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Preferred attachment of fluorine near oxygen-containing groups on the surface of double-walled carbon nanotubes. / Fedoseeva, Yu V.; Bulusheva, L. G.; Koroteev, V. O. et al.

In: Applied Surface Science, Vol. 504, 144357, 28.02.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Fedoseeva, YV, Bulusheva, LG, Koroteev, VO, Mevellec, JY, Senkovskiy, BV, Flahaut, E & Okotrub, AV 2020, 'Preferred attachment of fluorine near oxygen-containing groups on the surface of double-walled carbon nanotubes', Applied Surface Science, vol. 504, 144357. https://doi.org/10.1016/j.apsusc.2019.144357

APA

Fedoseeva, Y. V., Bulusheva, L. G., Koroteev, V. O., Mevellec, J. Y., Senkovskiy, B. V., Flahaut, E., & Okotrub, A. V. (2020). Preferred attachment of fluorine near oxygen-containing groups on the surface of double-walled carbon nanotubes. Applied Surface Science, 504, [144357]. https://doi.org/10.1016/j.apsusc.2019.144357

Vancouver

Fedoseeva YV, Bulusheva LG, Koroteev VO, Mevellec JY, Senkovskiy BV, Flahaut E et al. Preferred attachment of fluorine near oxygen-containing groups on the surface of double-walled carbon nanotubes. Applied Surface Science. 2020 Feb 28;504:144357. doi: 10.1016/j.apsusc.2019.144357

Author

Fedoseeva, Yu V. ; Bulusheva, L. G. ; Koroteev, V. O. et al. / Preferred attachment of fluorine near oxygen-containing groups on the surface of double-walled carbon nanotubes. In: Applied Surface Science. 2020 ; Vol. 504.

BibTeX

@article{b3151445181c4421951428af4a9b8787,
title = "Preferred attachment of fluorine near oxygen-containing groups on the surface of double-walled carbon nanotubes",
abstract = "Two samples of double-walled carbon nanotubes (DWCNTs), one with well-graphitized nanotube walls and another containing oxygen at outer nanotube surfaces, were fluorinated at room temperature using gaseous BrF3. The products were comprehensively studied using transmission electron microscopy, Raman scattering, X-ray photoelectron, and near-edge X-ray absorption fine structure spectroscopies. The experimental data found twice the concentration of sidewall fluorine in the oxygenated DWCNTs. Quantum chemical modeling supported the experimental results revealing the preferable development of CF areas near the carbon atoms bonded with oxygen-containing groups. This observation demonstrates that tuning of the physical and chemical properties of carbon nanotubes can be achieved via the controlled co-modification by fluorine and oxygen functional groups.",
keywords = "DFT, Double-walled carbon nanotubes, NEXAFS, Oxyfluorination, XPS, OXIDATION, GRAPHENE OXIDE, PERFORMANCE, RAMAN-SPECTROSCOPY, ADSORPTION, SINGLE-WALL, FUNCTIONALIZATION, TEMPERATURE, OXYFLUORINATION, SPECTRA",
author = "Fedoseeva, {Yu V.} and Bulusheva, {L. G.} and Koroteev, {V. O.} and Mevellec, {J. Y.} and Senkovskiy, {B. V.} and E. Flahaut and Okotrub, {A. V.}",
year = "2020",
month = feb,
day = "28",
doi = "10.1016/j.apsusc.2019.144357",
language = "English",
volume = "504",
journal = "Applied Surface Science",
issn = "0169-4332",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Preferred attachment of fluorine near oxygen-containing groups on the surface of double-walled carbon nanotubes

AU - Fedoseeva, Yu V.

AU - Bulusheva, L. G.

AU - Koroteev, V. O.

AU - Mevellec, J. Y.

AU - Senkovskiy, B. V.

AU - Flahaut, E.

AU - Okotrub, A. V.

PY - 2020/2/28

Y1 - 2020/2/28

N2 - Two samples of double-walled carbon nanotubes (DWCNTs), one with well-graphitized nanotube walls and another containing oxygen at outer nanotube surfaces, were fluorinated at room temperature using gaseous BrF3. The products were comprehensively studied using transmission electron microscopy, Raman scattering, X-ray photoelectron, and near-edge X-ray absorption fine structure spectroscopies. The experimental data found twice the concentration of sidewall fluorine in the oxygenated DWCNTs. Quantum chemical modeling supported the experimental results revealing the preferable development of CF areas near the carbon atoms bonded with oxygen-containing groups. This observation demonstrates that tuning of the physical and chemical properties of carbon nanotubes can be achieved via the controlled co-modification by fluorine and oxygen functional groups.

AB - Two samples of double-walled carbon nanotubes (DWCNTs), one with well-graphitized nanotube walls and another containing oxygen at outer nanotube surfaces, were fluorinated at room temperature using gaseous BrF3. The products were comprehensively studied using transmission electron microscopy, Raman scattering, X-ray photoelectron, and near-edge X-ray absorption fine structure spectroscopies. The experimental data found twice the concentration of sidewall fluorine in the oxygenated DWCNTs. Quantum chemical modeling supported the experimental results revealing the preferable development of CF areas near the carbon atoms bonded with oxygen-containing groups. This observation demonstrates that tuning of the physical and chemical properties of carbon nanotubes can be achieved via the controlled co-modification by fluorine and oxygen functional groups.

KW - DFT

KW - Double-walled carbon nanotubes

KW - NEXAFS

KW - Oxyfluorination

KW - XPS

KW - OXIDATION

KW - GRAPHENE OXIDE

KW - PERFORMANCE

KW - RAMAN-SPECTROSCOPY

KW - ADSORPTION

KW - SINGLE-WALL

KW - FUNCTIONALIZATION

KW - TEMPERATURE

KW - OXYFLUORINATION

KW - SPECTRA

UR - http://www.scopus.com/inward/record.url?scp=85075451751&partnerID=8YFLogxK

U2 - 10.1016/j.apsusc.2019.144357

DO - 10.1016/j.apsusc.2019.144357

M3 - Article

AN - SCOPUS:85075451751

VL - 504

JO - Applied Surface Science

JF - Applied Surface Science

SN - 0169-4332

M1 - 144357

ER -

ID: 22403224