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Structure and photoluminescence of Zn(II) and Сd(II) complexes with chiral bis-pyridine containing fragments of natural (–)-α-pinene. / Kokina, T. E.; Glinskaya, L. A.; Vasiliev, E. S. et al.

In: Journal of Structural Chemistry, Vol. 58, No. 5, 01.09.2017, p. 994-1003.

Research output: Contribution to journal › Article › peer-review

Harvard

Kokina, TE, Glinskaya, LA, Vasiliev, ES, Rakhmanova, MI, Makarova, SV, Piryazev, DA, Korol’kov, IV, Tkachev, AV & Larionov, SV 2017, 'Structure and photoluminescence of Zn(II) and Сd(II) complexes with chiral bis-pyridine containing fragments of natural (–)-α-pinene', Journal of Structural Chemistry, vol. 58, no. 5, pp. 994-1003. https://doi.org/10.1134/S0022476617050201

APA

Kokina, T. E., Glinskaya, L. A., Vasiliev, E. S., Rakhmanova, M. I., Makarova, S. V., Piryazev, D. A., Korol’kov, I. V., Tkachev, A. V., & Larionov, S. V. (2017). Structure and photoluminescence of Zn(II) and Сd(II) complexes with chiral bis-pyridine containing fragments of natural (–)-α-pinene. Journal of Structural Chemistry, 58(5), 994-1003. https://doi.org/10.1134/S0022476617050201

Vancouver

Kokina TE, Glinskaya LA, Vasiliev ES, Rakhmanova MI, Makarova SV, Piryazev DA et al. Structure and photoluminescence of Zn(II) and Сd(II) complexes with chiral bis-pyridine containing fragments of natural (–)-α-pinene. Journal of Structural Chemistry. 2017 Sept 1;58(5):994-1003. doi: 10.1134/S0022476617050201

Author

Kokina, T. E. ; Glinskaya, L. A. ; Vasiliev, E. S. et al. / Structure and photoluminescence of Zn(II) and Сd(II) complexes with chiral bis-pyridine containing fragments of natural (–)-α-pinene. In: Journal of Structural Chemistry. 2017 ; Vol. 58, No. 5. pp. 994-1003.

BibTeX

@article{5b7332e90e5d48bca391b31618319f3a,
title = "Structure and photoluminescence of Zn(II) and Сd(II) complexes with chiral bis-pyridine containing fragments of natural (–)-α-pinene",
abstract = "Complexes ZnLCl2 (I) and [CdLCl2]n (IV), where L is chiral bis-pyridine containing fragments of natural monoterpenoide (–)-α-pinene are synthesized. Single crystals of [ZnLCl2]·CH2Cl2 (II), [ZnLCl2]·i-PrOH (III), and IV compounds are grown. The crystal structures of II and III are composed of mononuclear ZnLCl2 complex molecules and solvate CH2Cl2 and i-PrOH molecules; the coordination polyhedron of the zinc atom Cl2N2 is a distorted tetrahedron. According to the single crystal XRD data, complex IV is a 1D coordination polymer; the coordination core CdN2Cl4 is a distorted octahedron and Cl atoms are bridging ligands. In the structures of II, III, and IV the L molecule functions as a bidentate chelate ligand. In the solid phase, complexes I and IV exhibit photoluminescence in the visible range (λmax 505 nm and 460 nm respectively). The band intensity in the photoluminescence spectra of I and IV complexes considerably exceeds the band intensity in the spectrum of free L.",
keywords = "bis-pyridine, photoluminescence, structure, terpenes, Zn(II) and Cd(II) complexes, DESIGN, RECOGNITION, CRYSTAL-STRUCTURE, PHOTOPHYSICAL PROPERTIES, ZINC(II), SENSORS, COORDINATION-COMPOUNDS, (+)-3-CARENE, LIGANDS, STEREOSELECTIVE-SYNTHESIS",
author = "Kokina, {T. E.} and Glinskaya, {L. A.} and Vasiliev, {E. S.} and Rakhmanova, {M. I.} and Makarova, {S. V.} and Piryazev, {D. A.} and Korol{\textquoteright}kov, {I. V.} and Tkachev, {A. V.} and Larionov, {S. V.}",
year = "2017",
month = sep,
day = "1",
doi = "10.1134/S0022476617050201",
language = "English",
volume = "58",
pages = "994--1003",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "5",

}

RIS

TY - JOUR

T1 - Structure and photoluminescence of Zn(II) and Сd(II) complexes with chiral bis-pyridine containing fragments of natural (–)-α-pinene

AU - Kokina, T. E.

AU - Glinskaya, L. A.

AU - Vasiliev, E. S.

AU - Rakhmanova, M. I.

AU - Makarova, S. V.

AU - Piryazev, D. A.

AU - Korol’kov, I. V.

AU - Tkachev, A. V.

AU - Larionov, S. V.

PY - 2017/9/1

Y1 - 2017/9/1

N2 - Complexes ZnLCl2 (I) and [CdLCl2]n (IV), where L is chiral bis-pyridine containing fragments of natural monoterpenoide (–)-α-pinene are synthesized. Single crystals of [ZnLCl2]·CH2Cl2 (II), [ZnLCl2]·i-PrOH (III), and IV compounds are grown. The crystal structures of II and III are composed of mononuclear ZnLCl2 complex molecules and solvate CH2Cl2 and i-PrOH molecules; the coordination polyhedron of the zinc atom Cl2N2 is a distorted tetrahedron. According to the single crystal XRD data, complex IV is a 1D coordination polymer; the coordination core CdN2Cl4 is a distorted octahedron and Cl atoms are bridging ligands. In the structures of II, III, and IV the L molecule functions as a bidentate chelate ligand. In the solid phase, complexes I and IV exhibit photoluminescence in the visible range (λmax 505 nm and 460 nm respectively). The band intensity in the photoluminescence spectra of I and IV complexes considerably exceeds the band intensity in the spectrum of free L.

AB - Complexes ZnLCl2 (I) and [CdLCl2]n (IV), where L is chiral bis-pyridine containing fragments of natural monoterpenoide (–)-α-pinene are synthesized. Single crystals of [ZnLCl2]·CH2Cl2 (II), [ZnLCl2]·i-PrOH (III), and IV compounds are grown. The crystal structures of II and III are composed of mononuclear ZnLCl2 complex molecules and solvate CH2Cl2 and i-PrOH molecules; the coordination polyhedron of the zinc atom Cl2N2 is a distorted tetrahedron. According to the single crystal XRD data, complex IV is a 1D coordination polymer; the coordination core CdN2Cl4 is a distorted octahedron and Cl atoms are bridging ligands. In the structures of II, III, and IV the L molecule functions as a bidentate chelate ligand. In the solid phase, complexes I and IV exhibit photoluminescence in the visible range (λmax 505 nm and 460 nm respectively). The band intensity in the photoluminescence spectra of I and IV complexes considerably exceeds the band intensity in the spectrum of free L.

KW - bis-pyridine

KW - photoluminescence

KW - structure

KW - terpenes

KW - Zn(II) and Cd(II) complexes

KW - DESIGN

KW - RECOGNITION

KW - CRYSTAL-STRUCTURE

KW - PHOTOPHYSICAL PROPERTIES

KW - ZINC(II)

KW - SENSORS

KW - COORDINATION-COMPOUNDS

KW - (+)-3-CARENE

KW - LIGANDS

KW - STEREOSELECTIVE-SYNTHESIS

UR - http://www.scopus.com/inward/record.url?scp=85032281171&partnerID=8YFLogxK

U2 - 10.1134/S0022476617050201

DO - 10.1134/S0022476617050201

M3 - Article

AN - SCOPUS:85032281171

VL - 58

SP - 994

EP - 1003

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

ER -

ID: 9873646