Research output: Contribution to journal › Article › peer-review
Spin-crossover in iron(ii) coordination compounds with 2,6-bis(benzimidazol-2-yl)pyridine. / Ivanova, A. D.; Korotaev, E. V.; Komarov, V. Yu et al.
In: New Journal of Chemistry, Vol. 44, No. 15, 21.04.2020, p. 5834-5840.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Spin-crossover in iron(ii) coordination compounds with 2,6-bis(benzimidazol-2-yl)pyridine
AU - Ivanova, A. D.
AU - Korotaev, E. V.
AU - Komarov, V. Yu
AU - Sheludyakova, L. A.
AU - Varnek, V. A.
AU - Lavrenova, L. G.
PY - 2020/4/21
Y1 - 2020/4/21
N2 - New iron(ii) complexes with 2,6-bis(benzimidazol-2-yl)pyridine (L), in particular, [FeL2]A2·nH2O (A = Br- (I), NO3- (II), C2N3- (III); n = 1 (I), 0.5 (II), 2 (III)) and [NiL2]Br2·1.23H2O·3.33EtOH (IV), have been synthesized and studied using single-crystal and powder X-ray diffraction techniques, UV-vis (diffuse reflection), IR and Mössbauer spectroscopy, as well as static magnetic susceptibility measurements. According to the experimental μeff(T) curves all the studied iron(ii) compounds exhibit 1A1 ↔ 5T2 spin-crossover.
AB - New iron(ii) complexes with 2,6-bis(benzimidazol-2-yl)pyridine (L), in particular, [FeL2]A2·nH2O (A = Br- (I), NO3- (II), C2N3- (III); n = 1 (I), 0.5 (II), 2 (III)) and [NiL2]Br2·1.23H2O·3.33EtOH (IV), have been synthesized and studied using single-crystal and powder X-ray diffraction techniques, UV-vis (diffuse reflection), IR and Mössbauer spectroscopy, as well as static magnetic susceptibility measurements. According to the experimental μeff(T) curves all the studied iron(ii) compounds exhibit 1A1 ↔ 5T2 spin-crossover.
KW - COMPLEXES
KW - LIGAND
UR - http://www.scopus.com/inward/record.url?scp=85083638023&partnerID=8YFLogxK
U2 - 10.1039/d0nj00474j
DO - 10.1039/d0nj00474j
M3 - Article
AN - SCOPUS:85083638023
VL - 44
SP - 5834
EP - 5840
JO - New Journal of Chemistry
JF - New Journal of Chemistry
SN - 1144-0546
IS - 15
ER -
ID: 24162354