Secondary Coordination in the Structures of Zinc(II) and Manganese(II) Oxalatopalladates(II)

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Secondary Coordination in the Structures of Zinc(II) and Manganese(II) Oxalatopalladates(II). / Garkul, I. A.; Zadesenets, A. V.; Korolkov, I. V. et al.

In: Journal of Structural Chemistry, Vol. 61, No. 5, 6, 01.05.2020, p. 719-726.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{3dc16b44101d4e7bbcec59eb8bce777f,

title = "Secondary Coordination in the Structures of Zinc(II) and Manganese(II) Oxalatopalladates(II)",

abstract = "New coordination compounds, namely, zinc(II) dioxalatopalladate tetrahydrate [{Zn(H2O)3(Pd(C2O4)2)}2(μ-H2O)2]·4H2O and manganese(II) dioxalatopalladate monohydrate {(μ-C2O4)Pd(μ-C2O4)Mn(H2O)3}n·μH2O are synthesized. The compounds are characterized by IR spectroscopy, elemental analysis, and single crystal X-ray diffraction. The crystallographic data for the complex with Zn are as follows: a = 7.2812(4) {\AA}, b = 9.0258(5) {\AA}, c = 10.2468(6) {\AA}, a = 81.0335(1)°, β = 80.5341(2)°, γ = 75.9627(1)°, space group 1 ¯ , Z = 2, ρcafc = 2.367 g/cm3. The crystallographic data for the complex with Mn are as follows: a = 6.3605(4) {\AA}, b = 8.8464(5) {\AA}, c = 18.7382(1) {\AA}, β = 98.398(2)°, space group P21/c, Z = 2, ρcalc = 2.607 g/cm3. The complexes crystallize in different structural motifs: an oligomer in the case of Zn and a chain in the case of Mn. In both structures, oxalatopalladate(II) is coordinated by terminal oxygen atoms to the base metal.",

keywords = "manganese, oxalate complexes, palladium, single crystal X-ray diffraction, zinc, OXIDATION, PD(II), NITRATE, CRYSTAL-STRUCTURE, SINGLE-SOURCE PRECURSORS, CO, CO(II), NI(II), DOUBLE COMPLEX SALTS, FE",

author = "Garkul, {I. A.} and Zadesenets, {A. V.} and Korolkov, {I. V.} and Baidina, {I. A.} and Korenev, {S. V.}",

note = "Funding Information: The work was supported by RFBR (No. 17-03-00693a). Acknowledgments Publisher Copyright: {\textcopyright} 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2020",

month = may,

day = "1",

doi = "10.1134/S0022476620050078",

language = "English",

volume = "61",

pages = "719--726",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "5",

}

RIS

TY - JOUR

T1 - Secondary Coordination in the Structures of Zinc(II) and Manganese(II) Oxalatopalladates(II)

AU - Garkul, I. A.

AU - Zadesenets, A. V.

AU - Korolkov, I. V.

AU - Baidina, I. A.

AU - Korenev, S. V.

N1 - Funding Information: The work was supported by RFBR (No. 17-03-00693a). Acknowledgments Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/5/1

Y1 - 2020/5/1

N2 - New coordination compounds, namely, zinc(II) dioxalatopalladate tetrahydrate [{Zn(H2O)3(Pd(C2O4)2)}2(μ-H2O)2]·4H2O and manganese(II) dioxalatopalladate monohydrate {(μ-C2O4)Pd(μ-C2O4)Mn(H2O)3}n·μH2O are synthesized. The compounds are characterized by IR spectroscopy, elemental analysis, and single crystal X-ray diffraction. The crystallographic data for the complex with Zn are as follows: a = 7.2812(4) Å, b = 9.0258(5) Å, c = 10.2468(6) Å, a = 81.0335(1)°, β = 80.5341(2)°, γ = 75.9627(1)°, space group 1 ¯ , Z = 2, ρcafc = 2.367 g/cm3. The crystallographic data for the complex with Mn are as follows: a = 6.3605(4) Å, b = 8.8464(5) Å, c = 18.7382(1) Å, β = 98.398(2)°, space group P21/c, Z = 2, ρcalc = 2.607 g/cm3. The complexes crystallize in different structural motifs: an oligomer in the case of Zn and a chain in the case of Mn. In both structures, oxalatopalladate(II) is coordinated by terminal oxygen atoms to the base metal.

AB - New coordination compounds, namely, zinc(II) dioxalatopalladate tetrahydrate [{Zn(H2O)3(Pd(C2O4)2)}2(μ-H2O)2]·4H2O and manganese(II) dioxalatopalladate monohydrate {(μ-C2O4)Pd(μ-C2O4)Mn(H2O)3}n·μH2O are synthesized. The compounds are characterized by IR spectroscopy, elemental analysis, and single crystal X-ray diffraction. The crystallographic data for the complex with Zn are as follows: a = 7.2812(4) Å, b = 9.0258(5) Å, c = 10.2468(6) Å, a = 81.0335(1)°, β = 80.5341(2)°, γ = 75.9627(1)°, space group 1 ¯ , Z = 2, ρcafc = 2.367 g/cm3. The crystallographic data for the complex with Mn are as follows: a = 6.3605(4) Å, b = 8.8464(5) Å, c = 18.7382(1) Å, β = 98.398(2)°, space group P21/c, Z = 2, ρcalc = 2.607 g/cm3. The complexes crystallize in different structural motifs: an oligomer in the case of Zn and a chain in the case of Mn. In both structures, oxalatopalladate(II) is coordinated by terminal oxygen atoms to the base metal.

KW - manganese

KW - oxalate complexes

KW - palladium

KW - single crystal X-ray diffraction

KW - zinc

KW - OXIDATION

KW - PD(II)

KW - NITRATE

KW - CRYSTAL-STRUCTURE

KW - SINGLE-SOURCE PRECURSORS

KW - CO

KW - CO(II)

KW - NI(II)

KW - DOUBLE COMPLEX SALTS

KW - FE

UR - http://www.scopus.com/inward/record.url?scp=85089234855&partnerID=8YFLogxK

UR - https://elibrary.ru/item.asp?id=45372697

U2 - 10.1134/S0022476620050078

DO - 10.1134/S0022476620050078

M3 - Article

AN - SCOPUS:85089234855

VL - 61

SP - 719

EP - 726

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

M1 - 6

ER -

ID: 24954235