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Single-phase CZTSe via isothermal recrystallization in a KI-KCl flux. / Bakhadur, A. M.; Uralbekov, B. M.; Atuchin, V. V. et al.

In: CrystEngComm, Vol. 24, No. 12, 02.03.2022, p. 2291-2296.

Research output: Contribution to journal › Article › peer-review

Harvard

Bakhadur, AM, Uralbekov, BM, Atuchin, VV, Mukherjee, S & Kokh, KA 2022, 'Single-phase CZTSe via isothermal recrystallization in a KI-KCl flux', CrystEngComm, vol. 24, no. 12, pp. 2291-2296. https://doi.org/10.1039/d1ce01653a

APA

Bakhadur, A. M., Uralbekov, B. M., Atuchin, V. V., Mukherjee, S., & Kokh, K. A. (2022). Single-phase CZTSe via isothermal recrystallization in a KI-KCl flux. CrystEngComm, 24(12), 2291-2296. https://doi.org/10.1039/d1ce01653a

Vancouver

Bakhadur AM, Uralbekov BM, Atuchin VV, Mukherjee S, Kokh KA. Single-phase CZTSe via isothermal recrystallization in a KI-KCl flux. CrystEngComm. 2022 Mar 2;24(12):2291-2296. doi: 10.1039/d1ce01653a

Author

Bakhadur, A. M. ; Uralbekov, B. M. ; Atuchin, V. V. et al. / Single-phase CZTSe via isothermal recrystallization in a KI-KCl flux. In: CrystEngComm. 2022 ; Vol. 24, No. 12. pp. 2291-2296.

BibTeX

@article{6df1afb18dac4bc9bce074709bc6f06c,
title = "Single-phase CZTSe via isothermal recrystallization in a KI-KCl flux",
abstract = "A facile, two-step procedure was developed to prepare a pure CZTSe (Cu2ZnSnSe4) phase from elemental Cu, Zn, Sn, and Se with the addition of a KI-KCl mixture. During the first step, the mixture charge was reacted at 1000 °C to convert all the metals to selenides. Next, the extracted charge was powdered and again heated to 750 °C to obtain homogeneous grains of CZTSe with a size of 30-100 microns. The main intermediate phase during the synthesis of Cu2SnSe3 was found to dissolve Zn up to 11.5 at% and, without Raman spectroscopy data, this phase could be easily confused with CZTSe because they are not optically distinguishable. On the other hand, the deviation of the Zn content in CZTSe does not exceed ±0.5 at%.",
author = "Bakhadur, {A. M.} and Uralbekov, {B. M.} and Atuchin, {V. V.} and S. Mukherjee and Kokh, {K. A.}",
note = "Funding Information: This work was supported by the Science Committee of the Ministry of Education and Science of the Republic of Kazakhstan (Grant No. AP08052719), the DST-RSF Project through the India-Russia Program of Cooperation in Science and Technology under Grant DST/INT/RUS/RSF/P-20 dated May 16, 2019, by the Ministry of Science and Higher Education of Russian Federation (project 075-15-2020-797 (13.1902.21.0024)), and by state assignment of IGM SB RAS. Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry",
year = "2022",
month = mar,
day = "2",
doi = "10.1039/d1ce01653a",
language = "English",
volume = "24",
pages = "2291--2296",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "12",

}

RIS

TY - JOUR

T1 - Single-phase CZTSe via isothermal recrystallization in a KI-KCl flux

AU - Bakhadur, A. M.

AU - Uralbekov, B. M.

AU - Atuchin, V. V.

AU - Mukherjee, S.

AU - Kokh, K. A.

N1 - Funding Information: This work was supported by the Science Committee of the Ministry of Education and Science of the Republic of Kazakhstan (Grant No. AP08052719), the DST-RSF Project through the India-Russia Program of Cooperation in Science and Technology under Grant DST/INT/RUS/RSF/P-20 dated May 16, 2019, by the Ministry of Science and Higher Education of Russian Federation (project 075-15-2020-797 (13.1902.21.0024)), and by state assignment of IGM SB RAS. Publisher Copyright: © 2022 The Royal Society of Chemistry

PY - 2022/3/2

Y1 - 2022/3/2

N2 - A facile, two-step procedure was developed to prepare a pure CZTSe (Cu2ZnSnSe4) phase from elemental Cu, Zn, Sn, and Se with the addition of a KI-KCl mixture. During the first step, the mixture charge was reacted at 1000 °C to convert all the metals to selenides. Next, the extracted charge was powdered and again heated to 750 °C to obtain homogeneous grains of CZTSe with a size of 30-100 microns. The main intermediate phase during the synthesis of Cu2SnSe3 was found to dissolve Zn up to 11.5 at% and, without Raman spectroscopy data, this phase could be easily confused with CZTSe because they are not optically distinguishable. On the other hand, the deviation of the Zn content in CZTSe does not exceed ±0.5 at%.

AB - A facile, two-step procedure was developed to prepare a pure CZTSe (Cu2ZnSnSe4) phase from elemental Cu, Zn, Sn, and Se with the addition of a KI-KCl mixture. During the first step, the mixture charge was reacted at 1000 °C to convert all the metals to selenides. Next, the extracted charge was powdered and again heated to 750 °C to obtain homogeneous grains of CZTSe with a size of 30-100 microns. The main intermediate phase during the synthesis of Cu2SnSe3 was found to dissolve Zn up to 11.5 at% and, without Raman spectroscopy data, this phase could be easily confused with CZTSe because they are not optically distinguishable. On the other hand, the deviation of the Zn content in CZTSe does not exceed ±0.5 at%.

UR - http://www.scopus.com/inward/record.url?scp=85127755278&partnerID=8YFLogxK

U2 - 10.1039/d1ce01653a

DO - 10.1039/d1ce01653a

M3 - Article

AN - SCOPUS:85127755278

VL - 24

SP - 2291

EP - 2296

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 12

ER -

ID: 35878455