Standard

Room temperature synthesis of fluorinated graphite intercalation compounds with low fluorine loading of host matrix. / Chekhova, G. N.; Pinakov, D. V.; Shubin, Yu V. et al.

In: Journal of Fluorine Chemistry, Vol. 232, 109482, 04.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Chekhova, GN, Pinakov, DV, Shubin, YV, Fadeeva, VP, Tikhova, VD, Okotrub, AV & Bulusheva, LG 2020, 'Room temperature synthesis of fluorinated graphite intercalation compounds with low fluorine loading of host matrix', Journal of Fluorine Chemistry, vol. 232, 109482. https://doi.org/10.1016/j.jfluchem.2020.109482

APA

Chekhova, G. N., Pinakov, D. V., Shubin, Y. V., Fadeeva, V. P., Tikhova, V. D., Okotrub, A. V., & Bulusheva, L. G. (2020). Room temperature synthesis of fluorinated graphite intercalation compounds with low fluorine loading of host matrix. Journal of Fluorine Chemistry, 232, [109482]. https://doi.org/10.1016/j.jfluchem.2020.109482

Vancouver

Chekhova GN, Pinakov DV, Shubin YV, Fadeeva VP, Tikhova VD, Okotrub AV et al. Room temperature synthesis of fluorinated graphite intercalation compounds with low fluorine loading of host matrix. Journal of Fluorine Chemistry. 2020 Apr;232:109482. doi: 10.1016/j.jfluchem.2020.109482

Author

Chekhova, G. N. ; Pinakov, D. V. ; Shubin, Yu V. et al. / Room temperature synthesis of fluorinated graphite intercalation compounds with low fluorine loading of host matrix. In: Journal of Fluorine Chemistry. 2020 ; Vol. 232.

BibTeX

@article{3e54a2bf2fb342138fb2ed74c02531a3,
title = "Room temperature synthesis of fluorinated graphite intercalation compounds with low fluorine loading of host matrix",
abstract = "The interaction of graphite with a gaseous mixture of BrF3 and Br2 at room temperature produced fluorinated graphite intercalation compounds with bromine. By changing the concentration of BrF3 in Br2 from 6.2 to 2.9 % we were able to obtain matrices of fluorinated graphene layers (C2Fx)n with x = 0.76, 0.66, 0.35, 0.25. It was shown that bromine was completely replaced by acetonitrile in the (C2Fx)n with x > 0.6, while two types of guests (CH3CN and Br2) were present between the layers with the lower fluorine loading. The Van der Waals forces hold CH3CN molecules in the (C2Fx)n host. The interaction of Br2 molecules with sp2-carbon regions remained in the C2Fx layers has donor-acceptor type. The models of guest molecules packing in host matrices (C2Fx)n are considered using the data on the stoichiometry and X-ray diffraction analysis.",
keywords = "Acetonitrile, Bromine, Fluorinated graphite, guest–host interaction, Intercalation compounds, CARBON, OXIDE, INCLUSION-COMPOUNDS, GRAPHENE, LAYERS, CXF, NMR, guest-host interaction, ACETONITRILE",
author = "Chekhova, {G. N.} and Pinakov, {D. V.} and Shubin, {Yu V.} and Fadeeva, {V. P.} and Tikhova, {V. D.} and Okotrub, {A. V.} and Bulusheva, {L. G.}",
year = "2020",
month = apr,
doi = "10.1016/j.jfluchem.2020.109482",
language = "English",
volume = "232",
journal = "Journal of Fluorine Chemistry",
issn = "0022-1139",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Room temperature synthesis of fluorinated graphite intercalation compounds with low fluorine loading of host matrix

AU - Chekhova, G. N.

AU - Pinakov, D. V.

AU - Shubin, Yu V.

AU - Fadeeva, V. P.

AU - Tikhova, V. D.

AU - Okotrub, A. V.

AU - Bulusheva, L. G.

PY - 2020/4

Y1 - 2020/4

N2 - The interaction of graphite with a gaseous mixture of BrF3 and Br2 at room temperature produced fluorinated graphite intercalation compounds with bromine. By changing the concentration of BrF3 in Br2 from 6.2 to 2.9 % we were able to obtain matrices of fluorinated graphene layers (C2Fx)n with x = 0.76, 0.66, 0.35, 0.25. It was shown that bromine was completely replaced by acetonitrile in the (C2Fx)n with x > 0.6, while two types of guests (CH3CN and Br2) were present between the layers with the lower fluorine loading. The Van der Waals forces hold CH3CN molecules in the (C2Fx)n host. The interaction of Br2 molecules with sp2-carbon regions remained in the C2Fx layers has donor-acceptor type. The models of guest molecules packing in host matrices (C2Fx)n are considered using the data on the stoichiometry and X-ray diffraction analysis.

AB - The interaction of graphite with a gaseous mixture of BrF3 and Br2 at room temperature produced fluorinated graphite intercalation compounds with bromine. By changing the concentration of BrF3 in Br2 from 6.2 to 2.9 % we were able to obtain matrices of fluorinated graphene layers (C2Fx)n with x = 0.76, 0.66, 0.35, 0.25. It was shown that bromine was completely replaced by acetonitrile in the (C2Fx)n with x > 0.6, while two types of guests (CH3CN and Br2) were present between the layers with the lower fluorine loading. The Van der Waals forces hold CH3CN molecules in the (C2Fx)n host. The interaction of Br2 molecules with sp2-carbon regions remained in the C2Fx layers has donor-acceptor type. The models of guest molecules packing in host matrices (C2Fx)n are considered using the data on the stoichiometry and X-ray diffraction analysis.

KW - Acetonitrile

KW - Bromine

KW - Fluorinated graphite

KW - guest–host interaction

KW - Intercalation compounds

KW - CARBON

KW - OXIDE

KW - INCLUSION-COMPOUNDS

KW - GRAPHENE

KW - LAYERS

KW - CXF

KW - NMR

KW - guest-host interaction

KW - ACETONITRILE

UR - http://www.scopus.com/inward/record.url?scp=85079146324&partnerID=8YFLogxK

U2 - 10.1016/j.jfluchem.2020.109482

DO - 10.1016/j.jfluchem.2020.109482

M3 - Article

AN - SCOPUS:85079146324

VL - 232

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

SN - 0022-1139

M1 - 109482

ER -

ID: 23424334