Research output: Contribution to journal › Article › peer-review
Study of the complexes of iron(II) dicyanamide and isothiocyanate with 2-(2-tert-butyltetrazol-5-yl)pyridine. / Shakirova, O. G.; Lavrenova, L. G.; Kuratieva, N. V. et al.
In: Journal of Structural Chemistry, Vol. 58, No. 5, 01.09.2017, p. 919-925.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Study of the complexes of iron(II) dicyanamide and isothiocyanate with 2-(2-tert-butyltetrazol-5-yl)pyridine
AU - Shakirova, O. G.
AU - Lavrenova, L. G.
AU - Kuratieva, N. V.
AU - Bogomyakov, A. S.
AU - Sheludyakova, L. A.
AU - Mosalkova, A. P.
AU - Grigoriev, Yu V.
PY - 2017/9/1
Y1 - 2017/9/1
N2 - Iron(II) dicyanamide and isothiocyanate compounds with 2-(2-tert-butyltetrazol-5-yl)pyridine (L) of the composition [FeL2(C2N3)2]•2H2O (I) and [FeL2(NCS)2]H2O (II) are synthesized and studied. The compounds are examined using powder and single crystal XRD (for I), electron (diffuse reflectance spectra) and IR spectroscopy, static magnetic susceptibility. The analysis of the dependence μeff(Т) indicates that the exchange interactions of antiferromagnetic nature appear between the iron(II) ions at temperatures below 50 K.
AB - Iron(II) dicyanamide and isothiocyanate compounds with 2-(2-tert-butyltetrazol-5-yl)pyridine (L) of the composition [FeL2(C2N3)2]•2H2O (I) and [FeL2(NCS)2]H2O (II) are synthesized and studied. The compounds are examined using powder and single crystal XRD (for I), electron (diffuse reflectance spectra) and IR spectroscopy, static magnetic susceptibility. The analysis of the dependence μeff(Т) indicates that the exchange interactions of antiferromagnetic nature appear between the iron(II) ions at temperatures below 50 K.
KW - 2-(2-tert-butyltetrazol-5-yl)pyridine
KW - coordination compounds
KW - iron(II)
KW - magnetic properties
KW - structure
KW - synthesis
KW - TRANSITION
KW - SPIN-CROSSOVER
KW - LIGAND
UR - http://www.scopus.com/inward/record.url?scp=85032036987&partnerID=8YFLogxK
U2 - 10.1134/S0022476617050092
DO - 10.1134/S0022476617050092
M3 - Article
AN - SCOPUS:85032036987
VL - 58
SP - 919
EP - 925
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 5
ER -
ID: 9873498