Research output: Contribution to journal › Article › peer-review
Preparation of porous materials by Spark Plasma Sintering : Peculiarities of alloy formation during consolidation of Fe@Pt core-shell and hollow Pt(Fe) particles. / Bokhonov, Boris B.; Dudina, Dina V.
In: Journal of Alloys and Compounds, Vol. 707, 01.01.2017, p. 233-237.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Preparation of porous materials by Spark Plasma Sintering
T2 - Peculiarities of alloy formation during consolidation of Fe@Pt core-shell and hollow Pt(Fe) particles
AU - Bokhonov, Boris B.
AU - Dudina, Dina V.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - In this work, the behavior of the Fe@Pt core-shell particles and hollow Pt(Fe) particles during pressureless Spark Plasma Sintering (SPS) was investigated. The Fe@Pt core-shell microparticles were synthesized by galvanic replacement reaction using reduction of H2PtCl6 aqueous solution by metallic iron. Pt(Fe) hollow particles were obtained by dissolving iron from the synthesized core-shell particles in HCl solution. Consolidation resulted in the formation of porous compacts, necking between the particles, alloying between the metals, and growth of the crystallites. The compositional design of the consolidated materials was possible through changing the order of sintering and HCl treatment stages. This work has demonstrated that acid corrosion and SPS can be used together to tailor the composition and morphology of materials derived from the core-shell particles.
AB - In this work, the behavior of the Fe@Pt core-shell particles and hollow Pt(Fe) particles during pressureless Spark Plasma Sintering (SPS) was investigated. The Fe@Pt core-shell microparticles were synthesized by galvanic replacement reaction using reduction of H2PtCl6 aqueous solution by metallic iron. Pt(Fe) hollow particles were obtained by dissolving iron from the synthesized core-shell particles in HCl solution. Consolidation resulted in the formation of porous compacts, necking between the particles, alloying between the metals, and growth of the crystallites. The compositional design of the consolidated materials was possible through changing the order of sintering and HCl treatment stages. This work has demonstrated that acid corrosion and SPS can be used together to tailor the composition and morphology of materials derived from the core-shell particles.
KW - Corrosion
KW - Metals and alloys
KW - Scanning electron microscopy
KW - Sintering
KW - OXIDATION
KW - NANOPARTICLES
KW - ROUTE
KW - MICROSPHERES
KW - VERSATILE
KW - NANOSTRUCTURES
KW - FABRICATION
UR - http://www.scopus.com/inward/record.url?scp=84995554219&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2016.09.146
DO - 10.1016/j.jallcom.2016.09.146
M3 - Article
AN - SCOPUS:84995554219
VL - 707
SP - 233
EP - 237
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
SN - 0925-8388
ER -
ID: 10320145