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Role of Bridging Na+ Cations in the Packing of Na2[Pd(NH3)4]5(W7O24)2·16H2O and Na[Pd(NH3)4]2(HW7O24)·7H2O Structures. / Khranenko, S. P.; Sukhikh, A. S.; Gromilov, S. A.

In: Journal of Structural Chemistry, Vol. 61, No. 2, 01.02.2020, p. 293-298.

Research output: Contribution to journal › Article › peer-review

Harvard

Khranenko, SP, Sukhikh, AS & Gromilov, SA 2020, 'Role of Bridging Na+ Cations in the Packing of Na2[Pd(NH3)4]5(W7O24)2·16H2O and Na[Pd(NH3)4]2(HW7O24)·7H2O Structures', Journal of Structural Chemistry, vol. 61, no. 2, pp. 293-298. https://doi.org/10.1134/S0022476620020146

APA

Khranenko, S. P., Sukhikh, A. S., & Gromilov, S. A. (2020). Role of Bridging Na+ Cations in the Packing of Na2[Pd(NH3)4]5(W7O24)2·16H2O and Na[Pd(NH3)4]2(HW7O24)·7H2O Structures. Journal of Structural Chemistry, 61(2), 293-298. https://doi.org/10.1134/S0022476620020146

Vancouver

Khranenko SP, Sukhikh AS, Gromilov SA. Role of Bridging Na+ Cations in the Packing of Na2[Pd(NH3)4]5(W7O24)2·16H2O and Na[Pd(NH3)4]2(HW7O24)·7H2O Structures. Journal of Structural Chemistry. 2020 Feb 1;61(2):293-298. doi: 10.1134/S0022476620020146

Author

Khranenko, S. P. ; Sukhikh, A. S. ; Gromilov, S. A. / Role of Bridging Na+ Cations in the Packing of Na2[Pd(NH3)4]5(W7O24)2·16H2O and Na[Pd(NH3)4]2(HW7O24)·7H2O Structures. In: Journal of Structural Chemistry. 2020 ; Vol. 61, No. 2. pp. 293-298.

BibTeX

@article{a8d0994e5f4540f2ac14b20753d3520d,
title = "Role of Bridging Na+ Cations in the Packing of Na2[Pd(NH3)4]5(W7O24)2·16H2O and Na[Pd(NH3)4]2(HW7O24)·7H2O Structures",
abstract = "Two complex salts with heptatungstate anions and [Pd(NH3)4]2+ and Na+ cations are synthesized. In the structure of Na2[Pd(NH3)]5(W7O24)2·16H2O (a = 11.5703(3) {\AA}, b = 12.4653(4) {\AA}, c = 14.8201(5) {\AA}, α = 69.733(1)°, β = 97.231(1)°, γ = 75.816(1)°, space group P-1, V = 1937.8(1) {\AA}3, Z = 1), the Na+ cations link heptatungstate anions into dimers; the Na…O distances are 2.321–2.446 {\AA}. In the structure of Na[Pd(NH3)4]2(HW7O24)·7H2O (a = 11.1113(8) {\AA}, b = 17.9869(12) {\AA}, c = 17.8140(13) {\AA}, β = 96.974(2)°, space group P21/n, V = 3533.9(4) {\AA}3, Z = 4), the bridging Na+ cations link hydroheptatungstate anions into zigzag chains; the Na…O distances are 2.291–2.724 {\AA}.",
keywords = "complex salt, crystal chemistry, heptatungstate anion, palladium tetrammine, X-ray diffraction analysis, CRYSTAL-STRUCTURE",
author = "Khranenko, {S. P.} and Sukhikh, {A. S.} and Gromilov, {S. A.}",
year = "2020",
month = feb,
day = "1",
doi = "10.1134/S0022476620020146",
language = "English",
volume = "61",
pages = "293--298",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "2",

}

RIS

TY - JOUR

T1 - Role of Bridging Na+ Cations in the Packing of Na2[Pd(NH3)4]5(W7O24)2·16H2O and Na[Pd(NH3)4]2(HW7O24)·7H2O Structures

AU - Khranenko, S. P.

AU - Sukhikh, A. S.

AU - Gromilov, S. A.

PY - 2020/2/1

Y1 - 2020/2/1

N2 - Two complex salts with heptatungstate anions and [Pd(NH3)4]2+ and Na+ cations are synthesized. In the structure of Na2[Pd(NH3)]5(W7O24)2·16H2O (a = 11.5703(3) Å, b = 12.4653(4) Å, c = 14.8201(5) Å, α = 69.733(1)°, β = 97.231(1)°, γ = 75.816(1)°, space group P-1, V = 1937.8(1) Å3, Z = 1), the Na+ cations link heptatungstate anions into dimers; the Na…O distances are 2.321–2.446 Å. In the structure of Na[Pd(NH3)4]2(HW7O24)·7H2O (a = 11.1113(8) Å, b = 17.9869(12) Å, c = 17.8140(13) Å, β = 96.974(2)°, space group P21/n, V = 3533.9(4) Å3, Z = 4), the bridging Na+ cations link hydroheptatungstate anions into zigzag chains; the Na…O distances are 2.291–2.724 Å.

AB - Two complex salts with heptatungstate anions and [Pd(NH3)4]2+ and Na+ cations are synthesized. In the structure of Na2[Pd(NH3)]5(W7O24)2·16H2O (a = 11.5703(3) Å, b = 12.4653(4) Å, c = 14.8201(5) Å, α = 69.733(1)°, β = 97.231(1)°, γ = 75.816(1)°, space group P-1, V = 1937.8(1) Å3, Z = 1), the Na+ cations link heptatungstate anions into dimers; the Na…O distances are 2.321–2.446 Å. In the structure of Na[Pd(NH3)4]2(HW7O24)·7H2O (a = 11.1113(8) Å, b = 17.9869(12) Å, c = 17.8140(13) Å, β = 96.974(2)°, space group P21/n, V = 3533.9(4) Å3, Z = 4), the bridging Na+ cations link hydroheptatungstate anions into zigzag chains; the Na…O distances are 2.291–2.724 Å.

KW - complex salt

KW - crystal chemistry

KW - heptatungstate anion

KW - palladium tetrammine

KW - X-ray diffraction analysis

KW - CRYSTAL-STRUCTURE

UR - http://www.scopus.com/inward/record.url?scp=85087942007&partnerID=8YFLogxK

U2 - 10.1134/S0022476620020146

DO - 10.1134/S0022476620020146

M3 - Article

AN - SCOPUS:85087942007

VL - 61

SP - 293

EP - 298

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -

ID: 24753218