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Study of bimetallic Ni-Mo carbides in catalytic hydrogenation of furfural to value-added chemicals. / Smirnov, Andrey A.; Shilov, Ivan N.; Bulavchenko, Olga A. et al.

Recent Advances on Environment, Chemical Engineering and Materials. ed. / B Lepadatescu. Vol. 2022 American Institute of Physics Inc., 2018. 020022 (AIP Conference Proceedings; Vol. 2022).

Research output: Chapter in Book/Report/Conference proceedingConference contributionResearchpeer-review

Harvard

Smirnov, AA, Shilov, IN, Bulavchenko, OA & Yakovlev, VA 2018, Study of bimetallic Ni-Mo carbides in catalytic hydrogenation of furfural to value-added chemicals. in B Lepadatescu (ed.), Recent Advances on Environment, Chemical Engineering and Materials. vol. 2022, 020022, AIP Conference Proceedings, vol. 2022, American Institute of Physics Inc., 2018 International Conference on Environment, Chemical Engineering and Materials, Sliema, Malta, 22.06.2018. https://doi.org/10.1063/1.5060702

APA

Smirnov, A. A., Shilov, I. N., Bulavchenko, O. A., & Yakovlev, V. A. (2018). Study of bimetallic Ni-Mo carbides in catalytic hydrogenation of furfural to value-added chemicals. In B. Lepadatescu (Ed.), Recent Advances on Environment, Chemical Engineering and Materials (Vol. 2022). [020022] (AIP Conference Proceedings; Vol. 2022). American Institute of Physics Inc.. https://doi.org/10.1063/1.5060702

Vancouver

Smirnov AA, Shilov IN, Bulavchenko OA, Yakovlev VA. Study of bimetallic Ni-Mo carbides in catalytic hydrogenation of furfural to value-added chemicals. In Lepadatescu B, editor, Recent Advances on Environment, Chemical Engineering and Materials. Vol. 2022. American Institute of Physics Inc. 2018. 020022. (AIP Conference Proceedings). doi: 10.1063/1.5060702

Author

Smirnov, Andrey A. ; Shilov, Ivan N. ; Bulavchenko, Olga A. et al. / Study of bimetallic Ni-Mo carbides in catalytic hydrogenation of furfural to value-added chemicals. Recent Advances on Environment, Chemical Engineering and Materials. editor / B Lepadatescu. Vol. 2022 American Institute of Physics Inc., 2018. (AIP Conference Proceedings).

BibTeX

@inproceedings{186eac528b924449b5b8630d3298673a,
title = "Study of bimetallic Ni-Mo carbides in catalytic hydrogenation of furfural to value-added chemicals",
abstract = "The paper aims to study the effect of the composition of high-percentage carbide Ni-Mo systems modified by SiO2 on their activity and selectivity in the hydrogenation of furfural. The process was carried out in a solution of isopropanol at a temperature of 150 °C and a hydrogen pressure of 6.0 MPa in autoclave reactor. The main hydrogenation products were furfuryl alcohol (FA) and 2-methylfuran (2-MF). The formation of side compounds, such as tetrahydrofurfuryl alcohol and 2-methyltetrahydrofuran, was also observed. According to X-ray analysis, the catalytic systems synthesized using the Pechini method using citric acid and ethylene glycol as the carbon source contain the carbide phases (hex)-Mo2C, (cub)-MoC and Ni2Mo3C. It is shown that carbide content decreases with the amount of nickel in the catalyst, in addition, formation of a Ni-Mo alloy enriched in nickel is observed. It was indicated that a high Ni content increases the yield of by-products. At the same time, catalysts with a high content of carbide phases have a lower activity, but they allow obtaining a 60 mol.% FA yield and up to 29 mol.% of 2-MF.",
keywords = "PLATFORM MOLECULES, FUEL ADDITIVES, HYDRODEOXYGENATION",
author = "Smirnov, {Andrey A.} and Shilov, {Ivan N.} and Bulavchenko, {Olga A.} and Yakovlev, {Vadim A.}",
note = "Publisher Copyright: {\textcopyright} 2018 Author(s).; 2018 International Conference on Environment, Chemical Engineering and Materials ; Conference date: 22-06-2018 Through 24-06-2018",
year = "2018",
month = nov,
day = "6",
doi = "10.1063/1.5060702",
language = "English",
volume = "2022",
series = "AIP Conference Proceedings",
publisher = "American Institute of Physics Inc.",
editor = "B Lepadatescu",
booktitle = "Recent Advances on Environment, Chemical Engineering and Materials",

}

RIS

TY - GEN

T1 - Study of bimetallic Ni-Mo carbides in catalytic hydrogenation of furfural to value-added chemicals

AU - Smirnov, Andrey A.

AU - Shilov, Ivan N.

AU - Bulavchenko, Olga A.

AU - Yakovlev, Vadim A.

N1 - Publisher Copyright: © 2018 Author(s).

PY - 2018/11/6

Y1 - 2018/11/6

N2 - The paper aims to study the effect of the composition of high-percentage carbide Ni-Mo systems modified by SiO2 on their activity and selectivity in the hydrogenation of furfural. The process was carried out in a solution of isopropanol at a temperature of 150 °C and a hydrogen pressure of 6.0 MPa in autoclave reactor. The main hydrogenation products were furfuryl alcohol (FA) and 2-methylfuran (2-MF). The formation of side compounds, such as tetrahydrofurfuryl alcohol and 2-methyltetrahydrofuran, was also observed. According to X-ray analysis, the catalytic systems synthesized using the Pechini method using citric acid and ethylene glycol as the carbon source contain the carbide phases (hex)-Mo2C, (cub)-MoC and Ni2Mo3C. It is shown that carbide content decreases with the amount of nickel in the catalyst, in addition, formation of a Ni-Mo alloy enriched in nickel is observed. It was indicated that a high Ni content increases the yield of by-products. At the same time, catalysts with a high content of carbide phases have a lower activity, but they allow obtaining a 60 mol.% FA yield and up to 29 mol.% of 2-MF.

AB - The paper aims to study the effect of the composition of high-percentage carbide Ni-Mo systems modified by SiO2 on their activity and selectivity in the hydrogenation of furfural. The process was carried out in a solution of isopropanol at a temperature of 150 °C and a hydrogen pressure of 6.0 MPa in autoclave reactor. The main hydrogenation products were furfuryl alcohol (FA) and 2-methylfuran (2-MF). The formation of side compounds, such as tetrahydrofurfuryl alcohol and 2-methyltetrahydrofuran, was also observed. According to X-ray analysis, the catalytic systems synthesized using the Pechini method using citric acid and ethylene glycol as the carbon source contain the carbide phases (hex)-Mo2C, (cub)-MoC and Ni2Mo3C. It is shown that carbide content decreases with the amount of nickel in the catalyst, in addition, formation of a Ni-Mo alloy enriched in nickel is observed. It was indicated that a high Ni content increases the yield of by-products. At the same time, catalysts with a high content of carbide phases have a lower activity, but they allow obtaining a 60 mol.% FA yield and up to 29 mol.% of 2-MF.

KW - PLATFORM MOLECULES

KW - FUEL ADDITIVES

KW - HYDRODEOXYGENATION

UR - http://www.scopus.com/inward/record.url?scp=85057344539&partnerID=8YFLogxK

U2 - 10.1063/1.5060702

DO - 10.1063/1.5060702

M3 - Conference contribution

AN - SCOPUS:85057344539

VL - 2022

T3 - AIP Conference Proceedings

BT - Recent Advances on Environment, Chemical Engineering and Materials

A2 - Lepadatescu, B

PB - American Institute of Physics Inc.

T2 - 2018 International Conference on Environment, Chemical Engineering and Materials

Y2 - 22 June 2018 through 24 June 2018

ER -

ID: 17565175