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Structures of molecular complexes of SbCl5 with pyridine and acetonitrile : equal bond lengths, different stability. / Davydova, E. I.; Virovets, A. V.; Peresypkina, E. V. et al.

In: Russian Chemical Bulletin, Vol. 69, No. 1, 01.01.2020, p. 84-90.

Research output: Contribution to journal › Article › peer-review

Harvard

Davydova, EI, Virovets, AV, Peresypkina, EV, Kazakov, IV & Timoshkin, AY 2020, 'Structures of molecular complexes of SbCl5 with pyridine and acetonitrile: equal bond lengths, different stability', Russian Chemical Bulletin, vol. 69, no. 1, pp. 84-90. https://doi.org/10.1007/s11172-020-2726-6

APA

Davydova, E. I., Virovets, A. V., Peresypkina, E. V., Kazakov, I. V., & Timoshkin, A. Y. (2020). Structures of molecular complexes of SbCl5 with pyridine and acetonitrile: equal bond lengths, different stability. Russian Chemical Bulletin, 69(1), 84-90. https://doi.org/10.1007/s11172-020-2726-6

Vancouver

Davydova EI, Virovets AV, Peresypkina EV, Kazakov IV, Timoshkin AY. Structures of molecular complexes of SbCl5 with pyridine and acetonitrile: equal bond lengths, different stability. Russian Chemical Bulletin. 2020 Jan 1;69(1):84-90. doi: 10.1007/s11172-020-2726-6

Author

Davydova, E. I. ; Virovets, A. V. ; Peresypkina, E. V. et al. / Structures of molecular complexes of SbCl5 with pyridine and acetonitrile : equal bond lengths, different stability. In: Russian Chemical Bulletin. 2020 ; Vol. 69, No. 1. pp. 84-90.

BibTeX

@article{1cd82445a7f647a59841a4ce0f307ebf,
title = "Structures of molecular complexes of SbCl5 with pyridine and acetonitrile: equal bond lengths, different stability",
abstract = "Molecular structure of crystalline complex SbCl5 • Py was determined for the first time and the structure of the complex SbCl5 • AN was refined by means of single crystal X-ray diffraction analysis. It is shown that donor-acceptor Sb–N bond lengths for these complexes are equal within the experimental error. Quantum chemical calculations of the complexes in the gas phase reveal that the energies of the donor-acceptor bond Sb–N are 88 and 180 kJ mol−1 for SbCl5 • AN and SbCl5 • Py, respectively. It is established that the length of the donor-acceptor bond Sb–N in the crystal cannot serve as a measure of its strength.",
keywords = "acetonitrile, antimony pentachloride, molecular complexes, pyridine, structure, ENERGY, CRYSTAL-STRUCTURES, ADDUCTS, DONOR-ACCEPTOR BOND, SOLID-STATE",
author = "Davydova, {E. I.} and Virovets, {A. V.} and Peresypkina, {E. V.} and Kazakov, {I. V.} and Timoshkin, {A. Yu}",
year = "2020",
month = jan,
day = "1",
doi = "10.1007/s11172-020-2726-6",
language = "English",
volume = "69",
pages = "84--90",
journal = "Russian Chemical Bulletin",
issn = "1066-5285",
publisher = "Springer Nature",
number = "1",

}

RIS

TY - JOUR

T1 - Structures of molecular complexes of SbCl5 with pyridine and acetonitrile

T2 - equal bond lengths, different stability

AU - Davydova, E. I.

AU - Virovets, A. V.

AU - Peresypkina, E. V.

AU - Kazakov, I. V.

AU - Timoshkin, A. Yu

PY - 2020/1/1

Y1 - 2020/1/1

N2 - Molecular structure of crystalline complex SbCl5 • Py was determined for the first time and the structure of the complex SbCl5 • AN was refined by means of single crystal X-ray diffraction analysis. It is shown that donor-acceptor Sb–N bond lengths for these complexes are equal within the experimental error. Quantum chemical calculations of the complexes in the gas phase reveal that the energies of the donor-acceptor bond Sb–N are 88 and 180 kJ mol−1 for SbCl5 • AN and SbCl5 • Py, respectively. It is established that the length of the donor-acceptor bond Sb–N in the crystal cannot serve as a measure of its strength.

AB - Molecular structure of crystalline complex SbCl5 • Py was determined for the first time and the structure of the complex SbCl5 • AN was refined by means of single crystal X-ray diffraction analysis. It is shown that donor-acceptor Sb–N bond lengths for these complexes are equal within the experimental error. Quantum chemical calculations of the complexes in the gas phase reveal that the energies of the donor-acceptor bond Sb–N are 88 and 180 kJ mol−1 for SbCl5 • AN and SbCl5 • Py, respectively. It is established that the length of the donor-acceptor bond Sb–N in the crystal cannot serve as a measure of its strength.

KW - acetonitrile

KW - antimony pentachloride

KW - molecular complexes

KW - pyridine

KW - structure

KW - ENERGY

KW - CRYSTAL-STRUCTURES

KW - ADDUCTS

KW - DONOR-ACCEPTOR BOND

KW - SOLID-STATE

UR - http://www.scopus.com/inward/record.url?scp=85083289440&partnerID=8YFLogxK

U2 - 10.1007/s11172-020-2726-6

DO - 10.1007/s11172-020-2726-6

M3 - Article

AN - SCOPUS:85083289440

VL - 69

SP - 84

EP - 90

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 1

ER -

ID: 24164126