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Polysulfide Coordination Clusters of the Lanthanides. / Ma, Ying Zhao; Bestgen, Sebastian; Gamer, Michael T. et al.

In: Angewandte Chemie - International Edition, Vol. 56, No. 43, 16.10.2017, p. 13249-13252.

Research output: Contribution to journal › Article › peer-review

Harvard

Ma, YZ, Bestgen, S, Gamer, MT, Konchenko, SN & Roesky, PW 2017, 'Polysulfide Coordination Clusters of the Lanthanides', Angewandte Chemie - International Edition, vol. 56, no. 43, pp. 13249-13252. https://doi.org/10.1002/anie.201707578

APA

Ma, Y. Z., Bestgen, S., Gamer, M. T., Konchenko, S. N., & Roesky, P. W. (2017). Polysulfide Coordination Clusters of the Lanthanides. Angewandte Chemie - International Edition, 56(43), 13249-13252. https://doi.org/10.1002/anie.201707578

Vancouver

Ma YZ, Bestgen S, Gamer MT, Konchenko SN, Roesky PW. Polysulfide Coordination Clusters of the Lanthanides. Angewandte Chemie - International Edition. 2017 Oct 16;56(43):13249-13252. doi: 10.1002/anie.201707578

Author

Ma, Ying Zhao ; Bestgen, Sebastian ; Gamer, Michael T. et al. / Polysulfide Coordination Clusters of the Lanthanides. In: Angewandte Chemie - International Edition. 2017 ; Vol. 56, No. 43. pp. 13249-13252.

BibTeX

@article{22374c8213b2424a9a459653c1fecb8b,
title = "Polysulfide Coordination Clusters of the Lanthanides",
abstract = "The reaction of [(DippForm)2Ln(thf)2] with an excess of elemental sulfur in toluene resulted in the formation of the trinuclear polysulfide coordination clusters [(DippForm)3Ln3S12] (Ln=Sm, Yb; DippForm=N,N′-bis(2,6-diisopropylphenyl)formamidinate). These are the first f element coordination clusters (LnnSx) with a larger polysulfide unit (n and x>2). The formation of the coordination clusters can be rationalized by the reductive cleavage of S8 with divalent lanthanides.",
keywords = "coordination clusters, lanthanides, samarium, sulfur, ytterbium",
author = "Ma, {Ying Zhao} and Sebastian Bestgen and Gamer, {Michael T.} and Konchenko, {Sergey N.} and Roesky, {Peter W.}",
year = "2017",
month = oct,
day = "16",
doi = "10.1002/anie.201707578",
language = "English",
volume = "56",
pages = "13249--13252",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "43",

}

RIS

TY - JOUR

T1 - Polysulfide Coordination Clusters of the Lanthanides

AU - Ma, Ying Zhao

AU - Bestgen, Sebastian

AU - Gamer, Michael T.

AU - Konchenko, Sergey N.

AU - Roesky, Peter W.

PY - 2017/10/16

Y1 - 2017/10/16

N2 - The reaction of [(DippForm)2Ln(thf)2] with an excess of elemental sulfur in toluene resulted in the formation of the trinuclear polysulfide coordination clusters [(DippForm)3Ln3S12] (Ln=Sm, Yb; DippForm=N,N′-bis(2,6-diisopropylphenyl)formamidinate). These are the first f element coordination clusters (LnnSx) with a larger polysulfide unit (n and x>2). The formation of the coordination clusters can be rationalized by the reductive cleavage of S8 with divalent lanthanides.

AB - The reaction of [(DippForm)2Ln(thf)2] with an excess of elemental sulfur in toluene resulted in the formation of the trinuclear polysulfide coordination clusters [(DippForm)3Ln3S12] (Ln=Sm, Yb; DippForm=N,N′-bis(2,6-diisopropylphenyl)formamidinate). These are the first f element coordination clusters (LnnSx) with a larger polysulfide unit (n and x>2). The formation of the coordination clusters can be rationalized by the reductive cleavage of S8 with divalent lanthanides.

KW - coordination clusters

KW - lanthanides

KW - samarium

KW - sulfur

KW - ytterbium

UR - http://www.scopus.com/inward/record.url?scp=85031099880&partnerID=8YFLogxK

U2 - 10.1002/anie.201707578

DO - 10.1002/anie.201707578

M3 - Article

AN - SCOPUS:85031099880

VL - 56

SP - 13249

EP - 13252

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 43

ER -

ID: 9892762