Research output: Contribution to journal › Article › peer-review
Special Features of Localization of Eu3+ Ion in the Matrix of (GdxY1–x)2O3 : Eu3+ Solutions During Sol-Gel Synthesis of the Luminophor. / Bakovets, V. V.; Pivovarova, T. D.; Dolgovesova, I. P. et al.
In: Russian Journal of General Chemistry, Vol. 88, No. 5, 01.05.2018, p. 992-999.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Special Features of Localization of Eu3+ Ion in the Matrix of (GdxY1–x)2O3
T2 - Eu3+ Solutions During Sol-Gel Synthesis of the Luminophor
AU - Bakovets, V. V.
AU - Pivovarova, T. D.
AU - Dolgovesova, I. P.
AU - Korolkov, I. V.
AU - Antonova, O. V.
AU - Kozhemyachenko, S. I.
PY - 2018/5/1
Y1 - 2018/5/1
N2 - Sol-gel synthesis of the (GdxY1–x)2O3: Eu3+ solid solutions (3.5 mol %) allows for the increase in the energy efficiency of emission of the red luminophor. The study of distribution of the luminescence activator Eu3+ has revealed that these ions substitute the Gd3+ ones in the cationic sublattice of ternary solid solution. The Eu3+ ions are predominantly localized in the noncentrosymmetrical position C2 at x < 0.50 and in centrosymmetrical position C3i at x > 0.50. The increase in the Eu3+ ions concentration in the C3i position stabilizes the cubic high-temperature structure of the solid solution in comparison with the monoclinic phase. The solid solution with x = 0.75 has been found to be the most efficient luminophor.
AB - Sol-gel synthesis of the (GdxY1–x)2O3: Eu3+ solid solutions (3.5 mol %) allows for the increase in the energy efficiency of emission of the red luminophor. The study of distribution of the luminescence activator Eu3+ has revealed that these ions substitute the Gd3+ ones in the cationic sublattice of ternary solid solution. The Eu3+ ions are predominantly localized in the noncentrosymmetrical position C2 at x < 0.50 and in centrosymmetrical position C3i at x > 0.50. The increase in the Eu3+ ions concentration in the C3i position stabilizes the cubic high-temperature structure of the solid solution in comparison with the monoclinic phase. The solid solution with x = 0.75 has been found to be the most efficient luminophor.
KW - europium cations localization
KW - local lattice order
KW - photoluminescence
KW - rare-earth elements oxides
KW - solid solution
KW - EARTH
KW - LUMINESCENCE
KW - DIFFRACTION
KW - POWDER
UR - http://www.scopus.com/inward/record.url?scp=85049313898&partnerID=8YFLogxK
U2 - 10.1134/S1070363218050262
DO - 10.1134/S1070363218050262
M3 - Article
AN - SCOPUS:85049313898
VL - 88
SP - 992
EP - 999
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 5
ER -
ID: 14317031