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Salts of Sterically Hindered Chalcogen-Varied Herz Cations Including Those with [Te3Cl14]2– and [Te4Cl18]2– Anions. / Makarov, Alexander Yu; Bagryanskaya, Irina Yu; Volkova, Yulia M. et al.

In: European Journal of Inorganic Chemistry, Vol. 2018, No. 11, 22.03.2018, p. 1322-1332.

Research output: Contribution to journal › Article › peer-review

Harvard

Makarov, AY, Bagryanskaya, IY, Volkova, YM, Shakirov, MM & Zibarev, AV 2018, 'Salts of Sterically Hindered Chalcogen-Varied Herz Cations Including Those with [Te3Cl14]2– and [Te4Cl18]2– Anions', European Journal of Inorganic Chemistry, vol. 2018, no. 11, pp. 1322-1332. https://doi.org/10.1002/ejic.201701470

APA

Makarov, A. Y., Bagryanskaya, I. Y., Volkova, Y. M., Shakirov, M. M., & Zibarev, A. V. (2018). Salts of Sterically Hindered Chalcogen-Varied Herz Cations Including Those with [Te3Cl14]2– and [Te4Cl18]2– Anions. European Journal of Inorganic Chemistry, 2018(11), 1322-1332. https://doi.org/10.1002/ejic.201701470

Vancouver

Makarov AY, Bagryanskaya IY, Volkova YM, Shakirov MM, Zibarev AV. Salts of Sterically Hindered Chalcogen-Varied Herz Cations Including Those with [Te3Cl14]2– and [Te4Cl18]2– Anions. European Journal of Inorganic Chemistry. 2018 Mar 22;2018(11):1322-1332. doi: 10.1002/ejic.201701470

Author

Makarov, Alexander Yu ; Bagryanskaya, Irina Yu ; Volkova, Yulia M. et al. / Salts of Sterically Hindered Chalcogen-Varied Herz Cations Including Those with [Te3Cl14]2– and [Te4Cl18]2– Anions. In: European Journal of Inorganic Chemistry. 2018 ; Vol. 2018, No. 11. pp. 1322-1332.

BibTeX

@article{4ef9cf2ba6a94e8297f92bdeb35202ba,
title = "Salts of Sterically Hindered Chalcogen-Varied Herz Cations Including Those with [Te3Cl14]2– and [Te4Cl18]2– Anions",
abstract = "Salts of sterically hindered chalcogen-varied Herz cations with various anions were synthesized. 4,6-Di-tert-butyl-substituted 1,2,3-benzothiaselenazolium (2), 2,1,3-benzothiaselenazolium (3), and 1,2,3-benzodiselenazolium (4) were obtained from corresponding 1,2,3-benzodithiazolium (1) or 2-bromo-4,6-di-tert-butylaniline (9) and were isolated as salts with [Cl]– or/and [SbCl6]– anions. Reaction of in situ prepared N,N,Te-tris(trimethylsilyl)-2-amino-3,5-di-tert-butyltellurophenole with SeCl4, S2Cl2, and SOCl2 resulted in elimination of Te and the formation of [4]2[TeCl6], [1]2[Te3Cl14], and [1]2[Te4Cl18] together with N-sulfinyl-2-amino-3,5-di-tert-butylphenyltellurium trichloride (11); expected 2,1,3-benzothiatellurazolium (5) and 2,1,3-benzoselenatellurazolium (6) were not observed. Compounds [1][Cl] (solvate with CHCl3), [2][SbCl6], [3][SbCl6], [4][SbCl6], [4]2[TeCl6], [1]2[Te3Cl14], [1]2[Te4Cl18], and 11 were structurally defined by X-ray diffraction. All of the [SbCl6]– salts were isomorphous, and the [Te3Cl14]2– and [Te4Cl18]2– anions were previously unknown. Compound 11 has a significantly shortened intramolecular Te···O contact.",
keywords = "Anions, Herz salts, Heterocycles, Selenium, Tellurium",
author = "Makarov, {Alexander Yu} and Bagryanskaya, {Irina Yu} and Volkova, {Yulia M.} and Shakirov, {Makhmut M.} and Zibarev, {Andrey V.}",
year = "2018",
month = mar,
day = "22",
doi = "10.1002/ejic.201701470",
language = "English",
volume = "2018",
pages = "1322--1332",
journal = "European Journal of Inorganic Chemistry",
issn = "1434-1948",
publisher = "Wiley-VCH Verlag",
number = "11",

}

RIS

TY - JOUR

T1 - Salts of Sterically Hindered Chalcogen-Varied Herz Cations Including Those with [Te3Cl14]2– and [Te4Cl18]2– Anions

AU - Makarov, Alexander Yu

AU - Bagryanskaya, Irina Yu

AU - Volkova, Yulia M.

AU - Shakirov, Makhmut M.

AU - Zibarev, Andrey V.

PY - 2018/3/22

Y1 - 2018/3/22

N2 - Salts of sterically hindered chalcogen-varied Herz cations with various anions were synthesized. 4,6-Di-tert-butyl-substituted 1,2,3-benzothiaselenazolium (2), 2,1,3-benzothiaselenazolium (3), and 1,2,3-benzodiselenazolium (4) were obtained from corresponding 1,2,3-benzodithiazolium (1) or 2-bromo-4,6-di-tert-butylaniline (9) and were isolated as salts with [Cl]– or/and [SbCl6]– anions. Reaction of in situ prepared N,N,Te-tris(trimethylsilyl)-2-amino-3,5-di-tert-butyltellurophenole with SeCl4, S2Cl2, and SOCl2 resulted in elimination of Te and the formation of [4]2[TeCl6], [1]2[Te3Cl14], and [1]2[Te4Cl18] together with N-sulfinyl-2-amino-3,5-di-tert-butylphenyltellurium trichloride (11); expected 2,1,3-benzothiatellurazolium (5) and 2,1,3-benzoselenatellurazolium (6) were not observed. Compounds [1][Cl] (solvate with CHCl3), [2][SbCl6], [3][SbCl6], [4][SbCl6], [4]2[TeCl6], [1]2[Te3Cl14], [1]2[Te4Cl18], and 11 were structurally defined by X-ray diffraction. All of the [SbCl6]– salts were isomorphous, and the [Te3Cl14]2– and [Te4Cl18]2– anions were previously unknown. Compound 11 has a significantly shortened intramolecular Te···O contact.

AB - Salts of sterically hindered chalcogen-varied Herz cations with various anions were synthesized. 4,6-Di-tert-butyl-substituted 1,2,3-benzothiaselenazolium (2), 2,1,3-benzothiaselenazolium (3), and 1,2,3-benzodiselenazolium (4) were obtained from corresponding 1,2,3-benzodithiazolium (1) or 2-bromo-4,6-di-tert-butylaniline (9) and were isolated as salts with [Cl]– or/and [SbCl6]– anions. Reaction of in situ prepared N,N,Te-tris(trimethylsilyl)-2-amino-3,5-di-tert-butyltellurophenole with SeCl4, S2Cl2, and SOCl2 resulted in elimination of Te and the formation of [4]2[TeCl6], [1]2[Te3Cl14], and [1]2[Te4Cl18] together with N-sulfinyl-2-amino-3,5-di-tert-butylphenyltellurium trichloride (11); expected 2,1,3-benzothiatellurazolium (5) and 2,1,3-benzoselenatellurazolium (6) were not observed. Compounds [1][Cl] (solvate with CHCl3), [2][SbCl6], [3][SbCl6], [4][SbCl6], [4]2[TeCl6], [1]2[Te3Cl14], [1]2[Te4Cl18], and 11 were structurally defined by X-ray diffraction. All of the [SbCl6]– salts were isomorphous, and the [Te3Cl14]2– and [Te4Cl18]2– anions were previously unknown. Compound 11 has a significantly shortened intramolecular Te···O contact.

KW - Anions

KW - Herz salts

KW - Heterocycles

KW - Selenium

KW - Tellurium

UR - http://www.scopus.com/inward/record.url?scp=85044456195&partnerID=8YFLogxK

U2 - 10.1002/ejic.201701470

DO - 10.1002/ejic.201701470

M3 - Article

AN - SCOPUS:85044456195

VL - 2018

SP - 1322

EP - 1332

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 11

ER -

ID: 12214536