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Radical polymerization of radical-labeled monomers : The triarylmethyl-based radical monomer as an example. / Edeleva, Mariya V.; Marque, Sylvain R.A.; Rogozhnikova, Olga Yu et al.

In: Journal of Polymer Science, Part A: Polymer Chemistry, Vol. 56, No. 23, 01.12.2018, p. 2656-2664.

Research output: Contribution to journal › Article › peer-review

Harvard

Edeleva, MV, Marque, SRA, Rogozhnikova, OY, Tormyshev, VM, Troitskaya, TI & Bagryanskaya, EG 2018, 'Radical polymerization of radical-labeled monomers: The triarylmethyl-based radical monomer as an example', Journal of Polymer Science, Part A: Polymer Chemistry, vol. 56, no. 23, pp. 2656-2664. https://doi.org/10.1002/pola.29249

APA

Edeleva, M. V., Marque, S. R. A., Rogozhnikova, O. Y., Tormyshev, V. M., Troitskaya, T. I., & Bagryanskaya, E. G. (2018). Radical polymerization of radical-labeled monomers: The triarylmethyl-based radical monomer as an example. Journal of Polymer Science, Part A: Polymer Chemistry, 56(23), 2656-2664. https://doi.org/10.1002/pola.29249

Vancouver

Edeleva MV, Marque SRA, Rogozhnikova OY, Tormyshev VM, Troitskaya TI, Bagryanskaya EG. Radical polymerization of radical-labeled monomers: The triarylmethyl-based radical monomer as an example. Journal of Polymer Science, Part A: Polymer Chemistry. 2018 Dec 1;56(23):2656-2664. doi: 10.1002/pola.29249

Author

Edeleva, Mariya V. ; Marque, Sylvain R.A. ; Rogozhnikova, Olga Yu et al. / Radical polymerization of radical-labeled monomers : The triarylmethyl-based radical monomer as an example. In: Journal of Polymer Science, Part A: Polymer Chemistry. 2018 ; Vol. 56, No. 23. pp. 2656-2664.

BibTeX

@article{538d2501a67a4dc4b0c918503f0d3f29,
title = "Radical polymerization of radical-labeled monomers: The triarylmethyl-based radical monomer as an example",
abstract = "Recent development of spin-labeled nitroxide-mediated polymerization (NMP) involving successful polymer preparation with high livingness and narrow dispersity in the presence of persistent trityl-based stable radicals attached to the initiators (90% recovery of a trityl radical signal after the polymerization) led us to the preparation of stable organic radical polymers based on trityl radical-substituted monomers using NMP as the method of polymerization despite the claims in the literature about its expected failure. Here, we present successful radical polymerization and NMP of a trityl radical-based tri- and mono-monomer yielding more than 90% recovery of the trityl radical signal.",
keywords = "kinetics of polymerization, nitroxide, stable organic radical, triarylmethyl radical, SYSTEM, NITROXIDE, BLOCK-COPOLYMERS, METHYL-METHACRYLATE, PHENYLAZOTRIPHENYLMETHANE, TRITYL RADICALS, COMBINATION, CHAIN TRANSFER, THERMAL INIFERTER, INITER PROCESS",
author = "Edeleva, {Mariya V.} and Marque, {Sylvain R.A.} and Rogozhnikova, {Olga Yu} and Tormyshev, {Victor M.} and Troitskaya, {Tatiana I.} and Bagryanskaya, {Elena G.}",
year = "2018",
month = dec,
day = "1",
doi = "10.1002/pola.29249",
language = "English",
volume = "56",
pages = "2656--2664",
journal = "Journal of Polymer Science, Part A: Polymer Chemistry",
issn = "0887-624X",
publisher = "John Wiley and Sons Inc.",
number = "23",

}

RIS

TY - JOUR

T1 - Radical polymerization of radical-labeled monomers

T2 - The triarylmethyl-based radical monomer as an example

AU - Edeleva, Mariya V.

AU - Marque, Sylvain R.A.

AU - Rogozhnikova, Olga Yu

AU - Tormyshev, Victor M.

AU - Troitskaya, Tatiana I.

AU - Bagryanskaya, Elena G.

PY - 2018/12/1

Y1 - 2018/12/1

N2 - Recent development of spin-labeled nitroxide-mediated polymerization (NMP) involving successful polymer preparation with high livingness and narrow dispersity in the presence of persistent trityl-based stable radicals attached to the initiators (90% recovery of a trityl radical signal after the polymerization) led us to the preparation of stable organic radical polymers based on trityl radical-substituted monomers using NMP as the method of polymerization despite the claims in the literature about its expected failure. Here, we present successful radical polymerization and NMP of a trityl radical-based tri- and mono-monomer yielding more than 90% recovery of the trityl radical signal.

AB - Recent development of spin-labeled nitroxide-mediated polymerization (NMP) involving successful polymer preparation with high livingness and narrow dispersity in the presence of persistent trityl-based stable radicals attached to the initiators (90% recovery of a trityl radical signal after the polymerization) led us to the preparation of stable organic radical polymers based on trityl radical-substituted monomers using NMP as the method of polymerization despite the claims in the literature about its expected failure. Here, we present successful radical polymerization and NMP of a trityl radical-based tri- and mono-monomer yielding more than 90% recovery of the trityl radical signal.

KW - kinetics of polymerization

KW - nitroxide

KW - stable organic radical

KW - triarylmethyl radical

KW - SYSTEM

KW - NITROXIDE

KW - BLOCK-COPOLYMERS

KW - METHYL-METHACRYLATE

KW - PHENYLAZOTRIPHENYLMETHANE

KW - TRITYL RADICALS

KW - COMBINATION

KW - CHAIN TRANSFER

KW - THERMAL INIFERTER

KW - INITER PROCESS

UR - http://www.scopus.com/inward/record.url?scp=85055275756&partnerID=8YFLogxK

U2 - 10.1002/pola.29249

DO - 10.1002/pola.29249

M3 - Article

AN - SCOPUS:85055275756

VL - 56

SP - 2656

EP - 2664

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

SN - 0887-624X

IS - 23

ER -

ID: 17234145