Standard

Samarocene oxide : From an undesired decomposition product to a new reagent. / Schoo, Christoph; Klementyeva, Svetlana V.; Gamer, Michael T. et al.

In: Chemical Communications, Vol. 52, No. 40, 2016, p. 6654-6657.

Research output: Contribution to journal › Article › peer-review

Harvard

Schoo, C, Klementyeva, SV, Gamer, MT, Konchenko, SN & Roesky, PW 2016, 'Samarocene oxide: From an undesired decomposition product to a new reagent', Chemical Communications, vol. 52, no. 40, pp. 6654-6657. https://doi.org/10.1039/c6cc02450e

APA

Schoo, C., Klementyeva, S. V., Gamer, M. T., Konchenko, S. N., & Roesky, P. W. (2016). Samarocene oxide: From an undesired decomposition product to a new reagent. Chemical Communications, 52(40), 6654-6657. https://doi.org/10.1039/c6cc02450e

Vancouver

Schoo C, Klementyeva SV, Gamer MT, Konchenko SN, Roesky PW. Samarocene oxide: From an undesired decomposition product to a new reagent. Chemical Communications. 2016;52(40):6654-6657. doi: 10.1039/c6cc02450e

Author

Schoo, Christoph ; Klementyeva, Svetlana V. ; Gamer, Michael T. et al. / Samarocene oxide : From an undesired decomposition product to a new reagent. In: Chemical Communications. 2016 ; Vol. 52, No. 40. pp. 6654-6657.

BibTeX

@article{1f251e2afa244078b89197f1056b075a,
title = "Samarocene oxide: From an undesired decomposition product to a new reagent",
abstract = "Samarocene oxide [Cp∗2Sm-O-SmCp∗2] is mostly considered as an undesired decomposition product of the well-established but highly air-sensitive samarocene, [Cp∗2Sm(thf)2]. [Cp∗2Sm-O-SmCp∗2] is often formed by accidental exposure of [Cp∗2Sm(thf)2] to air or wet solvents. We show here that [Cp∗2Sm-O-SmCp∗2] acts as a mild oxide base and thus is a valuable synthetic equivalent for {"}O2-{"}. The reaction of [Cp∗2Sm-O-SmCp∗2] with the inorganic and organic anhydrides COS, CS2, SO2, SO3, Re2O7, and (PhC(O))2O at room temperature resulted in each case in an O2- insertion. The corresponding products were isolated as their samarium complexes.",
author = "Christoph Schoo and Klementyeva, {Svetlana V.} and Gamer, {Michael T.} and Konchenko, {Sergey N.} and Roesky, {Peter W.}",
year = "2016",
doi = "10.1039/c6cc02450e",
language = "English",
volume = "52",
pages = "6654--6657",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "40",

}

RIS

TY - JOUR

T1 - Samarocene oxide

T2 - From an undesired decomposition product to a new reagent

AU - Schoo, Christoph

AU - Klementyeva, Svetlana V.

AU - Gamer, Michael T.

AU - Konchenko, Sergey N.

AU - Roesky, Peter W.

PY - 2016

Y1 - 2016

N2 - Samarocene oxide [Cp∗2Sm-O-SmCp∗2] is mostly considered as an undesired decomposition product of the well-established but highly air-sensitive samarocene, [Cp∗2Sm(thf)2]. [Cp∗2Sm-O-SmCp∗2] is often formed by accidental exposure of [Cp∗2Sm(thf)2] to air or wet solvents. We show here that [Cp∗2Sm-O-SmCp∗2] acts as a mild oxide base and thus is a valuable synthetic equivalent for "O2-". The reaction of [Cp∗2Sm-O-SmCp∗2] with the inorganic and organic anhydrides COS, CS2, SO2, SO3, Re2O7, and (PhC(O))2O at room temperature resulted in each case in an O2- insertion. The corresponding products were isolated as their samarium complexes.

AB - Samarocene oxide [Cp∗2Sm-O-SmCp∗2] is mostly considered as an undesired decomposition product of the well-established but highly air-sensitive samarocene, [Cp∗2Sm(thf)2]. [Cp∗2Sm-O-SmCp∗2] is often formed by accidental exposure of [Cp∗2Sm(thf)2] to air or wet solvents. We show here that [Cp∗2Sm-O-SmCp∗2] acts as a mild oxide base and thus is a valuable synthetic equivalent for "O2-". The reaction of [Cp∗2Sm-O-SmCp∗2] with the inorganic and organic anhydrides COS, CS2, SO2, SO3, Re2O7, and (PhC(O))2O at room temperature resulted in each case in an O2- insertion. The corresponding products were isolated as their samarium complexes.

UR - http://www.scopus.com/inward/record.url?scp=84969951905&partnerID=8YFLogxK

U2 - 10.1039/c6cc02450e

DO - 10.1039/c6cc02450e

M3 - Article

AN - SCOPUS:84969951905

VL - 52

SP - 6654

EP - 6657

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 40

ER -

ID: 25414166