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Structure of the [Re12CS14(μ-SO2)(μ-O)2(CN)6]6– Cluster Anion. / Gayfulin, Ya M.; Smolentsev, A. I.; Mironov, Yu V.

In: Journal of Structural Chemistry, Vol. 59, No. 3, 01.05.2018, p. 669-672.

Research output: Contribution to journal › Article › peer-review

Harvard

Gayfulin, YM, Smolentsev, AI & Mironov, YV 2018, 'Structure of the [Re12CS14(μ-SO2)(μ-O)2(CN)6]6– Cluster Anion', Journal of Structural Chemistry, vol. 59, no. 3, pp. 669-672. https://doi.org/10.1134/S0022476618030241

APA

Gayfulin, Y. M., Smolentsev, A. I., & Mironov, Y. V. (2018). Structure of the [Re12CS14(μ-SO2)(μ-O)2(CN)6]6– Cluster Anion. Journal of Structural Chemistry, 59(3), 669-672. https://doi.org/10.1134/S0022476618030241

Vancouver

Gayfulin YM, Smolentsev AI, Mironov YV. Structure of the [Re12CS14(μ-SO2)(μ-O)2(CN)6]6– Cluster Anion. Journal of Structural Chemistry. 2018 May 1;59(3):669-672. doi: 10.1134/S0022476618030241

Author

Gayfulin, Ya M. ; Smolentsev, A. I. ; Mironov, Yu V. / Structure of the [Re12CS14(μ-SO2)(μ-O)2(CN)6]6– Cluster Anion. In: Journal of Structural Chemistry. 2018 ; Vol. 59, No. 3. pp. 669-672.

BibTeX

@article{a71ae0c41e484fe79c964a4400f9bc5b,
title = "Structure of the [Re12CS14(μ-SO2)(μ-O)2(CN)6]6– Cluster Anion",
abstract = "A K[Ni(NH3)6]2.5[Re12CS14(μ-O)2(μ-SO2)(CN)6]·8H2O compound (1) with a new [Re12CS14(μ-O)2(μ-SO2)(CN)6]6– cluster anion is prepared by the interaction of [Ni(NH3)6](aq) 2+ with the products of incomplete substitution of μ-SO2 2− ligands in the [Re12CS14(μ-SO2)3(CN)6]6– cluster anion and structurally characterized. New data on the effect of the ionic radius of the bridging μ-Q ligands on the geometric characteristics of the prismatic central {Re3C(μ-Q)3Re3} unit of the bioctahedral cluster anions are obtained. The synthesis of compound 1 experimentally confirms the existence of stable intermediates in the μ-O2– substitution reaction for the μ-SO2 2− ligands of the [Re12CS14(μ-SO2)3(CN)6]6– anion and evidences that the reaction proceeds in steps.",
keywords = "bioctahedral cluster, crystal structure, rhenium, LIGANDS, BIOCTAHEDRAL CLUSTER, RHENIUM CLUSTER",
author = "Gayfulin, {Ya M.} and Smolentsev, {A. I.} and Mironov, {Yu V.}",
year = "2018",
month = may,
day = "1",
doi = "10.1134/S0022476618030241",
language = "English",
volume = "59",
pages = "669--672",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "3",

}

RIS

TY - JOUR

T1 - Structure of the [Re12CS14(μ-SO2)(μ-O)2(CN)6]6– Cluster Anion

AU - Gayfulin, Ya M.

AU - Smolentsev, A. I.

AU - Mironov, Yu V.

PY - 2018/5/1

Y1 - 2018/5/1

N2 - A K[Ni(NH3)6]2.5[Re12CS14(μ-O)2(μ-SO2)(CN)6]·8H2O compound (1) with a new [Re12CS14(μ-O)2(μ-SO2)(CN)6]6– cluster anion is prepared by the interaction of [Ni(NH3)6](aq) 2+ with the products of incomplete substitution of μ-SO2 2− ligands in the [Re12CS14(μ-SO2)3(CN)6]6– cluster anion and structurally characterized. New data on the effect of the ionic radius of the bridging μ-Q ligands on the geometric characteristics of the prismatic central {Re3C(μ-Q)3Re3} unit of the bioctahedral cluster anions are obtained. The synthesis of compound 1 experimentally confirms the existence of stable intermediates in the μ-O2– substitution reaction for the μ-SO2 2− ligands of the [Re12CS14(μ-SO2)3(CN)6]6– anion and evidences that the reaction proceeds in steps.

AB - A K[Ni(NH3)6]2.5[Re12CS14(μ-O)2(μ-SO2)(CN)6]·8H2O compound (1) with a new [Re12CS14(μ-O)2(μ-SO2)(CN)6]6– cluster anion is prepared by the interaction of [Ni(NH3)6](aq) 2+ with the products of incomplete substitution of μ-SO2 2− ligands in the [Re12CS14(μ-SO2)3(CN)6]6– cluster anion and structurally characterized. New data on the effect of the ionic radius of the bridging μ-Q ligands on the geometric characteristics of the prismatic central {Re3C(μ-Q)3Re3} unit of the bioctahedral cluster anions are obtained. The synthesis of compound 1 experimentally confirms the existence of stable intermediates in the μ-O2– substitution reaction for the μ-SO2 2− ligands of the [Re12CS14(μ-SO2)3(CN)6]6– anion and evidences that the reaction proceeds in steps.

KW - bioctahedral cluster

KW - crystal structure

KW - rhenium

KW - LIGANDS

KW - BIOCTAHEDRAL CLUSTER

KW - RHENIUM CLUSTER

UR - http://www.scopus.com/inward/record.url?scp=85049620472&partnerID=8YFLogxK

U2 - 10.1134/S0022476618030241

DO - 10.1134/S0022476618030241

M3 - Article

AN - SCOPUS:85049620472

VL - 59

SP - 669

EP - 672

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 3

ER -

ID: 14446883