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Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2Mo2(CO)4(η2-P2)] Complex and Silver(I) Salts. / Elsayed Moussa, Mehdi; Fleischmann, Martin; Peresypkina, Eugenia V. et al.

In: European Journal of Inorganic Chemistry, Vol. 2017, No. 25, 07.07.2017, p. 3222-3226.

Research output: Contribution to journal › Article › peer-review

Harvard

Elsayed Moussa, M, Fleischmann, M, Peresypkina, EV, Dütsch, L, Seidl, M, Balázs, G & Scheer, M 2017, 'Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2Mo2(CO)4(η2-P2)] Complex and Silver(I) Salts', European Journal of Inorganic Chemistry, vol. 2017, no. 25, pp. 3222-3226. https://doi.org/10.1002/ejic.201700646

APA

Elsayed Moussa, M., Fleischmann, M., Peresypkina, E. V., Dütsch, L., Seidl, M., Balázs, G., & Scheer, M. (2017). Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2Mo2(CO)4(η2-P2)] Complex and Silver(I) Salts. European Journal of Inorganic Chemistry, 2017(25), 3222-3226. https://doi.org/10.1002/ejic.201700646

Vancouver

Elsayed Moussa M, Fleischmann M, Peresypkina EV, Dütsch L, Seidl M, Balázs G et al. Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2Mo2(CO)4(η2-P2)] Complex and Silver(I) Salts. European Journal of Inorganic Chemistry. 2017 Jul 7;2017(25):3222-3226. doi: 10.1002/ejic.201700646

Author

Elsayed Moussa, Mehdi ; Fleischmann, Martin ; Peresypkina, Eugenia V. et al. / Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2Mo2(CO)4(η2-P2)] Complex and Silver(I) Salts. In: European Journal of Inorganic Chemistry. 2017 ; Vol. 2017, No. 25. pp. 3222-3226.

BibTeX

@article{6ef605cce3f54002b08409c84c3b4a41,
title = "Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2Mo2(CO)4(η2-P2)] Complex and Silver(I) Salts",
abstract = "The reactions of the tetrahedral diphosphorus [Cp2Mo2(CO)4(η2-P2)] (1; Cp = C5H5) complex with Ag[Al{OC(CF3)3}4] (AgTEF) (A) and Ag[FAl{OC(C6F5)(C6F10)}3] (AgFAl) (B) were studied. The first reaction led to the formation of the [Ag2(η2-1)2(η1:η1-1)2][TEF]2 (2) dimer and the [Ag2(η1:η1-1)3]n[TEF]2n (3) coordination polymer, whereas the second reaction afforded the [Ag2(η1:η1-1)2(η1-CH2Cl2)2(η2-C7H8)2][FAl]2 (4) or the [Ag2(η2-1)2(η1:η1-1)2][FAl]2 (5) dimer and the [Ag2(η1:η1-1)4]n[FAl]2n (6) coordination polymer. In each case, the products obtained depended on the ratio of the reactants and/or the synthetic procedure.",
keywords = "Coordinating anions, Coordination polymers, Phosphorus, Silver, Synthetic methods, MOLECULE, LIGAND COMPLEXES, NMR-SPECTROSCOPY, BUILDING-BLOCKS, BEHAVIOR, ORGANIC HYBRID MATERIALS, ONE-DIMENSIONAL POLYMERS, FRAMEWORKS, PENTAPHOSPHAFERROCENE, CHEMISTRY",
author = "{Elsayed Moussa}, Mehdi and Martin Fleischmann and Peresypkina, {Eugenia V.} and Luis D{\"u}tsch and Michael Seidl and Gabor Bal{\'a}zs and Manfred Scheer",
year = "2017",
month = jul,
day = "7",
doi = "10.1002/ejic.201700646",
language = "English",
volume = "2017",
pages = "3222--3226",
journal = "European Journal of Inorganic Chemistry",
issn = "1434-1948",
publisher = "Wiley-VCH Verlag",
number = "25",

}

RIS

TY - JOUR

T1 - Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2Mo2(CO)4(η2-P2)] Complex and Silver(I) Salts

AU - Elsayed Moussa, Mehdi

AU - Fleischmann, Martin

AU - Peresypkina, Eugenia V.

AU - Dütsch, Luis

AU - Seidl, Michael

AU - Balázs, Gabor

AU - Scheer, Manfred

PY - 2017/7/7

Y1 - 2017/7/7

N2 - The reactions of the tetrahedral diphosphorus [Cp2Mo2(CO)4(η2-P2)] (1; Cp = C5H5) complex with Ag[Al{OC(CF3)3}4] (AgTEF) (A) and Ag[FAl{OC(C6F5)(C6F10)}3] (AgFAl) (B) were studied. The first reaction led to the formation of the [Ag2(η2-1)2(η1:η1-1)2][TEF]2 (2) dimer and the [Ag2(η1:η1-1)3]n[TEF]2n (3) coordination polymer, whereas the second reaction afforded the [Ag2(η1:η1-1)2(η1-CH2Cl2)2(η2-C7H8)2][FAl]2 (4) or the [Ag2(η2-1)2(η1:η1-1)2][FAl]2 (5) dimer and the [Ag2(η1:η1-1)4]n[FAl]2n (6) coordination polymer. In each case, the products obtained depended on the ratio of the reactants and/or the synthetic procedure.

AB - The reactions of the tetrahedral diphosphorus [Cp2Mo2(CO)4(η2-P2)] (1; Cp = C5H5) complex with Ag[Al{OC(CF3)3}4] (AgTEF) (A) and Ag[FAl{OC(C6F5)(C6F10)}3] (AgFAl) (B) were studied. The first reaction led to the formation of the [Ag2(η2-1)2(η1:η1-1)2][TEF]2 (2) dimer and the [Ag2(η1:η1-1)3]n[TEF]2n (3) coordination polymer, whereas the second reaction afforded the [Ag2(η1:η1-1)2(η1-CH2Cl2)2(η2-C7H8)2][FAl]2 (4) or the [Ag2(η2-1)2(η1:η1-1)2][FAl]2 (5) dimer and the [Ag2(η1:η1-1)4]n[FAl]2n (6) coordination polymer. In each case, the products obtained depended on the ratio of the reactants and/or the synthetic procedure.

KW - Coordinating anions

KW - Coordination polymers

KW - Phosphorus

KW - Silver

KW - Synthetic methods

KW - MOLECULE

KW - LIGAND COMPLEXES

KW - NMR-SPECTROSCOPY

KW - BUILDING-BLOCKS

KW - BEHAVIOR

KW - ORGANIC HYBRID MATERIALS

KW - ONE-DIMENSIONAL POLYMERS

KW - FRAMEWORKS

KW - PENTAPHOSPHAFERROCENE

KW - CHEMISTRY

UR - http://www.scopus.com/inward/record.url?scp=85024102591&partnerID=8YFLogxK

U2 - 10.1002/ejic.201700646

DO - 10.1002/ejic.201700646

M3 - Article

C2 - 28943780

AN - SCOPUS:85024102591

VL - 2017

SP - 3222

EP - 3226

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 25

ER -

ID: 9977186