Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II)

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Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II). / Barsukova, M. O.; Samsonenko, D. G.; Sapchenko, S. A. et al.

In: Russian Chemical Bulletin, Vol. 66, No. 8, 01.08.2017, p. 1472-1477.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{570728d341964ed38bbe654d85c52622,

title = "Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II)",

abstract = "The influence of heterocyclic compounds on the formation of coordination polymers in the system of cadmium(II) nitrate tetrahydrate and biphenyl-4,4′-dicarboxylic acid is demonstrated. Two new coordination polymers [Cd(H2O)(bpdc)(im)2] (1, bpdc2– is biphenyl-4,4′-dicarboxylate, im is imidazole) and [(CH3)2NH2]4[Cd6(dmf)(bpdc)8]·10DMF (2) were obtained under solvothermal conditions in the presence of imidazole or benzimidazole, respectively. Product 1 has a chain structure, while compound 2 possesses a three-dimensional structure with the hex topology. The obtained compounds were characterized by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction.",

keywords = "benzimidazole, cadmium, imidazole, metal–organic framework, X-ray diffraction, ACID, BUILDING UNITS, MOFS, COORDINATION POLYMERS, metal-organic framework",

author = "Barsukova, {M. O.} and Samsonenko, {D. G.} and Sapchenko, {S. A.} and Dybtsev, {D. N.} and Fedin, {V. P.}",

year = "2017",

month = aug,

day = "1",

doi = "10.1007/s11172-017-1910-9",

language = "English",

volume = "66",

pages = "1472--1477",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer Nature",

number = "8",

}

RIS

TY - JOUR

T1 - Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II)

AU - Barsukova, M. O.

AU - Samsonenko, D. G.

AU - Sapchenko, S. A.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2017/8/1

Y1 - 2017/8/1

N2 - The influence of heterocyclic compounds on the formation of coordination polymers in the system of cadmium(II) nitrate tetrahydrate and biphenyl-4,4′-dicarboxylic acid is demonstrated. Two new coordination polymers [Cd(H2O)(bpdc)(im)2] (1, bpdc2– is biphenyl-4,4′-dicarboxylate, im is imidazole) and [(CH3)2NH2]4[Cd6(dmf)(bpdc)8]·10DMF (2) were obtained under solvothermal conditions in the presence of imidazole or benzimidazole, respectively. Product 1 has a chain structure, while compound 2 possesses a three-dimensional structure with the hex topology. The obtained compounds were characterized by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction.

AB - The influence of heterocyclic compounds on the formation of coordination polymers in the system of cadmium(II) nitrate tetrahydrate and biphenyl-4,4′-dicarboxylic acid is demonstrated. Two new coordination polymers [Cd(H2O)(bpdc)(im)2] (1, bpdc2– is biphenyl-4,4′-dicarboxylate, im is imidazole) and [(CH3)2NH2]4[Cd6(dmf)(bpdc)8]·10DMF (2) were obtained under solvothermal conditions in the presence of imidazole or benzimidazole, respectively. Product 1 has a chain structure, while compound 2 possesses a three-dimensional structure with the hex topology. The obtained compounds were characterized by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction.

KW - benzimidazole

KW - cadmium

KW - imidazole

KW - metal–organic framework

KW - X-ray diffraction

KW - ACID

KW - BUILDING UNITS

KW - MOFS

KW - COORDINATION POLYMERS

KW - metal-organic framework

UR - http://www.scopus.com/inward/record.url?scp=85037671924&partnerID=8YFLogxK

U2 - 10.1007/s11172-017-1910-9

DO - 10.1007/s11172-017-1910-9

M3 - Article

AN - SCOPUS:85037671924

VL - 66

SP - 1472

EP - 1477

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 8

ER -

ID: 9647147