ (Bipy is 2,2-bipyridine) containing fullerene C60 coordinated to the palladium atom by the reaction of [Mo3S4Cl3(R2Bipy)3]PF6 with Pd2(Dba)3 (Dba is dibenzylideneacetone) and C60 is shown by a complex of physicochemical methods. The reaction products are studied by IR and NMR (1H, 31Р, and C–H correlations) spectroscopy and mass spectrometry. The quantum-chemical calculations are performed by the DFT method for the correct interpretation of the spectroscopic data and elucidation of the electronic structures of the fullerene-containing compounds.",

keywords = "cluster complexes, DFT calculations, fullerene, molybdenum, palladium",

author = "Laricheva, {Yu A.} and Shmelev, {N. Yu} and Gushchin, {A. L.} and Sokolov, {M. N.}",

note = "Funding Information: This work was supported by the Russian Foundation for Basic Research, projects nos. 18-33-20056 and 19-33-90097. Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",

year = "2021",

month = mar,

doi = "10.1134/S1070328421020032",

language = "English",

volume = "47",

pages = "196--203",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "3",

}

RIS

TY - JOUR

T1 - Study of the Reactions of Fullerene С60 with the Palladium-Containing Clusters of Molybdenum {Mo3PdS4} by Spectroscopic and Calculation Methods

AU - Laricheva, Yu A.

AU - Shmelev, N. Yu

AU - Gushchin, A. L.

AU - Sokolov, M. N.

N1 - Funding Information: This work was supported by the Russian Foundation for Basic Research, projects nos. 18-33-20056 and 19-33-90097. Publisher Copyright: © 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/3

Y1 - 2021/3

N2 - The fabrication of hybrid materials combining the physicochemical properties of various classes is a complicated but promising trend for the development of the modern science. The formation of new hybrid cluster cations [Mo3Pd(C60)S4Cl3(R2Bipy)3]+ and [{Mo3PdS4Cl3(R2Bipy)3}2(C60)]2+ (Bipy is 2,2-bipyridine) containing fullerene C60 coordinated to the palladium atom by the reaction of [Mo3S4Cl3(R2Bipy)3]PF6 with Pd2(Dba)3 (Dba is dibenzylideneacetone) and C60 is shown by a complex of physicochemical methods. The reaction products are studied by IR and NMR (1H, 31Р, and C–H correlations) spectroscopy and mass spectrometry. The quantum-chemical calculations are performed by the DFT method for the correct interpretation of the spectroscopic data and elucidation of the electronic structures of the fullerene-containing compounds.

AB - The fabrication of hybrid materials combining the physicochemical properties of various classes is a complicated but promising trend for the development of the modern science. The formation of new hybrid cluster cations [Mo3Pd(C60)S4Cl3(R2Bipy)3]+ and [{Mo3PdS4Cl3(R2Bipy)3}2(C60)]2+ (Bipy is 2,2-bipyridine) containing fullerene C60 coordinated to the palladium atom by the reaction of [Mo3S4Cl3(R2Bipy)3]PF6 with Pd2(Dba)3 (Dba is dibenzylideneacetone) and C60 is shown by a complex of physicochemical methods. The reaction products are studied by IR and NMR (1H, 31Р, and C–H correlations) spectroscopy and mass spectrometry. The quantum-chemical calculations are performed by the DFT method for the correct interpretation of the spectroscopic data and elucidation of the electronic structures of the fullerene-containing compounds.

KW - cluster complexes

KW - DFT calculations

KW - fullerene

KW - molybdenum

KW - palladium

UR - http://www.scopus.com/inward/record.url?scp=85102953196&partnerID=8YFLogxK

U2 - 10.1134/S1070328421020032

DO - 10.1134/S1070328421020032

M3 - Article

AN - SCOPUS:85102953196

VL - 47

SP - 196

EP - 203

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 3

ER -

ID: 28201856