Standard

Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium : Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4. / Makhinya, A. N.; Il’in, M. A.; Korol’kov, I. V. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 44, No. 10, 01.10.2018, p. 613-618.

Research output: Contribution to journal › Article › peer-review

Harvard

Makhinya, AN, Il’in, MA, Korol’kov, IV & Baidina, IA 2018, 'Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium: Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 44, no. 10, pp. 613-618. https://doi.org/10.1134/S1070328418100093

APA

Makhinya, A. N., Il’in, M. A., Korol’kov, I. V., & Baidina, I. A. (2018). Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium: Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 44(10), 613-618. https://doi.org/10.1134/S1070328418100093

Vancouver

Makhinya AN, Il’in MA, Korol’kov IV, Baidina IA. Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium: Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2018 Oct 1;44(10):613-618. doi: 10.1134/S1070328418100093

Author

Makhinya, A. N. ; Il’in, M. A. ; Korol’kov, I. V. et al. / Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium : Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2018 ; Vol. 44, No. 10. pp. 613-618.

BibTeX

@article{216f859e85ad49fca79436dd67d7fc9f,
title = "Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium: Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4",
abstract = "Abstract: The slow evaporation of an acetone solution containing trans-[Ru(NO)Py4(OH)]2+ cations and hexafluorophosphate anions results in the crystallization of trans-[Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO (I). The reactions of trans‑[Ru(NO)Py4(OH)]Cl2 ⋅ H2O with solutions of chloric or hydrochloric acid followed by the evaporation of the reaction solutions at ambient temperature afford trans-[Ru(NO)Py4(H2O)](ClO4)3 (II) or [H5O2]2[Ru(NO)Py4Cl]Cl4 (III), respectively. The obtained chloride complex III is unstable and at ambient temperature eliminates hydrogen chloride to transform into trans-[Ru(NO)Py4Cl]Cl2 ⋅ 4H2O (IV). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files ССDC nos. 1421042 (I) and 1421041 (III)).",
keywords = "amino complexes, chloride complexes, hydroxo complexes, IR spectroscopy, nitrosoruthenium complexes, pyridine, X-ray structure analysis, LINKAGE ISOMERS, LIGHT, RUTHENIUM, INDUCED METASTABLE STATES",
author = "Makhinya, {A. N.} and Il{\textquoteright}in, {M. A.} and Korol{\textquoteright}kov, {I. V.} and Baidina, {I. A.}",
note = "Publisher Copyright: {\textcopyright} 2018, Pleiades Publishing, Ltd.",
year = "2018",
month = oct,
day = "1",
doi = "10.1134/S1070328418100093",
language = "English",
volume = "44",
pages = "613--618",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "10",

}

RIS

TY - JOUR

T1 - Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium

T2 - Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4

AU - Makhinya, A. N.

AU - Il’in, M. A.

AU - Korol’kov, I. V.

AU - Baidina, I. A.

N1 - Publisher Copyright: © 2018, Pleiades Publishing, Ltd.

PY - 2018/10/1

Y1 - 2018/10/1

N2 - Abstract: The slow evaporation of an acetone solution containing trans-[Ru(NO)Py4(OH)]2+ cations and hexafluorophosphate anions results in the crystallization of trans-[Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO (I). The reactions of trans‑[Ru(NO)Py4(OH)]Cl2 ⋅ H2O with solutions of chloric or hydrochloric acid followed by the evaporation of the reaction solutions at ambient temperature afford trans-[Ru(NO)Py4(H2O)](ClO4)3 (II) or [H5O2]2[Ru(NO)Py4Cl]Cl4 (III), respectively. The obtained chloride complex III is unstable and at ambient temperature eliminates hydrogen chloride to transform into trans-[Ru(NO)Py4Cl]Cl2 ⋅ 4H2O (IV). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files ССDC nos. 1421042 (I) and 1421041 (III)).

AB - Abstract: The slow evaporation of an acetone solution containing trans-[Ru(NO)Py4(OH)]2+ cations and hexafluorophosphate anions results in the crystallization of trans-[Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO (I). The reactions of trans‑[Ru(NO)Py4(OH)]Cl2 ⋅ H2O with solutions of chloric or hydrochloric acid followed by the evaporation of the reaction solutions at ambient temperature afford trans-[Ru(NO)Py4(H2O)](ClO4)3 (II) or [H5O2]2[Ru(NO)Py4Cl]Cl4 (III), respectively. The obtained chloride complex III is unstable and at ambient temperature eliminates hydrogen chloride to transform into trans-[Ru(NO)Py4Cl]Cl2 ⋅ 4H2O (IV). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files ССDC nos. 1421042 (I) and 1421041 (III)).

KW - amino complexes

KW - chloride complexes

KW - hydroxo complexes

KW - IR spectroscopy

KW - nitrosoruthenium complexes

KW - pyridine

KW - X-ray structure analysis

KW - LINKAGE ISOMERS

KW - LIGHT

KW - RUTHENIUM

KW - INDUCED METASTABLE STATES

UR - http://www.scopus.com/inward/record.url?scp=85054478295&partnerID=8YFLogxK

U2 - 10.1134/S1070328418100093

DO - 10.1134/S1070328418100093

M3 - Article

AN - SCOPUS:85054478295

VL - 44

SP - 613

EP - 618

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 10

ER -

ID: 17035970