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Protonation of N2O and NO2 in a solid phase. / Stoyanov, Evgenii S.; Stoyanova, Irina V.

In: Physical Chemistry Chemical Physics, Vol. 19, No. 48, 13.12.2017, p. 32733-32740.

Research output: Contribution to journal › Article › peer-review

Harvard

Stoyanov, ES & Stoyanova, IV 2017, 'Protonation of N2O and NO2 in a solid phase', Physical Chemistry Chemical Physics, vol. 19, no. 48, pp. 32733-32740. https://doi.org/10.1039/c7cp04474g

APA

Stoyanov, E. S., & Stoyanova, I. V. (2017). Protonation of N2O and NO2 in a solid phase. Physical Chemistry Chemical Physics, 19(48), 32733-32740. https://doi.org/10.1039/c7cp04474g

Vancouver

Stoyanov ES, Stoyanova IV. Protonation of N2O and NO2 in a solid phase. Physical Chemistry Chemical Physics. 2017 Dec 13;19(48):32733-32740. doi: 10.1039/c7cp04474g

Author

Stoyanov, Evgenii S. ; Stoyanova, Irina V. / Protonation of N2O and NO2 in a solid phase. In: Physical Chemistry Chemical Physics. 2017 ; Vol. 19, No. 48. pp. 32733-32740.

BibTeX

@article{9a576fbe6fa84543ba90581b3f876470,
title = "Protonation of N2O and NO2 in a solid phase",
abstract = "Adsorption of gaseous N2O on the acidic surface Br{\o}nsted centers of the strongest known solid acid, H(CHB11F11), results in formation of the N≡N-OH+ cation. Its positive charge is localized mainly to the H-atom, which is H-bonded to the CHB11F11 - anion forming an asymmetric proton disolvate of the L1-H+⋯L2 type, where L1 = N2O and L2 = CHB11F11 -. NO2 protonation under the same conditions leads to the formation of the highly reactive cation radical NO2H+, which reacts rapidly with an NO2 molecule according to the equation N2OH+ + NO2 → [N2O4H+] → N2OH+ + O2 resulting in the formation of two types of N2OH+ cations: (i) a typical Br{\o}nsted superacid, NN-OH+, with a strongly acidic OH group involved in a rather strong H-bond with the anion, and (ii) a typical strong Lewis acid, NN+-OH, with a positive charge localized to the central N atom and ionic interactions with the surrounding anions via the charged central N atom.",
keywords = "NATURAL RESONANCE THEORY, SPECTROSCOPIC DETECTION, ACID PROTONATION, GAS-PHASE, IONS, BOND, CHEMISTRY, AFFINITY, CATION, ORDER",
author = "Stoyanov, {Evgenii S.} and Stoyanova, {Irina V.}",
year = "2017",
month = dec,
day = "13",
doi = "10.1039/c7cp04474g",
language = "English",
volume = "19",
pages = "32733--32740",
journal = "Physical Chemistry Chemical Physics",
issn = "1463-9076",
publisher = "Royal Society of Chemistry",
number = "48",

}

RIS

TY - JOUR

T1 - Protonation of N2O and NO2 in a solid phase

AU - Stoyanov, Evgenii S.

AU - Stoyanova, Irina V.

PY - 2017/12/13

Y1 - 2017/12/13

N2 - Adsorption of gaseous N2O on the acidic surface Brønsted centers of the strongest known solid acid, H(CHB11F11), results in formation of the N≡N-OH+ cation. Its positive charge is localized mainly to the H-atom, which is H-bonded to the CHB11F11 - anion forming an asymmetric proton disolvate of the L1-H+⋯L2 type, where L1 = N2O and L2 = CHB11F11 -. NO2 protonation under the same conditions leads to the formation of the highly reactive cation radical NO2H+, which reacts rapidly with an NO2 molecule according to the equation N2OH+ + NO2 → [N2O4H+] → N2OH+ + O2 resulting in the formation of two types of N2OH+ cations: (i) a typical Brønsted superacid, NN-OH+, with a strongly acidic OH group involved in a rather strong H-bond with the anion, and (ii) a typical strong Lewis acid, NN+-OH, with a positive charge localized to the central N atom and ionic interactions with the surrounding anions via the charged central N atom.

AB - Adsorption of gaseous N2O on the acidic surface Brønsted centers of the strongest known solid acid, H(CHB11F11), results in formation of the N≡N-OH+ cation. Its positive charge is localized mainly to the H-atom, which is H-bonded to the CHB11F11 - anion forming an asymmetric proton disolvate of the L1-H+⋯L2 type, where L1 = N2O and L2 = CHB11F11 -. NO2 protonation under the same conditions leads to the formation of the highly reactive cation radical NO2H+, which reacts rapidly with an NO2 molecule according to the equation N2OH+ + NO2 → [N2O4H+] → N2OH+ + O2 resulting in the formation of two types of N2OH+ cations: (i) a typical Brønsted superacid, NN-OH+, with a strongly acidic OH group involved in a rather strong H-bond with the anion, and (ii) a typical strong Lewis acid, NN+-OH, with a positive charge localized to the central N atom and ionic interactions with the surrounding anions via the charged central N atom.

KW - NATURAL RESONANCE THEORY

KW - SPECTROSCOPIC DETECTION

KW - ACID PROTONATION

KW - GAS-PHASE

KW - IONS

KW - BOND

KW - CHEMISTRY

KW - AFFINITY

KW - CATION

KW - ORDER

UR - http://www.scopus.com/inward/record.url?scp=85038403425&partnerID=8YFLogxK

U2 - 10.1039/c7cp04474g

DO - 10.1039/c7cp04474g

M3 - Article

C2 - 29199288

AN - SCOPUS:85038403425

VL - 19

SP - 32733

EP - 32740

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

IS - 48

ER -

ID: 9645370