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Selective Hydrogenation of Biomass-Derived Furfural : Enhanced Catalytic Performance of Pd−Cu Alloy Nanoparticles in Porous Polymer. / Salnikova, Ksenia E.; Larichev, Yurii V.; Sulman, Esther M. et al.

In: ChemPlusChem, Vol. 85, No. 8, 01.08.2020, p. 1697-1703.

Research output: Contribution to journalArticlepeer-review

Harvard

Salnikova, KE, Larichev, YV, Sulman, EM, Bykov, AV, Sidorov, AI, Demidenko, GN, Sulman, MG, Bronstein, LM & Matveeva, VG 2020, 'Selective Hydrogenation of Biomass-Derived Furfural: Enhanced Catalytic Performance of Pd−Cu Alloy Nanoparticles in Porous Polymer', ChemPlusChem, vol. 85, no. 8, pp. 1697-1703. https://doi.org/10.1002/cplu.202000383

APA

Salnikova, K. E., Larichev, Y. V., Sulman, E. M., Bykov, A. V., Sidorov, A. I., Demidenko, G. N., Sulman, M. G., Bronstein, L. M., & Matveeva, V. G. (2020). Selective Hydrogenation of Biomass-Derived Furfural: Enhanced Catalytic Performance of Pd−Cu Alloy Nanoparticles in Porous Polymer. ChemPlusChem, 85(8), 1697-1703. https://doi.org/10.1002/cplu.202000383

Vancouver

Salnikova KE, Larichev YV, Sulman EM, Bykov AV, Sidorov AI, Demidenko GN et al. Selective Hydrogenation of Biomass-Derived Furfural: Enhanced Catalytic Performance of Pd−Cu Alloy Nanoparticles in Porous Polymer. ChemPlusChem. 2020 Aug 1;85(8):1697-1703. Epub 2020 Jun 29. doi: 10.1002/cplu.202000383

Author

Salnikova, Ksenia E. ; Larichev, Yurii V. ; Sulman, Esther M. et al. / Selective Hydrogenation of Biomass-Derived Furfural : Enhanced Catalytic Performance of Pd−Cu Alloy Nanoparticles in Porous Polymer. In: ChemPlusChem. 2020 ; Vol. 85, No. 8. pp. 1697-1703.

BibTeX

@article{b5e10412fe4b43ce825bbfb5860bd4ab,
title = "Selective Hydrogenation of Biomass-Derived Furfural: Enhanced Catalytic Performance of Pd−Cu Alloy Nanoparticles in Porous Polymer",
abstract = "Here, the development of a new catalyst is reported for the selective furfural (FF) hydrogenation to furfuryl alcohol (FA) based on about 7 nm sized Pd−Cu alloy nanoparticles (NPs) formed in inexpensive, commercially available micro/mesoporous hypercrosslinked polystyrene (HPS). A comparison of the catalytic properties of as-synthesized and reduced (denoted “r”) catalysts as well as Pd−Cu alloy and monometallic palladium NPs showed a considerable enhancement of the catalytic performance of Pd−Cu/HPS-r compared to other catalysts studied, resulting in about 100 % FF conversion, 95.2 % selectivity for FA and a TOF of 1209 h−1. This was attributed to the enrichment of the NP surface with copper atoms, disrupting the furan ring adsorption, and to the presence of both zerovalent and cationic palladium and copper species, resulting in optimal hydrogen and FF adsorption. These factors along with exceptional stability of the catalyst in ten consecutive catalytic cycles make it highly promising in practical applications.",
keywords = "furfural, hydrogenation, hypercrosslinked polystyrene, nanostructures, Pd−Cu alloys, PALLADIUM, AQUEOUS-PHASE HYDROGENATION, CARBON, CONVERSION, COPPER, TETRAHYDROFURFURYL ALCOHOL, FACILE SYNTHESIS, REDUCTION, PROMISING PLATFORM, Pd-Cu alloys, EFFICIENT",
author = "Salnikova, {Ksenia E.} and Larichev, {Yurii V.} and Sulman, {Esther M.} and Bykov, {Alexey V.} and Sidorov, {Alexander I.} and Demidenko, {Galina N.} and Sulman, {Mikhail G.} and Bronstein, {Lyudmila M.} and Matveeva, {Valentina G.}",
note = "Publisher Copyright: {\textcopyright} 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = aug,
day = "1",
doi = "10.1002/cplu.202000383",
language = "English",
volume = "85",
pages = "1697--1703",
journal = "ChemPlusChem",
issn = "2192-6506",
publisher = "Wiley-VCH Verlag",
number = "8",

}

RIS

TY - JOUR

T1 - Selective Hydrogenation of Biomass-Derived Furfural

T2 - Enhanced Catalytic Performance of Pd−Cu Alloy Nanoparticles in Porous Polymer

AU - Salnikova, Ksenia E.

AU - Larichev, Yurii V.

AU - Sulman, Esther M.

AU - Bykov, Alexey V.

AU - Sidorov, Alexander I.

AU - Demidenko, Galina N.

AU - Sulman, Mikhail G.

AU - Bronstein, Lyudmila M.

AU - Matveeva, Valentina G.

N1 - Publisher Copyright: © 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/8/1

Y1 - 2020/8/1

N2 - Here, the development of a new catalyst is reported for the selective furfural (FF) hydrogenation to furfuryl alcohol (FA) based on about 7 nm sized Pd−Cu alloy nanoparticles (NPs) formed in inexpensive, commercially available micro/mesoporous hypercrosslinked polystyrene (HPS). A comparison of the catalytic properties of as-synthesized and reduced (denoted “r”) catalysts as well as Pd−Cu alloy and monometallic palladium NPs showed a considerable enhancement of the catalytic performance of Pd−Cu/HPS-r compared to other catalysts studied, resulting in about 100 % FF conversion, 95.2 % selectivity for FA and a TOF of 1209 h−1. This was attributed to the enrichment of the NP surface with copper atoms, disrupting the furan ring adsorption, and to the presence of both zerovalent and cationic palladium and copper species, resulting in optimal hydrogen and FF adsorption. These factors along with exceptional stability of the catalyst in ten consecutive catalytic cycles make it highly promising in practical applications.

AB - Here, the development of a new catalyst is reported for the selective furfural (FF) hydrogenation to furfuryl alcohol (FA) based on about 7 nm sized Pd−Cu alloy nanoparticles (NPs) formed in inexpensive, commercially available micro/mesoporous hypercrosslinked polystyrene (HPS). A comparison of the catalytic properties of as-synthesized and reduced (denoted “r”) catalysts as well as Pd−Cu alloy and monometallic palladium NPs showed a considerable enhancement of the catalytic performance of Pd−Cu/HPS-r compared to other catalysts studied, resulting in about 100 % FF conversion, 95.2 % selectivity for FA and a TOF of 1209 h−1. This was attributed to the enrichment of the NP surface with copper atoms, disrupting the furan ring adsorption, and to the presence of both zerovalent and cationic palladium and copper species, resulting in optimal hydrogen and FF adsorption. These factors along with exceptional stability of the catalyst in ten consecutive catalytic cycles make it highly promising in practical applications.

KW - furfural

KW - hydrogenation

KW - hypercrosslinked polystyrene

KW - nanostructures

KW - Pd−Cu alloys

KW - PALLADIUM

KW - AQUEOUS-PHASE HYDROGENATION

KW - CARBON

KW - CONVERSION

KW - COPPER

KW - TETRAHYDROFURFURYL ALCOHOL

KW - FACILE SYNTHESIS

KW - REDUCTION

KW - PROMISING PLATFORM

KW - Pd-Cu alloys

KW - EFFICIENT

UR - http://www.scopus.com/inward/record.url?scp=85087857332&partnerID=8YFLogxK

U2 - 10.1002/cplu.202000383

DO - 10.1002/cplu.202000383

M3 - Article

C2 - 32662952

AN - SCOPUS:85087857332

VL - 85

SP - 1697

EP - 1703

JO - ChemPlusChem

JF - ChemPlusChem

SN - 2192-6506

IS - 8

ER -

ID: 24767310