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Structural characterization of a bioctahedral cluster [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– anion. / Lappi, T. I.; Gayfulin, Ya M.; Smolentsev, A. I. et al.

In: Journal of Structural Chemistry, Vol. 58, No. 4, 01.07.2017, p. 835-837.

Research output: Contribution to journal › Article › peer-review

Harvard

Lappi, TI, Gayfulin, YM, Smolentsev, AI & Mironov, YV 2017, 'Structural characterization of a bioctahedral cluster [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– anion', Journal of Structural Chemistry, vol. 58, no. 4, pp. 835-837. https://doi.org/10.1134/S002247661704031X

APA

Lappi, T. I., Gayfulin, Y. M., Smolentsev, A. I., & Mironov, Y. V. (2017). Structural characterization of a bioctahedral cluster [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– anion. Journal of Structural Chemistry, 58(4), 835-837. https://doi.org/10.1134/S002247661704031X

Vancouver

Lappi TI, Gayfulin YM, Smolentsev AI, Mironov YV. Structural characterization of a bioctahedral cluster [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– anion. Journal of Structural Chemistry. 2017 Jul 1;58(4):835-837. doi: 10.1134/S002247661704031X

Author

Lappi, T. I. ; Gayfulin, Ya M. ; Smolentsev, A. I. et al. / Structural characterization of a bioctahedral cluster [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– anion. In: Journal of Structural Chemistry. 2017 ; Vol. 58, No. 4. pp. 835-837.

BibTeX

@article{cff670d4b31a4ac8a0d4a1304bc8a2d5,
title = "Structural characterization of a bioctahedral cluster [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– anion",
abstract = "The [Zn(H2O)4]3[Re12CS14(μ-SO2)(μ-S)2(CN)6]0.875[Re12CS14(μ-S)3(CN)6]0.125•6H2O compound (1) containing a new [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– cluster anion is synthesized by the reaction of ZnCl2 and K6[Re12CS14(μ-S/SO/SO2)3(CN)6] in an aqueous solution and structurally characterized. Compound 1 crystallizes in a rhombic space group Pnma with the following unit cell parameters: a = 22.0834(7) {\AA}, b = 28.2551(9) {\AA}, c = 9.7775(3) {\AA}, V = 6100.9(3) {\AA}3, Z = 4, dcalc = 3.806 g/cm3. The crystal structure consists of two cluster anions in the ratio 7:1, occupying the same position, distorted [Zn(H2O)4]2+ cations, and solvate H2O molecules linked by hydrogen bonds.",
keywords = "bioctahedral cluster complex, coordination polymer, crystal structure, rhenium, COMPLEX, RHENIUM CLUSTER",
author = "Lappi, {T. I.} and Gayfulin, {Ya M.} and Smolentsev, {A. I.} and Mironov, {Yu V.}",
note = "Publisher Copyright: {\textcopyright} 2017, Pleiades Publishing, Ltd.",
year = "2017",
month = jul,
day = "1",
doi = "10.1134/S002247661704031X",
language = "English",
volume = "58",
pages = "835--837",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "4",

}

RIS

TY - JOUR

T1 - Structural characterization of a bioctahedral cluster [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– anion

AU - Lappi, T. I.

AU - Gayfulin, Ya M.

AU - Smolentsev, A. I.

AU - Mironov, Yu V.

N1 - Publisher Copyright: © 2017, Pleiades Publishing, Ltd.

PY - 2017/7/1

Y1 - 2017/7/1

N2 - The [Zn(H2O)4]3[Re12CS14(μ-SO2)(μ-S)2(CN)6]0.875[Re12CS14(μ-S)3(CN)6]0.125•6H2O compound (1) containing a new [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– cluster anion is synthesized by the reaction of ZnCl2 and K6[Re12CS14(μ-S/SO/SO2)3(CN)6] in an aqueous solution and structurally characterized. Compound 1 crystallizes in a rhombic space group Pnma with the following unit cell parameters: a = 22.0834(7) Å, b = 28.2551(9) Å, c = 9.7775(3) Å, V = 6100.9(3) Å3, Z = 4, dcalc = 3.806 g/cm3. The crystal structure consists of two cluster anions in the ratio 7:1, occupying the same position, distorted [Zn(H2O)4]2+ cations, and solvate H2O molecules linked by hydrogen bonds.

AB - The [Zn(H2O)4]3[Re12CS14(μ-SO2)(μ-S)2(CN)6]0.875[Re12CS14(μ-S)3(CN)6]0.125•6H2O compound (1) containing a new [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– cluster anion is synthesized by the reaction of ZnCl2 and K6[Re12CS14(μ-S/SO/SO2)3(CN)6] in an aqueous solution and structurally characterized. Compound 1 crystallizes in a rhombic space group Pnma with the following unit cell parameters: a = 22.0834(7) Å, b = 28.2551(9) Å, c = 9.7775(3) Å, V = 6100.9(3) Å3, Z = 4, dcalc = 3.806 g/cm3. The crystal structure consists of two cluster anions in the ratio 7:1, occupying the same position, distorted [Zn(H2O)4]2+ cations, and solvate H2O molecules linked by hydrogen bonds.

KW - bioctahedral cluster complex

KW - coordination polymer

KW - crystal structure

KW - rhenium

KW - COMPLEX

KW - RHENIUM CLUSTER

UR - http://www.scopus.com/inward/record.url?scp=85029596253&partnerID=8YFLogxK

U2 - 10.1134/S002247661704031X

DO - 10.1134/S002247661704031X

M3 - Article

AN - SCOPUS:85029596253

VL - 58

SP - 835

EP - 837

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -

ID: 9046221