Standard

Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n : Synthesis, Supramolecular Structures, and Thermal Behavior. / Korneeva, E. V.; Loseva, O. V.; Smolentsev, A. I. et al.

In: Russian Journal of General Chemistry, Vol. 88, No. 8, 01.08.2018, p. 1681-1689.

Research output: Contribution to journal › Article › peer-review

Harvard

Korneeva, EV, Loseva, OV, Smolentsev, AI & Ivanov, AV 2018, 'Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n: Synthesis, Supramolecular Structures, and Thermal Behavior', Russian Journal of General Chemistry, vol. 88, no. 8, pp. 1681-1689. https://doi.org/10.1134/S1070363218080200

APA

Korneeva, E. V., Loseva, O. V., Smolentsev, A. I., & Ivanov, A. V. (2018). Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n: Synthesis, Supramolecular Structures, and Thermal Behavior. Russian Journal of General Chemistry, 88(8), 1681-1689. https://doi.org/10.1134/S1070363218080200

Vancouver

Korneeva EV, Loseva OV, Smolentsev AI, Ivanov AV. Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n: Synthesis, Supramolecular Structures, and Thermal Behavior. Russian Journal of General Chemistry. 2018 Aug 1;88(8):1681-1689. doi: 10.1134/S1070363218080200

Author

Korneeva, E. V. ; Loseva, O. V. ; Smolentsev, A. I. et al. / Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n : Synthesis, Supramolecular Structures, and Thermal Behavior. In: Russian Journal of General Chemistry. 2018 ; Vol. 88, No. 8. pp. 1681-1689.

BibTeX

@article{b0a439358ede461bb6d5a8105347167f,
title = "Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n: Synthesis, Supramolecular Structures, and Thermal Behavior",
abstract = "New ion polymeric gold(III)–silver(I) complexes, {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n have been synthesized and characterized by X-ray diffraction data and IR spectra. The structure of the first complex is represented by [Au{S2CNEt2}2]+ complex cations and polymeric silver chloride anion ([AgCl2]–)n; the second complex consists of isomeric cations, linear [AgCl2]– anions, chloride ions, and water molecules. Gold cations are involved in zigzag (AuAuAu angle 99.06°) and linear polymeric chains via secondary Au···S bond pairs. Thermal decomposition of the complexes with regeneration of gold and silver has been studied by simultaneous thermal analysis (STA).",
keywords = "gold(III)–silver(I) complexes, ion polymeric complexes, ligand exchange, Silver(I) dithiocarbamates, supramolecular self-organization, HETEROPOLYNUCLEAR COMPLEX, HEXAMER, CHEMISORPTION, ISO-C3H7, MOLECULAR-STRUCTURE, CRYSTAL-STRUCTURE, ANTIBACTERIAL, SELF-ORGANIZATION, ANTITUMOR-ACTIVITY, gold(III)-silver(I) complexes, GOLD(III)",
author = "Korneeva, {E. V.} and Loseva, {O. V.} and Smolentsev, {A. I.} and Ivanov, {A. V.}",
year = "2018",
month = aug,
day = "1",
doi = "10.1134/S1070363218080200",
language = "English",
volume = "88",
pages = "1681--1689",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "8",

}

RIS

TY - JOUR

T1 - Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n

T2 - Synthesis, Supramolecular Structures, and Thermal Behavior

AU - Korneeva, E. V.

AU - Loseva, O. V.

AU - Smolentsev, A. I.

AU - Ivanov, A. V.

PY - 2018/8/1

Y1 - 2018/8/1

N2 - New ion polymeric gold(III)–silver(I) complexes, {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n have been synthesized and characterized by X-ray diffraction data and IR spectra. The structure of the first complex is represented by [Au{S2CNEt2}2]+ complex cations and polymeric silver chloride anion ([AgCl2]–)n; the second complex consists of isomeric cations, linear [AgCl2]– anions, chloride ions, and water molecules. Gold cations are involved in zigzag (AuAuAu angle 99.06°) and linear polymeric chains via secondary Au···S bond pairs. Thermal decomposition of the complexes with regeneration of gold and silver has been studied by simultaneous thermal analysis (STA).

AB - New ion polymeric gold(III)–silver(I) complexes, {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n have been synthesized and characterized by X-ray diffraction data and IR spectra. The structure of the first complex is represented by [Au{S2CNEt2}2]+ complex cations and polymeric silver chloride anion ([AgCl2]–)n; the second complex consists of isomeric cations, linear [AgCl2]– anions, chloride ions, and water molecules. Gold cations are involved in zigzag (AuAuAu angle 99.06°) and linear polymeric chains via secondary Au···S bond pairs. Thermal decomposition of the complexes with regeneration of gold and silver has been studied by simultaneous thermal analysis (STA).

KW - gold(III)–silver(I) complexes

KW - ion polymeric complexes

KW - ligand exchange

KW - Silver(I) dithiocarbamates

KW - supramolecular self-organization

KW - HETEROPOLYNUCLEAR COMPLEX

KW - HEXAMER

KW - CHEMISORPTION

KW - ISO-C3H7

KW - MOLECULAR-STRUCTURE

KW - CRYSTAL-STRUCTURE

KW - ANTIBACTERIAL

KW - SELF-ORGANIZATION

KW - ANTITUMOR-ACTIVITY

KW - gold(III)-silver(I) complexes

KW - GOLD(III)

UR - http://www.scopus.com/inward/record.url?scp=85055952339&partnerID=8YFLogxK

U2 - 10.1134/S1070363218080200

DO - 10.1134/S1070363218080200

M3 - Article

AN - SCOPUS:85055952339

VL - 88

SP - 1681

EP - 1689

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 8

ER -

ID: 17303134