Standard

Structure of carbon nanoparticles synthesized by adiabatic compression of acetylene and their application in supercapacitors. / Fedoseeva, Yu V.; Popov, K. M.; Pozdnyakov, G. A. et al.

In: Journal of Structural Chemistry, Vol. 58, No. 6, 01.11.2017, p. 1196-1204.

Research output: Contribution to journal › Article › peer-review

Harvard

Fedoseeva, YV, Popov, KM, Pozdnyakov, GA, Yakovlev, VN, Sen’kovskiy, BV, Bulusheva, LG & Okotrub, AV 2017, 'Structure of carbon nanoparticles synthesized by adiabatic compression of acetylene and their application in supercapacitors', Journal of Structural Chemistry, vol. 58, no. 6, pp. 1196-1204. https://doi.org/10.1134/S002247661706018X

APA

Fedoseeva, Y. V., Popov, K. M., Pozdnyakov, G. A., Yakovlev, V. N., Sen’kovskiy, B. V., Bulusheva, L. G., & Okotrub, A. V. (2017). Structure of carbon nanoparticles synthesized by adiabatic compression of acetylene and their application in supercapacitors. Journal of Structural Chemistry, 58(6), 1196-1204. https://doi.org/10.1134/S002247661706018X

Vancouver

Fedoseeva YV, Popov KM, Pozdnyakov GA, Yakovlev VN, Sen’kovskiy BV, Bulusheva LG et al. Structure of carbon nanoparticles synthesized by adiabatic compression of acetylene and their application in supercapacitors. Journal of Structural Chemistry. 2017 Nov 1;58(6):1196-1204. doi: 10.1134/S002247661706018X

Author

Fedoseeva, Yu V. ; Popov, K. M. ; Pozdnyakov, G. A. et al. / Structure of carbon nanoparticles synthesized by adiabatic compression of acetylene and their application in supercapacitors. In: Journal of Structural Chemistry. 2017 ; Vol. 58, No. 6. pp. 1196-1204.

BibTeX

@article{501d4014082f48d0939a75a8e2eb4afc,
title = "Structure of carbon nanoparticles synthesized by adiabatic compression of acetylene and their application in supercapacitors",
abstract = "The work reports the study of the structure of carbon nanoparticles prepared by the pyrolysis of heliumdiluted acetylene under adiabatic compression in a piston reactor. At a pushing gas pressure of 0.5 MPa, 0.7 MPa, and 0.9 MPa the reaction gas was heated to temperatures of 400 °C, 600 °C, and 750 °C. By transmission electron microscopy it is found that carbon nanoparticles have a spherical shape and their size varies from 20 nm to 60 nm. The structural features of carbon nanoparticles are determined from the X-ray photoelectron spectroscopy data and the analysis of the near-edge X-ray absorption fine structure spectroscopy. Carbon nanoparticles prepared at a pushing gas pressure of 0.5 MPa have an amorphous structure and consist of hydrogenated carbon with impurities of polycyclic aromatic fragments. At a stronger compression ratio, carbon nanoparticles with a layered structure consisting mainly of sp2 hybridized carbon atoms are formed. The capacitance behavior and electrochemical impedance of carbon nanoparticle-based supercapacitors are compared.",
keywords = "acetylene pyrolysis, adiabatic compression, carbon nanoparticles, NEXAFS, XPS, STORAGE, NANOTUBES, NANOSTRUCTURES",
author = "Fedoseeva, {Yu V.} and Popov, {K. M.} and Pozdnyakov, {G. A.} and Yakovlev, {V. N.} and Sen{\textquoteright}kovskiy, {B. V.} and Bulusheva, {L. G.} and Okotrub, {A. V.}",
year = "2017",
month = nov,
day = "1",
doi = "10.1134/S002247661706018X",
language = "English",
volume = "58",
pages = "1196--1204",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "6",

}

RIS

TY - JOUR

T1 - Structure of carbon nanoparticles synthesized by adiabatic compression of acetylene and their application in supercapacitors

AU - Fedoseeva, Yu V.

AU - Popov, K. M.

AU - Pozdnyakov, G. A.

AU - Yakovlev, V. N.

AU - Sen’kovskiy, B. V.

AU - Bulusheva, L. G.

AU - Okotrub, A. V.

PY - 2017/11/1

Y1 - 2017/11/1

N2 - The work reports the study of the structure of carbon nanoparticles prepared by the pyrolysis of heliumdiluted acetylene under adiabatic compression in a piston reactor. At a pushing gas pressure of 0.5 MPa, 0.7 MPa, and 0.9 MPa the reaction gas was heated to temperatures of 400 °C, 600 °C, and 750 °C. By transmission electron microscopy it is found that carbon nanoparticles have a spherical shape and their size varies from 20 nm to 60 nm. The structural features of carbon nanoparticles are determined from the X-ray photoelectron spectroscopy data and the analysis of the near-edge X-ray absorption fine structure spectroscopy. Carbon nanoparticles prepared at a pushing gas pressure of 0.5 MPa have an amorphous structure and consist of hydrogenated carbon with impurities of polycyclic aromatic fragments. At a stronger compression ratio, carbon nanoparticles with a layered structure consisting mainly of sp2 hybridized carbon atoms are formed. The capacitance behavior and electrochemical impedance of carbon nanoparticle-based supercapacitors are compared.

AB - The work reports the study of the structure of carbon nanoparticles prepared by the pyrolysis of heliumdiluted acetylene under adiabatic compression in a piston reactor. At a pushing gas pressure of 0.5 MPa, 0.7 MPa, and 0.9 MPa the reaction gas was heated to temperatures of 400 °C, 600 °C, and 750 °C. By transmission electron microscopy it is found that carbon nanoparticles have a spherical shape and their size varies from 20 nm to 60 nm. The structural features of carbon nanoparticles are determined from the X-ray photoelectron spectroscopy data and the analysis of the near-edge X-ray absorption fine structure spectroscopy. Carbon nanoparticles prepared at a pushing gas pressure of 0.5 MPa have an amorphous structure and consist of hydrogenated carbon with impurities of polycyclic aromatic fragments. At a stronger compression ratio, carbon nanoparticles with a layered structure consisting mainly of sp2 hybridized carbon atoms are formed. The capacitance behavior and electrochemical impedance of carbon nanoparticle-based supercapacitors are compared.

KW - acetylene pyrolysis

KW - adiabatic compression

KW - carbon nanoparticles

KW - NEXAFS

KW - XPS

KW - STORAGE

KW - NANOTUBES

KW - NANOSTRUCTURES

UR - http://www.scopus.com/inward/record.url?scp=85036581497&partnerID=8YFLogxK

U2 - 10.1134/S002247661706018X

DO - 10.1134/S002247661706018X

M3 - Article

AN - SCOPUS:85036581497

VL - 58

SP - 1196

EP - 1204

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 6

ER -

ID: 9648497