Research output: Contribution to journal › Article › peer-review
Redox Processes in Reduced Graphite Oxide Decorated by Carboxyl Functional Groups. / Kobets, Anna A.; Iurchenkova, Anna A.; Asanov, Igor P. et al.
In: Physica Status Solidi (B) Basic Research, Vol. 256, No. 9, 1800700, 01.09.2019.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Redox Processes in Reduced Graphite Oxide Decorated by Carboxyl Functional Groups
AU - Kobets, Anna A.
AU - Iurchenkova, Anna A.
AU - Asanov, Igor P.
AU - Okotrub, Aleksander V.
AU - Fedorovskaya, Ekaterina O.
PY - 2019/9/1
Y1 - 2019/9/1
N2 - The reduction of graphite oxide makes it possible to obtain a graphene material with a developed surface, high conductivity and remarkable electrochemical behavior. The study of the electrochemical activity of oxygen-containing functional groups on the graphene surface is important for the creation of electrochemical energy sources and sensors. In this work, the reduced graphite oxide is selectively decorated by carboxyl functional groups. The initial and carboxylated reduced graphite oxide are studied by SEM microscopy, FTIR, Raman, and X-ray photoelectron spectroscopy. It is shown that a large number of carboxyl groups added to reduced graphite oxide surface change the sample morphology. Studying of reduced graphite oxide and carboxylated reduced graphite oxide by cyclic voltammetry shows reversible redox processes, which is associated with oxidation and reduction of the hydroxyl, carbonyl, and carboxyl groups. In addition, the dependence of peak potentials on the pH value is studied.
AB - The reduction of graphite oxide makes it possible to obtain a graphene material with a developed surface, high conductivity and remarkable electrochemical behavior. The study of the electrochemical activity of oxygen-containing functional groups on the graphene surface is important for the creation of electrochemical energy sources and sensors. In this work, the reduced graphite oxide is selectively decorated by carboxyl functional groups. The initial and carboxylated reduced graphite oxide are studied by SEM microscopy, FTIR, Raman, and X-ray photoelectron spectroscopy. It is shown that a large number of carboxyl groups added to reduced graphite oxide surface change the sample morphology. Studying of reduced graphite oxide and carboxylated reduced graphite oxide by cyclic voltammetry shows reversible redox processes, which is associated with oxidation and reduction of the hydroxyl, carbonyl, and carboxyl groups. In addition, the dependence of peak potentials on the pH value is studied.
KW - cyclic voltammetry
KW - graphene functionalization
KW - oxygen-containing functional groups
KW - reduced graphite oxide
KW - X-ray photoelectron spectroscopy
KW - GRAPHENE OXIDE
KW - ELECTROCHEMICAL PROPERTIES
KW - CHEMICAL-REDUCTION
KW - PERFORMANCE
KW - RAMAN-SPECTROSCOPY
KW - SULFUR
KW - FILMS
KW - NANOTUBES
KW - ELECTRODE
KW - FABRICATION
UR - http://www.scopus.com/inward/record.url?scp=85062726443&partnerID=8YFLogxK
U2 - 10.1002/pssb.201800700
DO - 10.1002/pssb.201800700
M3 - Article
AN - SCOPUS:85062726443
VL - 256
JO - Physica Status Solidi (B): Basic Research
JF - Physica Status Solidi (B): Basic Research
SN - 0370-1972
IS - 9
M1 - 1800700
ER -
ID: 18815448