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Reactions of [Ru(NO)Cl5]2- with pseudotrilacunary {XW9O33}9- (X = AsIII, SbIII) anions. / Mukhacheva, Anna A.; Shmakova, Alexandra A.; Volchek, Victoria V. et al.

In: Dalton Transactions, Vol. 48, No. 42, 14.11.2019, p. 15989-15999.

Research output: Contribution to journal › Article › peer-review

Harvard

Mukhacheva, AA, Shmakova, AA, Volchek, VV, Romanova, TE, Benassi, E, Gushchin, AL, Yanshole, V, Sheven, DG, Kompankov, NB, Abramov, PA & Sokolov, MN 2019, 'Reactions of [Ru(NO)Cl5]2- with pseudotrilacunary {XW9O33}9- (X = AsIII, SbIII) anions', Dalton Transactions, vol. 48, no. 42, pp. 15989-15999. https://doi.org/10.1039/c9dt03328a

APA

Mukhacheva, A. A., Shmakova, A. A., Volchek, V. V., Romanova, T. E., Benassi, E., Gushchin, A. L., Yanshole, V., Sheven, D. G., Kompankov, N. B., Abramov, P. A., & Sokolov, M. N. (2019). Reactions of [Ru(NO)Cl5]2- with pseudotrilacunary {XW9O33}9- (X = AsIII, SbIII) anions. Dalton Transactions, 48(42), 15989-15999. https://doi.org/10.1039/c9dt03328a

Vancouver

Mukhacheva AA, Shmakova AA, Volchek VV, Romanova TE, Benassi E, Gushchin AL et al. Reactions of [Ru(NO)Cl5]2- with pseudotrilacunary {XW9O33}9- (X = AsIII, SbIII) anions. Dalton Transactions. 2019 Nov 14;48(42):15989-15999. doi: 10.1039/c9dt03328a

Author

Mukhacheva, Anna A. ; Shmakova, Alexandra A. ; Volchek, Victoria V. et al. / Reactions of [Ru(NO)Cl5]2- with pseudotrilacunary {XW9O33}9- (X = AsIII, SbIII) anions. In: Dalton Transactions. 2019 ; Vol. 48, No. 42. pp. 15989-15999.

BibTeX

@article{4b8d48abd2bf41d9b81a2735eb08b893,
title = "Reactions of [Ru(NO)Cl5]2- with pseudotrilacunary {XW9O33}9- (X = AsIII, SbIII) anions",
abstract = "Reactions of [Ru(NO)Cl5]2- with pseudotrivacant B-α-[XW9O33]9- (X = AsIII, SbIII) at 160 °C result in the rearrangement of polyoxometalate backbones into {XM18} structures. In the case of arsenic, oxidation of AsIII to AsV takes place with the formation of a mixture of plenary and monosubstituted Dawson [As2W18O62]6- and [As2W17Ru(NO)O61]7- anions, of which the latter was isolated as Me2NH2+ (DMA-1a and DMA-1b) and Bu4N+ (Bu4N-1) salts and fully characterized. Both α1 and α2 isomers of [As2W17Ru(NO)O61]7- were present in the reaction mixture; pure [α2-As2W17Ru(NO)O61]7- was isolated as the Bu4N+ salt. In the case of antimony, [SbW9O33]9- is converted into a mixture of [SbW18O60]9- and [SbW17{Ru(NO)}O59]10-. The formation of trisubstituted [SbW15{Ru(NO)}3O57]12- as a minor byproduct was detected by HPLC-ICP-AES. The monosubstituted [SbW17{Ru(NO)}O59]10- anion was isolated as DMAH+ (DMA-2) and mixed inorganic cation (CsKNa-2) salts and characterized by XRD, HPLC-ICP-AES, EA and TGA techniques. X-ray analysis shows the presence of the {Ru(NO)}-group in the 6-membered ({"}equatorial{"}) belt of the Sb-free hemisphere. The experimental findings were confirmed and interpreted by means of quantum chemical calculations.",
keywords = "WATER OXIDATION, STRUCTURAL-CHARACTERIZATION, ORGANOMETALLIC DERIVATIVES, ELECTROCHEMICAL-BEHAVIOR, PHOTOREDOX CHEMISTRY, GAMMA-CYCLODEXTRIN, CATALYTIC-ACTIVITY, AQUEOUS-SOLUTION, KEGGIN STRUCTURE, NOBLE-METALS",
author = "Mukhacheva, {Anna A.} and Shmakova, {Alexandra A.} and Volchek, {Victoria V.} and Romanova, {Tamara E.} and Enrico Benassi and Gushchin, {Artem L.} and Vadim Yanshole and Sheven, {Dmitri G.} and Kompankov, {Nikolay B.} and Abramov, {Pavel A.} and Sokolov, {Maxim N.}",
year = "2019",
month = nov,
day = "14",
doi = "10.1039/c9dt03328a",
language = "English",
volume = "48",
pages = "15989--15999",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "42",

}

RIS

TY - JOUR

T1 - Reactions of [Ru(NO)Cl5]2- with pseudotrilacunary {XW9O33}9- (X = AsIII, SbIII) anions

AU - Mukhacheva, Anna A.

AU - Shmakova, Alexandra A.

AU - Volchek, Victoria V.

AU - Romanova, Tamara E.

AU - Benassi, Enrico

AU - Gushchin, Artem L.

AU - Yanshole, Vadim

AU - Sheven, Dmitri G.

AU - Kompankov, Nikolay B.

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

PY - 2019/11/14

Y1 - 2019/11/14

N2 - Reactions of [Ru(NO)Cl5]2- with pseudotrivacant B-α-[XW9O33]9- (X = AsIII, SbIII) at 160 °C result in the rearrangement of polyoxometalate backbones into {XM18} structures. In the case of arsenic, oxidation of AsIII to AsV takes place with the formation of a mixture of plenary and monosubstituted Dawson [As2W18O62]6- and [As2W17Ru(NO)O61]7- anions, of which the latter was isolated as Me2NH2+ (DMA-1a and DMA-1b) and Bu4N+ (Bu4N-1) salts and fully characterized. Both α1 and α2 isomers of [As2W17Ru(NO)O61]7- were present in the reaction mixture; pure [α2-As2W17Ru(NO)O61]7- was isolated as the Bu4N+ salt. In the case of antimony, [SbW9O33]9- is converted into a mixture of [SbW18O60]9- and [SbW17{Ru(NO)}O59]10-. The formation of trisubstituted [SbW15{Ru(NO)}3O57]12- as a minor byproduct was detected by HPLC-ICP-AES. The monosubstituted [SbW17{Ru(NO)}O59]10- anion was isolated as DMAH+ (DMA-2) and mixed inorganic cation (CsKNa-2) salts and characterized by XRD, HPLC-ICP-AES, EA and TGA techniques. X-ray analysis shows the presence of the {Ru(NO)}-group in the 6-membered ("equatorial") belt of the Sb-free hemisphere. The experimental findings were confirmed and interpreted by means of quantum chemical calculations.

AB - Reactions of [Ru(NO)Cl5]2- with pseudotrivacant B-α-[XW9O33]9- (X = AsIII, SbIII) at 160 °C result in the rearrangement of polyoxometalate backbones into {XM18} structures. In the case of arsenic, oxidation of AsIII to AsV takes place with the formation of a mixture of plenary and monosubstituted Dawson [As2W18O62]6- and [As2W17Ru(NO)O61]7- anions, of which the latter was isolated as Me2NH2+ (DMA-1a and DMA-1b) and Bu4N+ (Bu4N-1) salts and fully characterized. Both α1 and α2 isomers of [As2W17Ru(NO)O61]7- were present in the reaction mixture; pure [α2-As2W17Ru(NO)O61]7- was isolated as the Bu4N+ salt. In the case of antimony, [SbW9O33]9- is converted into a mixture of [SbW18O60]9- and [SbW17{Ru(NO)}O59]10-. The formation of trisubstituted [SbW15{Ru(NO)}3O57]12- as a minor byproduct was detected by HPLC-ICP-AES. The monosubstituted [SbW17{Ru(NO)}O59]10- anion was isolated as DMAH+ (DMA-2) and mixed inorganic cation (CsKNa-2) salts and characterized by XRD, HPLC-ICP-AES, EA and TGA techniques. X-ray analysis shows the presence of the {Ru(NO)}-group in the 6-membered ("equatorial") belt of the Sb-free hemisphere. The experimental findings were confirmed and interpreted by means of quantum chemical calculations.

KW - WATER OXIDATION

KW - STRUCTURAL-CHARACTERIZATION

KW - ORGANOMETALLIC DERIVATIVES

KW - ELECTROCHEMICAL-BEHAVIOR

KW - PHOTOREDOX CHEMISTRY

KW - GAMMA-CYCLODEXTRIN

KW - CATALYTIC-ACTIVITY

KW - AQUEOUS-SOLUTION

KW - KEGGIN STRUCTURE

KW - NOBLE-METALS

UR - http://www.scopus.com/inward/record.url?scp=85074243519&partnerID=8YFLogxK

U2 - 10.1039/c9dt03328a

DO - 10.1039/c9dt03328a

M3 - Article

C2 - 31595900

AN - SCOPUS:85074243519

VL - 48

SP - 15989

EP - 15999

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 42

ER -

ID: 22087742