Research output: Contribution to journal › Article › peer-review
Pyrene containing liquid crystalline asymmetric phthalocyanines and their composite materials with single-walled carbon nanotubes. / Kaya, Esra Nur; Polyakov, Maxim S.; Basova, Tamara V. et al.
In: Journal of Porphyrins and Phthalocyanines, Vol. 22, No. 1-3, 01.01.2018, p. 56-63.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Pyrene containing liquid crystalline asymmetric phthalocyanines and their composite materials with single-walled carbon nanotubes
AU - Kaya, Esra Nur
AU - Polyakov, Maxim S.
AU - Basova, Tamara V.
AU - Durmuş, Mahmut
AU - Hassan, Aseel
PY - 2018/1/1
Y1 - 2018/1/1
N2 - In the present work we have studied the dispersion of single-walled carbon nanotubes in liquid crystalline asymmetrically substituted phthalocyanines (MPc, where M = Cu, Co, and 2H) bearing one pyrene and six polyoxy groups as side chains. The influence of single-walled carbon nanotubes on the phase behavior of MPcs was investigated using X-ray diffraction, polarized optical microscopy and differential scanning calorimetry. It was demonstrated that the incorporation of small amounts of single-walled carbon nanotubes (≤1 wt.%) does not alter the MPc mesophases. The structural features and the sensor response of composite thin films of MPc with single-walled carbon nanotubes to ammonia vapor (10-50 ppm) was studied and compared with those of the films of pure MPc derivatives.
AB - In the present work we have studied the dispersion of single-walled carbon nanotubes in liquid crystalline asymmetrically substituted phthalocyanines (MPc, where M = Cu, Co, and 2H) bearing one pyrene and six polyoxy groups as side chains. The influence of single-walled carbon nanotubes on the phase behavior of MPcs was investigated using X-ray diffraction, polarized optical microscopy and differential scanning calorimetry. It was demonstrated that the incorporation of small amounts of single-walled carbon nanotubes (≤1 wt.%) does not alter the MPc mesophases. The structural features and the sensor response of composite thin films of MPc with single-walled carbon nanotubes to ammonia vapor (10-50 ppm) was studied and compared with those of the films of pure MPc derivatives.
KW - carbon nanotubes
KW - composite materials
KW - liquid crystals
KW - phthalocyanines
KW - sensors
KW - THIN-FILMS
KW - TRANSITION-METAL-COMPLEXES
KW - BEHAVIOR
KW - HOMEOTROPIC ALIGNMENT
KW - ORIENTATION
KW - NH3 SENSING PERFORMANCE
KW - SUBSTITUTED PHTHALOCYANINES
KW - HYBRIDS
UR - http://www.scopus.com/inward/record.url?scp=85044208106&partnerID=8YFLogxK
U2 - 10.1142/S1088424618500025
DO - 10.1142/S1088424618500025
M3 - Article
AN - SCOPUS:85044208106
VL - 22
SP - 56
EP - 63
JO - Journal of Porphyrins and Phthalocyanines
JF - Journal of Porphyrins and Phthalocyanines
SN - 1088-4246
IS - 1-3
ER -
ID: 12177952