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Stoichiometric and Structural Diversity of Silver Hydroxymethylacetylenide Coordination Polymers. / Chupina, Anastasiya V.; Korolkov, Ilya; Abramov, Pavel A. et al.

In: European Journal of Inorganic Chemistry, Vol. 2020, No. 38, 15.10.2020, p. 3666-3672.

Research output: Contribution to journal › Article › peer-review

Harvard

Chupina, AV, Korolkov, I, Abramov, PA & Sokolov, MN 2020, 'Stoichiometric and Structural Diversity of Silver Hydroxymethylacetylenide Coordination Polymers', European Journal of Inorganic Chemistry, vol. 2020, no. 38, pp. 3666-3672. https://doi.org/10.1002/ejic.202000546

APA

Chupina, A. V., Korolkov, I., Abramov, P. A., & Sokolov, M. N. (2020). Stoichiometric and Structural Diversity of Silver Hydroxymethylacetylenide Coordination Polymers. European Journal of Inorganic Chemistry, 2020(38), 3666-3672. https://doi.org/10.1002/ejic.202000546

Vancouver

Chupina AV, Korolkov I, Abramov PA, Sokolov MN. Stoichiometric and Structural Diversity of Silver Hydroxymethylacetylenide Coordination Polymers. European Journal of Inorganic Chemistry. 2020 Oct 15;2020(38):3666-3672. doi: 10.1002/ejic.202000546

Author

Chupina, Anastasiya V. ; Korolkov, Ilya ; Abramov, Pavel A. et al. / Stoichiometric and Structural Diversity of Silver Hydroxymethylacetylenide Coordination Polymers. In: European Journal of Inorganic Chemistry. 2020 ; Vol. 2020, No. 38. pp. 3666-3672.

BibTeX

@article{79565d29ca834d7cb45834b55c8530ad,
title = "Stoichiometric and Structural Diversity of Silver Hydroxymethylacetylenide Coordination Polymers",
abstract = "Addition of in situ generated hydroxymethylacetylenide (terminal C-deprotonated propargylic alcohol, prop-2-yn-1-ol, C3H3OH) to aqueous solutions of AgNO3 in 1:1 molar ratio results in the formation of two new coordination polymers, {AgNO3·2[Ag(C3H2OH)]·2/3H2O}∞ (1) and {AgNO3·3Ag(C3H2OH)}∞ (2). Storage of crystalline samples of 1 or 2 under mother liquor at 5 °C for two weeks results in a new crystalline phase, {AgNO3·2[Ag(C3H2OH)]·H2O}∞ (3). Another two weeks evolution yields {AgNO3·2Ag(C3H2OH)}∞ (4). This product can be prepared in high scale by changing the reagent ratio between the hydroxymethylacetylenide and AgNO3 to 0.5:1. All products are colorless crystalline materials, and their structures were determined by single-crystal X-ray diffraction. They are highly light sensitive, in particular, in the presence of trace amounts of impurities.",
keywords = "Coordination polymers, Hydroxymethylacetylenide, Silver, XRD, ALKYNYL CAGE, NANOCLUSTER, COLUMN, ACETYLIDE DIANION, ACETYLENEDIIDE, CLUSTER",
author = "Chupina, {Anastasiya V.} and Ilya Korolkov and Abramov, {Pavel A.} and Sokolov, {Maxim N.}",
year = "2020",
month = oct,
day = "15",
doi = "10.1002/ejic.202000546",
language = "English",
volume = "2020",
pages = "3666--3672",
journal = "European Journal of Inorganic Chemistry",
issn = "1434-1948",
publisher = "Wiley-VCH Verlag",
number = "38",

}

RIS

TY - JOUR

T1 - Stoichiometric and Structural Diversity of Silver Hydroxymethylacetylenide Coordination Polymers

AU - Chupina, Anastasiya V.

AU - Korolkov, Ilya

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

PY - 2020/10/15

Y1 - 2020/10/15

N2 - Addition of in situ generated hydroxymethylacetylenide (terminal C-deprotonated propargylic alcohol, prop-2-yn-1-ol, C3H3OH) to aqueous solutions of AgNO3 in 1:1 molar ratio results in the formation of two new coordination polymers, {AgNO3·2[Ag(C3H2OH)]·2/3H2O}∞ (1) and {AgNO3·3Ag(C3H2OH)}∞ (2). Storage of crystalline samples of 1 or 2 under mother liquor at 5 °C for two weeks results in a new crystalline phase, {AgNO3·2[Ag(C3H2OH)]·H2O}∞ (3). Another two weeks evolution yields {AgNO3·2Ag(C3H2OH)}∞ (4). This product can be prepared in high scale by changing the reagent ratio between the hydroxymethylacetylenide and AgNO3 to 0.5:1. All products are colorless crystalline materials, and their structures were determined by single-crystal X-ray diffraction. They are highly light sensitive, in particular, in the presence of trace amounts of impurities.

AB - Addition of in situ generated hydroxymethylacetylenide (terminal C-deprotonated propargylic alcohol, prop-2-yn-1-ol, C3H3OH) to aqueous solutions of AgNO3 in 1:1 molar ratio results in the formation of two new coordination polymers, {AgNO3·2[Ag(C3H2OH)]·2/3H2O}∞ (1) and {AgNO3·3Ag(C3H2OH)}∞ (2). Storage of crystalline samples of 1 or 2 under mother liquor at 5 °C for two weeks results in a new crystalline phase, {AgNO3·2[Ag(C3H2OH)]·H2O}∞ (3). Another two weeks evolution yields {AgNO3·2Ag(C3H2OH)}∞ (4). This product can be prepared in high scale by changing the reagent ratio between the hydroxymethylacetylenide and AgNO3 to 0.5:1. All products are colorless crystalline materials, and their structures were determined by single-crystal X-ray diffraction. They are highly light sensitive, in particular, in the presence of trace amounts of impurities.

KW - Coordination polymers

KW - Hydroxymethylacetylenide

KW - Silver

KW - XRD

KW - ALKYNYL CAGE

KW - NANOCLUSTER

KW - COLUMN

KW - ACETYLIDE DIANION

KW - ACETYLENEDIIDE

KW - CLUSTER

UR - http://www.scopus.com/inward/record.url?scp=85088256661&partnerID=8YFLogxK

U2 - 10.1002/ejic.202000546

DO - 10.1002/ejic.202000546

M3 - Article

AN - SCOPUS:85088256661

VL - 2020

SP - 3666

EP - 3672

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 38

ER -

ID: 24783500