Research output: Contribution to journal › Article › peer-review
Specific features of the phase formation, synthesis, and growth of ZnMoO4 crystals. / Galashov, E. N.; Galkin, P. S.; Plusnin, P. E. et al.
In: Crystallography Reports, Vol. 59, No. 2, 03.2014, p. 288-290.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Specific features of the phase formation, synthesis, and growth of ZnMoO4 crystals
AU - Galashov, E. N.
AU - Galkin, P. S.
AU - Plusnin, P. E.
AU - Shlegel, V. N.
N1 - Copyright: Copyright 2014 Elsevier B.V., All rights reserved.
PY - 2014/3
Y1 - 2014/3
N2 - The ZnO-MoO3 phase diagram in the range of ZnO compositions from 0.95 to 1.05 mol % is refined by differential scanning calorimetry. Data on crystal stoichiometry are obtained using the weighting method by reducing ZnMoO4 in a hydrogen atmosphere. The specific features of solid-phase synthesis of ZnMoO4 are studied, and its heat of fusion is measured. The modes of solid-phase synthesis and growth of ZnMoO4 crystals are optimized. Some experimental data on the ZnMoO4 crystal growth in the [001] direction by the low-thermal gradient Czochralski method are presented. Crystals with a cross section of ∼50 × 50 mm2, a length of 160 mm, and a weight up to 1 kg have been obtained.
AB - The ZnO-MoO3 phase diagram in the range of ZnO compositions from 0.95 to 1.05 mol % is refined by differential scanning calorimetry. Data on crystal stoichiometry are obtained using the weighting method by reducing ZnMoO4 in a hydrogen atmosphere. The specific features of solid-phase synthesis of ZnMoO4 are studied, and its heat of fusion is measured. The modes of solid-phase synthesis and growth of ZnMoO4 crystals are optimized. Some experimental data on the ZnMoO4 crystal growth in the [001] direction by the low-thermal gradient Czochralski method are presented. Crystals with a cross section of ∼50 × 50 mm2, a length of 160 mm, and a weight up to 1 kg have been obtained.
UR - http://www.scopus.com/inward/record.url?scp=84897398430&partnerID=8YFLogxK
U2 - 10.1134/S1063774514020084
DO - 10.1134/S1063774514020084
M3 - Article
AN - SCOPUS:84897398430
VL - 59
SP - 288
EP - 290
JO - Crystallography Reports
JF - Crystallography Reports
SN - 1063-7745
IS - 2
ER -
ID: 27432193