Research output: Contribution to journal › Article › peer-review
Study of the Impact of Y2O3Support Synthesis on Carbon Dioxide Methanation Catalyst Applications. / Derevschikov, Vladimir S.; Kukushkin, Roman G.; Yatsenko, Dmitry A. et al.
In: Industrial and Engineering Chemistry Research, Vol. 61, No. 43, 02.11.2022, p. 15810–15819.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Study of the Impact of Y2O3Support Synthesis on Carbon Dioxide Methanation Catalyst Applications
AU - Derevschikov, Vladimir S.
AU - Kukushkin, Roman G.
AU - Yatsenko, Dmitry A.
AU - Potemkin, Dmitriy I.
AU - Ruvinskiy, Pavel S.
AU - Shinkevich, Ksenia S.
AU - Glazneva, Tatiana S.
AU - Yakovlev, Vadim A.
N1 - Funding Information: This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for the Boreskov Institute of Catalysis (project(s) AAAA-A21-121011390054-1 (0239-2021-0010) and AAAA-A21-121011390007-7 (0239-2021-0005)). The authors thank A.A. Leonova, Ayupov A.B., and Dr. A.V. Ishenko for performing N adsorption and HR-TEM measurements. The authors acknowledge the Shared Research Center “VTAN” of the Novosibirsk State University supported by the Ministry of Science and Higher Education of the Russian Federation of Russia under agreement #075-12-2021-697. 2 Publisher Copyright: ©
PY - 2022/11/2
Y1 - 2022/11/2
N2 - The present work reports on the fine-tuning of the composition of yttrium oxide as a support for carbon dioxide methanation (CME) catalyst applications. Using a suite of analytical techniques (X-ray diffraction, Brunauer-Emmett-Teller surface area analysis, mercury porosimetry, Fourier transform infrared spectroscopy, scanning electron microscopy and transmission electron microscopy), we examine the impact of the synthetic parameters, for example, calcination temperature, on the resulting properties of Y2O3 supports. Novel yttria-based carriers were used to produce a series of Ni/Y2O3 catalytic systems that were evaluated under fixed-bed CME conditions. We observe a superior specific activity of Ni/Y2O3 catalysts in comparison with a commercial Ni-based benchmark and assign this performance of the former to the stabilizing effect of the Y2O3-support on the active component.
AB - The present work reports on the fine-tuning of the composition of yttrium oxide as a support for carbon dioxide methanation (CME) catalyst applications. Using a suite of analytical techniques (X-ray diffraction, Brunauer-Emmett-Teller surface area analysis, mercury porosimetry, Fourier transform infrared spectroscopy, scanning electron microscopy and transmission electron microscopy), we examine the impact of the synthetic parameters, for example, calcination temperature, on the resulting properties of Y2O3 supports. Novel yttria-based carriers were used to produce a series of Ni/Y2O3 catalytic systems that were evaluated under fixed-bed CME conditions. We observe a superior specific activity of Ni/Y2O3 catalysts in comparison with a commercial Ni-based benchmark and assign this performance of the former to the stabilizing effect of the Y2O3-support on the active component.
UR - http://www.scopus.com/inward/record.url?scp=85140997059&partnerID=8YFLogxK
U2 - 10.1021/acs.iecr.2c01813
DO - 10.1021/acs.iecr.2c01813
M3 - Article
AN - SCOPUS:85140997059
VL - 61
SP - 15810
EP - 15819
JO - Industrial & Engineering Chemistry Research
JF - Industrial & Engineering Chemistry Research
SN - 0888-5885
IS - 43
ER -
ID: 38749356