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Quantifying the effects of quadrupolar sinks : Via 15N relaxation dynamics in metronidazoles hyperpolarized via SABRE-SHEATH. / Birchall, Jonathan R.; Kabir, Mohammad S.H.; Salnikov, Oleg G. et al.

In: Chemical Communications, Vol. 56, No. 64, 18.08.2020, p. 9098-9101.

Research output: Contribution to journal › Article › peer-review

Harvard

Birchall, JR, Kabir, MSH, Salnikov, OG, Chukanov, NV, Svyatova, A, Kovtunov, KV, Koptyug, IV, Gelovani, JG, Goodson, BM, Pham, W & Chekmenev, EY 2020, 'Quantifying the effects of quadrupolar sinks: Via 15N relaxation dynamics in metronidazoles hyperpolarized via SABRE-SHEATH', Chemical Communications, vol. 56, no. 64, pp. 9098-9101. https://doi.org/10.1039/d0cc03994b

APA

Birchall, J. R., Kabir, M. S. H., Salnikov, O. G., Chukanov, N. V., Svyatova, A., Kovtunov, K. V., Koptyug, I. V., Gelovani, J. G., Goodson, B. M., Pham, W., & Chekmenev, E. Y. (2020). Quantifying the effects of quadrupolar sinks: Via 15N relaxation dynamics in metronidazoles hyperpolarized via SABRE-SHEATH. Chemical Communications, 56(64), 9098-9101. https://doi.org/10.1039/d0cc03994b

Vancouver

Birchall JR, Kabir MSH, Salnikov OG, Chukanov NV, Svyatova A, Kovtunov KV et al. Quantifying the effects of quadrupolar sinks: Via 15N relaxation dynamics in metronidazoles hyperpolarized via SABRE-SHEATH. Chemical Communications. 2020 Aug 18;56(64):9098-9101. doi: 10.1039/d0cc03994b

Author

Birchall, Jonathan R. ; Kabir, Mohammad S.H. ; Salnikov, Oleg G. et al. / Quantifying the effects of quadrupolar sinks : Via 15N relaxation dynamics in metronidazoles hyperpolarized via SABRE-SHEATH. In: Chemical Communications. 2020 ; Vol. 56, No. 64. pp. 9098-9101.

BibTeX

@article{29604011db364125b55901d5b802f556,
title = "Quantifying the effects of quadrupolar sinks: Via 15N relaxation dynamics in metronidazoles hyperpolarized via SABRE-SHEATH",
abstract = " 15N spin-lattice relaxation dynamics in metronidazole- 15N 3 and metronidazole- 15N 2 isotopologues are studied for rational design of 15N-enriched biomolecules for signal amplification by reversible exchange in microtesla fields. 15N relaxation dynamics mapping reveals the deleterious effects of interactions with the polarization transfer catalyst and a quadrupolar 14N nucleus within the spin-relayed 15N- 15N network. ",
keywords = "REVERSIBLE EXCHANGE, SIGNAL AMPLIFICATION, CATALYSTS, MRI",
author = "Birchall, {Jonathan R.} and Kabir, {Mohammad S.H.} and Salnikov, {Oleg G.} and Chukanov, {Nikita V.} and Alexandra Svyatova and Kovtunov, {Kirill V.} and Koptyug, {Igor V.} and Gelovani, {Juri G.} and Goodson, {Boyd M.} and Wellington Pham and Chekmenev, {Eduard Y.}",
year = "2020",
month = aug,
day = "18",
doi = "10.1039/d0cc03994b",
language = "English",
volume = "56",
pages = "9098--9101",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "64",

}

RIS

TY - JOUR

T1 - Quantifying the effects of quadrupolar sinks

T2 - Via 15N relaxation dynamics in metronidazoles hyperpolarized via SABRE-SHEATH

AU - Birchall, Jonathan R.

AU - Kabir, Mohammad S.H.

AU - Salnikov, Oleg G.

AU - Chukanov, Nikita V.

AU - Svyatova, Alexandra

AU - Kovtunov, Kirill V.

AU - Koptyug, Igor V.

AU - Gelovani, Juri G.

AU - Goodson, Boyd M.

AU - Pham, Wellington

AU - Chekmenev, Eduard Y.

PY - 2020/8/18

Y1 - 2020/8/18

N2 - 15N spin-lattice relaxation dynamics in metronidazole- 15N 3 and metronidazole- 15N 2 isotopologues are studied for rational design of 15N-enriched biomolecules for signal amplification by reversible exchange in microtesla fields. 15N relaxation dynamics mapping reveals the deleterious effects of interactions with the polarization transfer catalyst and a quadrupolar 14N nucleus within the spin-relayed 15N- 15N network.

AB - 15N spin-lattice relaxation dynamics in metronidazole- 15N 3 and metronidazole- 15N 2 isotopologues are studied for rational design of 15N-enriched biomolecules for signal amplification by reversible exchange in microtesla fields. 15N relaxation dynamics mapping reveals the deleterious effects of interactions with the polarization transfer catalyst and a quadrupolar 14N nucleus within the spin-relayed 15N- 15N network.

KW - REVERSIBLE EXCHANGE

KW - SIGNAL AMPLIFICATION

KW - CATALYSTS

KW - MRI

UR - http://www.scopus.com/inward/record.url?scp=85089359035&partnerID=8YFLogxK

U2 - 10.1039/d0cc03994b

DO - 10.1039/d0cc03994b

M3 - Article

C2 - 32661534

AN - SCOPUS:85089359035

VL - 56

SP - 9098

EP - 9101

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 64

ER -

ID: 25291289