Standard

Stabilization of interpenetrating cluster-based frameworks promoted by N-H⋯X hydrogen bonds : Synthesis, structures and properties of {[Cd(NH3)4]3[Re3Mo3Se8(CN)6]}X (X = Cl, Br and I). / Muravieva, Viktoria K.; Gayfulin, Yakov M.; Lemoine, Pierric et al.

In: CrystEngComm, Vol. 20, No. 29, 07.08.2018, p. 4164-4172.

Research output: Contribution to journal › Article › peer-review

Harvard

Muravieva, VK, Gayfulin, YM, Lemoine, P, Naumov, NG & Cordier, S 2018, 'Stabilization of interpenetrating cluster-based frameworks promoted by N-H⋯X hydrogen bonds: Synthesis, structures and properties of {[Cd(NH3)4]3[Re3Mo3Se8(CN)6]}X (X = Cl, Br and I)', CrystEngComm, vol. 20, no. 29, pp. 4164-4172. https://doi.org/10.1039/c8ce00527c

APA

Muravieva, V. K., Gayfulin, Y. M., Lemoine, P., Naumov, N. G., & Cordier, S. (2018). Stabilization of interpenetrating cluster-based frameworks promoted by N-H⋯X hydrogen bonds: Synthesis, structures and properties of {[Cd(NH3)4]3[Re3Mo3Se8(CN)6]}X (X = Cl, Br and I). CrystEngComm, 20(29), 4164-4172. https://doi.org/10.1039/c8ce00527c

Vancouver

Muravieva VK, Gayfulin YM, Lemoine P, Naumov NG, Cordier S. Stabilization of interpenetrating cluster-based frameworks promoted by N-H⋯X hydrogen bonds: Synthesis, structures and properties of {[Cd(NH3)4]3[Re3Mo3Se8(CN)6]}X (X = Cl, Br and I). CrystEngComm. 2018 Aug 7;20(29):4164-4172. doi: 10.1039/c8ce00527c

Author

Muravieva, Viktoria K. ; Gayfulin, Yakov M. ; Lemoine, Pierric et al. / Stabilization of interpenetrating cluster-based frameworks promoted by N-H⋯X hydrogen bonds : Synthesis, structures and properties of {[Cd(NH3)4]3[Re3Mo3Se8(CN)6]}X (X = Cl, Br and I). In: CrystEngComm. 2018 ; Vol. 20, No. 29. pp. 4164-4172.

BibTeX

@article{82d7632877f64b7ea19a782b45a2e42d,
title = "Stabilization of interpenetrating cluster-based frameworks promoted by N-H⋯X hydrogen bonds: Synthesis, structures and properties of {[Cd(NH3)4]3[Re3Mo3Se8(CN)6]}X (X = Cl, Br and I)",
abstract = "Control of covalent coordination polymer structures using non-covalent interactions is a promising way for obtaining functional materials by self-assembly in solution. Here we report the crucial role of halide anions in the formation of interpenetrating frameworks based on cyanometalate clusters. It was found that the interaction of [Re3Mo3Se8(CN)6]5- cluster anions and Cd2+ cations in aqueous ammonia led to the formation of the 1D polymeric compound {[Cd(NH3)5]2[Cd(NH3)4]3[Re3Mo3Se8(CN)6]2}·5H2O (1). Compound 1 is unstable outside the mother liquor due to the rapid loss of NH3 and H2O molecules. Addition of KX (X = Cl, Br, I) to the reaction mixture led to selective formation of 3D framework compounds {[Cd(NH3)4]3[Re3Mo3Se8(CN)6]}X (2-4 for X = Cl, Br, I, respectively) stabilized by N-H⋯X hydrogen bonding. Compounds 2-4 demonstrate high thermal stability as well as reversible loss of ammonia and reversible oxidation in the solid state.",
keywords = "METAL-ORGANIC FRAMEWORKS, POROUS COORDINATION POLYMERS, INORGANIC 3D NETWORKS, CRYSTAL-STRUCTURE, PRUSSIAN BLUE, CATALYTIC-ACTIVITIES, MOLECULAR TECTONICS, OCTAHEDRAL RHENIUM, DFT CALCULATIONS, SOLID-STATE",
author = "Muravieva, {Viktoria K.} and Gayfulin, {Yakov M.} and Pierric Lemoine and Naumov, {Nikolay G.} and St{\'e}phane Cordier",
year = "2018",
month = aug,
day = "7",
doi = "10.1039/c8ce00527c",
language = "English",
volume = "20",
pages = "4164--4172",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "29",

}

RIS

TY - JOUR

T1 - Stabilization of interpenetrating cluster-based frameworks promoted by N-H⋯X hydrogen bonds

T2 - Synthesis, structures and properties of {[Cd(NH3)4]3[Re3Mo3Se8(CN)6]}X (X = Cl, Br and I)

AU - Muravieva, Viktoria K.

AU - Gayfulin, Yakov M.

AU - Lemoine, Pierric

AU - Naumov, Nikolay G.

AU - Cordier, Stéphane

PY - 2018/8/7

Y1 - 2018/8/7

N2 - Control of covalent coordination polymer structures using non-covalent interactions is a promising way for obtaining functional materials by self-assembly in solution. Here we report the crucial role of halide anions in the formation of interpenetrating frameworks based on cyanometalate clusters. It was found that the interaction of [Re3Mo3Se8(CN)6]5- cluster anions and Cd2+ cations in aqueous ammonia led to the formation of the 1D polymeric compound {[Cd(NH3)5]2[Cd(NH3)4]3[Re3Mo3Se8(CN)6]2}·5H2O (1). Compound 1 is unstable outside the mother liquor due to the rapid loss of NH3 and H2O molecules. Addition of KX (X = Cl, Br, I) to the reaction mixture led to selective formation of 3D framework compounds {[Cd(NH3)4]3[Re3Mo3Se8(CN)6]}X (2-4 for X = Cl, Br, I, respectively) stabilized by N-H⋯X hydrogen bonding. Compounds 2-4 demonstrate high thermal stability as well as reversible loss of ammonia and reversible oxidation in the solid state.

AB - Control of covalent coordination polymer structures using non-covalent interactions is a promising way for obtaining functional materials by self-assembly in solution. Here we report the crucial role of halide anions in the formation of interpenetrating frameworks based on cyanometalate clusters. It was found that the interaction of [Re3Mo3Se8(CN)6]5- cluster anions and Cd2+ cations in aqueous ammonia led to the formation of the 1D polymeric compound {[Cd(NH3)5]2[Cd(NH3)4]3[Re3Mo3Se8(CN)6]2}·5H2O (1). Compound 1 is unstable outside the mother liquor due to the rapid loss of NH3 and H2O molecules. Addition of KX (X = Cl, Br, I) to the reaction mixture led to selective formation of 3D framework compounds {[Cd(NH3)4]3[Re3Mo3Se8(CN)6]}X (2-4 for X = Cl, Br, I, respectively) stabilized by N-H⋯X hydrogen bonding. Compounds 2-4 demonstrate high thermal stability as well as reversible loss of ammonia and reversible oxidation in the solid state.

KW - METAL-ORGANIC FRAMEWORKS

KW - POROUS COORDINATION POLYMERS

KW - INORGANIC 3D NETWORKS

KW - CRYSTAL-STRUCTURE

KW - PRUSSIAN BLUE

KW - CATALYTIC-ACTIVITIES

KW - MOLECULAR TECTONICS

KW - OCTAHEDRAL RHENIUM

KW - DFT CALCULATIONS

KW - SOLID-STATE

UR - http://www.scopus.com/inward/record.url?scp=85050748352&partnerID=8YFLogxK

U2 - 10.1039/c8ce00527c

DO - 10.1039/c8ce00527c

M3 - Article

AN - SCOPUS:85050748352

VL - 20

SP - 4164

EP - 4172

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 29

ER -

ID: 15963331