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Reaction of K2[Ru(NO)Cl5] with K8[γ-SiW10O36] Under Hydrothermal Conditions : Synthesis of [SiW11O39{Ru(NO)}]5–. / Shmakova, A. A.; Volchek, V. V.; Abramov, P. A. et al.

In: Journal of Structural Chemistry, Vol. 59, No. 6, 01.11.2018, p. 1427-1432.

Research output: Contribution to journal › Article › peer-review

Harvard

Shmakova, AA, Volchek, VV, Abramov, PA & Sokolov, MN 2018, 'Reaction of K2[Ru(NO)Cl5] with K8[γ-SiW10O36] Under Hydrothermal Conditions: Synthesis of [SiW11O39{Ru(NO)}]5–', Journal of Structural Chemistry, vol. 59, no. 6, pp. 1427-1432. https://doi.org/10.1134/S0022476618060252

APA

Shmakova, A. A., Volchek, V. V., Abramov, P. A., & Sokolov, M. N. (2018). Reaction of K2[Ru(NO)Cl5] with K8[γ-SiW10O36] Under Hydrothermal Conditions: Synthesis of [SiW11O39{Ru(NO)}]5–. Journal of Structural Chemistry, 59(6), 1427-1432. https://doi.org/10.1134/S0022476618060252

Vancouver

Shmakova AA, Volchek VV, Abramov PA, Sokolov MN. Reaction of K2[Ru(NO)Cl5] with K8[γ-SiW10O36] Under Hydrothermal Conditions: Synthesis of [SiW11O39{Ru(NO)}]5–. Journal of Structural Chemistry. 2018 Nov 1;59(6):1427-1432. doi: 10.1134/S0022476618060252

Author

Shmakova, A. A. ; Volchek, V. V. ; Abramov, P. A. et al. / Reaction of K2[Ru(NO)Cl5] with K8[γ-SiW10O36] Under Hydrothermal Conditions : Synthesis of [SiW11O39{Ru(NO)}]5–. In: Journal of Structural Chemistry. 2018 ; Vol. 59, No. 6. pp. 1427-1432.

BibTeX

@article{7c9f9120131b49c5ae601eb2e709add5,
title = "Reaction of K2[Ru(NO)Cl5] with K8[γ-SiW10O36] Under Hydrothermal Conditions: Synthesis of [SiW11O39{Ru(NO)}]5–",
abstract = "The thermostating of an aqueous solution of K2[Ru(NO)Cl5] and K8[γ-SiW10O36] at 160 °С for 16 h leads to a change in the color of the solution from pink to brown. According to the HPLC-ICP-AES data, the reaction products are Keggin anions: [SiW11O39{Ru(NO)}]5– (1) and [SiW12O40]4– (2). The formation of 1 and 2 is demonstrated by mass spectrometry for tetrabutylammonium salts in an acetonitrile solution. Red crystals of the composition ((CH3)2NH2)4H[α-SiW11O39{Ru(NO)}]·6H2O (1а) are obtained by fractional crystallization of dimethylammonium salts.",
keywords = "crystal structure, Keggin anion, ruthenium, NMR, POLYOXOTUNGSTATES, HETEROPOLYANIONS, POLYOXOMETALATE, RUTHENIUM",
author = "Shmakova, {A. A.} and Volchek, {V. V.} and Abramov, {P. A.} and Sokolov, {M. N.}",
note = "Publisher Copyright: {\textcopyright} 2018, Pleiades Publishing, Ltd.",
year = "2018",
month = nov,
day = "1",
doi = "10.1134/S0022476618060252",
language = "English",
volume = "59",
pages = "1427--1432",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "6",

}

RIS

TY - JOUR

T1 - Reaction of K2[Ru(NO)Cl5] with K8[γ-SiW10O36] Under Hydrothermal Conditions

T2 - Synthesis of [SiW11O39{Ru(NO)}]5–

AU - Shmakova, A. A.

AU - Volchek, V. V.

AU - Abramov, P. A.

AU - Sokolov, M. N.

N1 - Publisher Copyright: © 2018, Pleiades Publishing, Ltd.

PY - 2018/11/1

Y1 - 2018/11/1

N2 - The thermostating of an aqueous solution of K2[Ru(NO)Cl5] and K8[γ-SiW10O36] at 160 °С for 16 h leads to a change in the color of the solution from pink to brown. According to the HPLC-ICP-AES data, the reaction products are Keggin anions: [SiW11O39{Ru(NO)}]5– (1) and [SiW12O40]4– (2). The formation of 1 and 2 is demonstrated by mass spectrometry for tetrabutylammonium salts in an acetonitrile solution. Red crystals of the composition ((CH3)2NH2)4H[α-SiW11O39{Ru(NO)}]·6H2O (1а) are obtained by fractional crystallization of dimethylammonium salts.

AB - The thermostating of an aqueous solution of K2[Ru(NO)Cl5] and K8[γ-SiW10O36] at 160 °С for 16 h leads to a change in the color of the solution from pink to brown. According to the HPLC-ICP-AES data, the reaction products are Keggin anions: [SiW11O39{Ru(NO)}]5– (1) and [SiW12O40]4– (2). The formation of 1 and 2 is demonstrated by mass spectrometry for tetrabutylammonium salts in an acetonitrile solution. Red crystals of the composition ((CH3)2NH2)4H[α-SiW11O39{Ru(NO)}]·6H2O (1а) are obtained by fractional crystallization of dimethylammonium salts.

KW - crystal structure

KW - Keggin anion

KW - ruthenium

KW - NMR

KW - POLYOXOTUNGSTATES

KW - HETEROPOLYANIONS

KW - POLYOXOMETALATE

KW - RUTHENIUM

UR - http://www.scopus.com/inward/record.url?scp=85058441602&partnerID=8YFLogxK

U2 - 10.1134/S0022476618060252

DO - 10.1134/S0022476618060252

M3 - Article

AN - SCOPUS:85058441602

VL - 59

SP - 1427

EP - 1432

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 6

ER -

ID: 17878191