Structural features of cadmium(II) complexes with bis(benzimidazol-2-yl)methane

Standard

Structural features of cadmium(II) complexes with bis(benzimidazol-2-yl)methane. / Smirnova, K. S.; Sukhikh, T. S.; Adonin, S. A. et al.

In: Journal of Structural Chemistry, Vol. 62, No. 5, 05.2021, p. 718-726.

Research output: Contribution to journal › Article › peer-review

Harvard

Smirnova, KS, Sukhikh, TS, Adonin, SA, El’tsov, IV & Lider, EV 2021, 'Structural features of cadmium(II) complexes with bis(benzimidazol-2-yl)methane', Journal of Structural Chemistry, vol. 62, no. 5, pp. 718-726. https://doi.org/10.1134/S0022476621050085

APA

Smirnova, K. S., Sukhikh, T. S., Adonin, S. A., El’tsov, I. V., & Lider, E. V. (2021). Structural features of cadmium(II) complexes with bis(benzimidazol-2-yl)methane. Journal of Structural Chemistry, 62(5), 718-726. https://doi.org/10.1134/S0022476621050085

Vancouver

Smirnova KS, Sukhikh TS, Adonin SA, El’tsov IV , Lider EV. Structural features of cadmium(II) complexes with bis(benzimidazol-2-yl)methane. Journal of Structural Chemistry. 2021 May;62(5):718-726. doi: 10.1134/S0022476621050085

Author

Smirnova, K. S. ; Sukhikh, T. S. ; Adonin, S. A. et al. / Structural features of cadmium(II) complexes with bis(benzimidazol-2-yl)methane. In: Journal of Structural Chemistry. 2021 ; Vol. 62, No. 5. pp. 718-726.

BibTeX

@article{a6dbfca45b1447379f477afb03c8a05e,

title = "Structural features of cadmium(II) complexes with bis(benzimidazol-2-yl)methane",

abstract = "A series of cadmium(II) coordination compounds with bis(benzimidazol-2-yl)methane (L) is synthesized. Single crystals are obtained, and molecular and crystal structures of [Cd4(L)4Cl6(EtOH)0.77(H2O)1.23] [CdCl4]·H2O·5EtOH, [Cd(L)I2], and [Cd(L)2(EtOH)2][Cd(L)(NO3)3]2·6EtOH complexes are determined. According to the single crystal X-ray diffraction analysis, the organic ligand has a bidentate cyclic coordination. Distinctions in the structures of the compounds depending on the anion present are observed. The [Cd(L)I2] complex is mononuclear with cadmium ions are in the tetrahedral environment. Cadmium chloride and nitrate complexes are cationic-anionic with cadmium ions in different environments, and their coordination numbers vary in the range of 4-7.",

keywords = "benzimidazole, cadmium, cationic-anionic compounds, crystal structure, mononuclear complexes",

author = "Smirnova, {K. S.} and Sukhikh, {T. S.} and Adonin, {S. A.} and El{\textquoteright}tsov, {I. V.} and Lider, {E. V.}",

year = "2021",

month = may,

doi = "10.1134/S0022476621050085",

language = "English",

volume = "62",

pages = "718--726",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "5",

}

RIS

TY - JOUR

T1 - Structural features of cadmium(II) complexes with bis(benzimidazol-2-yl)methane

AU - Smirnova, K. S.

AU - Sukhikh, T. S.

AU - Adonin, S. A.

AU - El’tsov, I. V.

AU - Lider, E. V.

PY - 2021/5

Y1 - 2021/5

N2 - A series of cadmium(II) coordination compounds with bis(benzimidazol-2-yl)methane (L) is synthesized. Single crystals are obtained, and molecular and crystal structures of [Cd4(L)4Cl6(EtOH)0.77(H2O)1.23] [CdCl4]·H2O·5EtOH, [Cd(L)I2], and [Cd(L)2(EtOH)2][Cd(L)(NO3)3]2·6EtOH complexes are determined. According to the single crystal X-ray diffraction analysis, the organic ligand has a bidentate cyclic coordination. Distinctions in the structures of the compounds depending on the anion present are observed. The [Cd(L)I2] complex is mononuclear with cadmium ions are in the tetrahedral environment. Cadmium chloride and nitrate complexes are cationic-anionic with cadmium ions in different environments, and their coordination numbers vary in the range of 4-7.

AB - A series of cadmium(II) coordination compounds with bis(benzimidazol-2-yl)methane (L) is synthesized. Single crystals are obtained, and molecular and crystal structures of [Cd4(L)4Cl6(EtOH)0.77(H2O)1.23] [CdCl4]·H2O·5EtOH, [Cd(L)I2], and [Cd(L)2(EtOH)2][Cd(L)(NO3)3]2·6EtOH complexes are determined. According to the single crystal X-ray diffraction analysis, the organic ligand has a bidentate cyclic coordination. Distinctions in the structures of the compounds depending on the anion present are observed. The [Cd(L)I2] complex is mononuclear with cadmium ions are in the tetrahedral environment. Cadmium chloride and nitrate complexes are cationic-anionic with cadmium ions in different environments, and their coordination numbers vary in the range of 4-7.

KW - benzimidazole

KW - cadmium

KW - cationic-anionic compounds

KW - crystal structure

KW - mononuclear complexes

UR - http://www.scopus.com/inward/record.url?scp=85108096621&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/5bf91832-774a-30aa-8b4c-2c7c8b663916/

U2 - 10.1134/S0022476621050085

DO - 10.1134/S0022476621050085

M3 - Article

AN - SCOPUS:85108096621

VL - 62

SP - 718

EP - 726

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

ER -

ID: 28919293