Research output: Contribution to journal › Article › peer-review
Redetermination of the crystal structure of the 2D heterometallic framework prepared from [Ni(cyclam)]2+ and [Re(CN)7]3-. / Sukhikh, Taisiya S.; Vostrikova, Kira E.
In: Journal of Solid State Chemistry, Vol. 258, 01.02.2018, p. 485-487.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Redetermination of the crystal structure of the 2D heterometallic framework prepared from [Ni(cyclam)]2+ and [Re(CN)7]3-
AU - Sukhikh, Taisiya S.
AU - Vostrikova, Kira E.
PY - 2018/2/1
Y1 - 2018/2/1
N2 - A new XRD experiment and crystal structure refinement was performed for the earlier published compound in the paper “Heterobimetallic coordination polymers involving 3d metal complexes and heavier transition metals cyanometallates” by Peresypkina et al. (2015) [1]. A choice of a crystal cell taking in consideration the superstructural reflections allowed to obtain more reliable data about the symmetry and bond distances in the heterometallic 2D framework {[Ni(cyclam)]2[ReO(OH)0.5(MeOH)0.5(CN)4]}2.5+. Additionally, doubling of the parameter c permitted to get more details about interlayer space. As a result, disordered perchlorate anions and solvate molecules were located.
AB - A new XRD experiment and crystal structure refinement was performed for the earlier published compound in the paper “Heterobimetallic coordination polymers involving 3d metal complexes and heavier transition metals cyanometallates” by Peresypkina et al. (2015) [1]. A choice of a crystal cell taking in consideration the superstructural reflections allowed to obtain more reliable data about the symmetry and bond distances in the heterometallic 2D framework {[Ni(cyclam)]2[ReO(OH)0.5(MeOH)0.5(CN)4]}2.5+. Additionally, doubling of the parameter c permitted to get more details about interlayer space. As a result, disordered perchlorate anions and solvate molecules were located.
KW - 2D coordination polymer
KW - Crystal structure
KW - Cyclam
KW - Heptacyanorhenate
KW - Nickel(II)
KW - Rhenium
UR - http://www.scopus.com/inward/record.url?scp=85034743681&partnerID=8YFLogxK
U2 - 10.1016/j.jssc.2017.11.016
DO - 10.1016/j.jssc.2017.11.016
M3 - Article
AN - SCOPUS:85034743681
VL - 258
SP - 485
EP - 487
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
ER -
ID: 9161037