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Solid/gas biocatalysis. / Kulishova, L. M.; Zharkov, D. O.

In: Biochemistry (Moscow), Vol. 82, No. 2, 01.02.2017, p. 95-105.

Research output: Contribution to journalReview articlepeer-review

Harvard

Kulishova, LM & Zharkov, DO 2017, 'Solid/gas biocatalysis', Biochemistry (Moscow), vol. 82, no. 2, pp. 95-105. https://doi.org/10.1134/S000629791702002X

APA

Kulishova, L. M., & Zharkov, D. O. (2017). Solid/gas biocatalysis. Biochemistry (Moscow), 82(2), 95-105. https://doi.org/10.1134/S000629791702002X

Vancouver

Kulishova LM, Zharkov DO. Solid/gas biocatalysis. Biochemistry (Moscow). 2017 Feb 1;82(2):95-105. doi: 10.1134/S000629791702002X

Author

Kulishova, L. M. ; Zharkov, D. O. / Solid/gas biocatalysis. In: Biochemistry (Moscow). 2017 ; Vol. 82, No. 2. pp. 95-105.

BibTeX

@article{6e07fd30cb6849db845e680ba9f36f29,
title = "Solid/gas biocatalysis",
abstract = "Solid/gas biocatalysis is a nontraditional reaction system that employs the ability of some enzymes, being in the solid state, to catalyze reactions of substrates in the gas phase. Manipulation of the reaction parameters (temperature and pressure) in the solid/gas system allows precise control over the thermodynamic activity of water and substrate and creation of a controlled microenvironment for the enzyme, making it an appropriate model for enzymology studies. Owing to such advantages as high stability of dry enzymes and cofactors and easy fractionation of gas mixtures, solid/gas biotechnology has already found several industrial applications. Here we review key thermodynamic factors affecting the properties of enzymes, including their activity and stability, in a solid/gas system. Examples of promising enzymes and microorganisms for development and improvement of solid/gas biocatalytic technologies in organic synthesis, biosensors, and green chemistry are discussed.",
keywords = "alcohol dehydrogenases, dehalogenases, esterases, immobilized enzymes, lipases, lyophilized enzymes, protein hydration, solid/gas biocatalysis",
author = "Kulishova, {L. M.} and Zharkov, {D. O.}",
year = "2017",
month = feb,
day = "1",
doi = "10.1134/S000629791702002X",
language = "English",
volume = "82",
pages = "95--105",
journal = "Biochemistry (Moscow)",
issn = "0006-2979",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "2",

}

RIS

TY - JOUR

T1 - Solid/gas biocatalysis

AU - Kulishova, L. M.

AU - Zharkov, D. O.

PY - 2017/2/1

Y1 - 2017/2/1

N2 - Solid/gas biocatalysis is a nontraditional reaction system that employs the ability of some enzymes, being in the solid state, to catalyze reactions of substrates in the gas phase. Manipulation of the reaction parameters (temperature and pressure) in the solid/gas system allows precise control over the thermodynamic activity of water and substrate and creation of a controlled microenvironment for the enzyme, making it an appropriate model for enzymology studies. Owing to such advantages as high stability of dry enzymes and cofactors and easy fractionation of gas mixtures, solid/gas biotechnology has already found several industrial applications. Here we review key thermodynamic factors affecting the properties of enzymes, including their activity and stability, in a solid/gas system. Examples of promising enzymes and microorganisms for development and improvement of solid/gas biocatalytic technologies in organic synthesis, biosensors, and green chemistry are discussed.

AB - Solid/gas biocatalysis is a nontraditional reaction system that employs the ability of some enzymes, being in the solid state, to catalyze reactions of substrates in the gas phase. Manipulation of the reaction parameters (temperature and pressure) in the solid/gas system allows precise control over the thermodynamic activity of water and substrate and creation of a controlled microenvironment for the enzyme, making it an appropriate model for enzymology studies. Owing to such advantages as high stability of dry enzymes and cofactors and easy fractionation of gas mixtures, solid/gas biotechnology has already found several industrial applications. Here we review key thermodynamic factors affecting the properties of enzymes, including their activity and stability, in a solid/gas system. Examples of promising enzymes and microorganisms for development and improvement of solid/gas biocatalytic technologies in organic synthesis, biosensors, and green chemistry are discussed.

KW - alcohol dehydrogenases

KW - dehalogenases

KW - esterases

KW - immobilized enzymes

KW - lipases

KW - lyophilized enzymes

KW - protein hydration

KW - solid/gas biocatalysis

UR - http://www.scopus.com/inward/record.url?scp=85013218766&partnerID=8YFLogxK

U2 - 10.1134/S000629791702002X

DO - 10.1134/S000629791702002X

M3 - Review article

C2 - 28320294

AN - SCOPUS:85013218766

VL - 82

SP - 95

EP - 105

JO - Biochemistry (Moscow)

JF - Biochemistry (Moscow)

SN - 0006-2979

IS - 2

ER -

ID: 8672736