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Polynuclear Sulfide-Bridging Rh(III) Complexes with P(CH2OH)(3). / Anyushin, A. V.; Kompan'kov, N. B.; Abramov, P. A. et al.

In: Journal of Structural Chemistry, Vol. 60, No. 7, 07.2019, p. 1072-1079.

Research output: Contribution to journal › Article › peer-review

Harvard

Anyushin, AV, Kompan'kov, NB, Abramov, PA & Sokolov, MN 2019, 'Polynuclear Sulfide-Bridging Rh(III) Complexes with P(CH2OH)(3)', Journal of Structural Chemistry, vol. 60, no. 7, pp. 1072-1079. https://doi.org/10.1134/S0022476619070072

APA

Anyushin, A. V., Kompan'kov, N. B., Abramov, P. A., & Sokolov, M. N. (2019). Polynuclear Sulfide-Bridging Rh(III) Complexes with P(CH2OH)(3). Journal of Structural Chemistry, 60(7), 1072-1079. https://doi.org/10.1134/S0022476619070072

Vancouver

Anyushin AV, Kompan'kov NB, Abramov PA, Sokolov MN. Polynuclear Sulfide-Bridging Rh(III) Complexes with P(CH2OH)(3). Journal of Structural Chemistry. 2019 Jul;60(7):1072-1079. doi: 10.1134/S0022476619070072

Author

Anyushin, A. V. ; Kompan'kov, N. B. ; Abramov, P. A. et al. / Polynuclear Sulfide-Bridging Rh(III) Complexes with P(CH2OH)(3). In: Journal of Structural Chemistry. 2019 ; Vol. 60, No. 7. pp. 1072-1079.

BibTeX

@article{c5f67281e604407f9d35b2b5e4e16782,
title = "Polynuclear Sulfide-Bridging Rh(III) Complexes with P(CH2OH)(3)",
abstract = "A reaction of RhCl3 center dot 3H(2)O with P(CH2OH)(3) (THP) and H2S in methanol results in the formation of a new trinuclear complex [Rh-3(mu 3-S)(2)(mu(2)-S)(mu(2)-Cl)(2)(THP)(6)]Cl (1) with a yield of 29%. The structure of 1 is determined by X-ray crystallography. With the same initial compounds with hexamethyldisilthiane as a sulfide source a binuclear [Rh-2(mu(2)-S-2)(mu(2)-S)(THP)(6)](2+) complex is obtained in which mono- and disulfide bridges are present simultaneously. The latter is isolated and structurally characterized as [Rh-2(mu-S-2)(mu(2)-S)(THP)(6)][Mo6Cl14]center dot 0.6MeOH (2) with a yield of 12%. The compounds obtained are characterized by mass spectrometry and P-31 NMR spectra.",
keywords = "polynuclear complexes, sulfides, rhodium, self-assemblage, hydrophilic phosphines, AQUEOUS SPECIATION, CRYSTAL-STRUCTURE, SUBSTITUTION-REACTIONS, KINETICS, CLUSTERS, TRIS(HYDROXYMETHYL)PHOSPHINE, HYDROGENATION, CATALYSTS, LIGANDS",
author = "Anyushin, {A. V.} and Kompan'kov, {N. B.} and Abramov, {P. A.} and Sokolov, {M. N.}",
year = "2019",
month = jul,
doi = "10.1134/S0022476619070072",
language = "English",
volume = "60",
pages = "1072--1079",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "7",

}

RIS

TY - JOUR

T1 - Polynuclear Sulfide-Bridging Rh(III) Complexes with P(CH2OH)(3)

AU - Anyushin, A. V.

AU - Kompan'kov, N. B.

AU - Abramov, P. A.

AU - Sokolov, M. N.

PY - 2019/7

Y1 - 2019/7

N2 - A reaction of RhCl3 center dot 3H(2)O with P(CH2OH)(3) (THP) and H2S in methanol results in the formation of a new trinuclear complex [Rh-3(mu 3-S)(2)(mu(2)-S)(mu(2)-Cl)(2)(THP)(6)]Cl (1) with a yield of 29%. The structure of 1 is determined by X-ray crystallography. With the same initial compounds with hexamethyldisilthiane as a sulfide source a binuclear [Rh-2(mu(2)-S-2)(mu(2)-S)(THP)(6)](2+) complex is obtained in which mono- and disulfide bridges are present simultaneously. The latter is isolated and structurally characterized as [Rh-2(mu-S-2)(mu(2)-S)(THP)(6)][Mo6Cl14]center dot 0.6MeOH (2) with a yield of 12%. The compounds obtained are characterized by mass spectrometry and P-31 NMR spectra.

AB - A reaction of RhCl3 center dot 3H(2)O with P(CH2OH)(3) (THP) and H2S in methanol results in the formation of a new trinuclear complex [Rh-3(mu 3-S)(2)(mu(2)-S)(mu(2)-Cl)(2)(THP)(6)]Cl (1) with a yield of 29%. The structure of 1 is determined by X-ray crystallography. With the same initial compounds with hexamethyldisilthiane as a sulfide source a binuclear [Rh-2(mu(2)-S-2)(mu(2)-S)(THP)(6)](2+) complex is obtained in which mono- and disulfide bridges are present simultaneously. The latter is isolated and structurally characterized as [Rh-2(mu-S-2)(mu(2)-S)(THP)(6)][Mo6Cl14]center dot 0.6MeOH (2) with a yield of 12%. The compounds obtained are characterized by mass spectrometry and P-31 NMR spectra.

KW - polynuclear complexes

KW - sulfides

KW - rhodium

KW - self-assemblage

KW - hydrophilic phosphines

KW - AQUEOUS SPECIATION

KW - CRYSTAL-STRUCTURE

KW - SUBSTITUTION-REACTIONS

KW - KINETICS

KW - CLUSTERS

KW - TRIS(HYDROXYMETHYL)PHOSPHINE

KW - HYDROGENATION

KW - CATALYSTS

KW - LIGANDS

U2 - 10.1134/S0022476619070072

DO - 10.1134/S0022476619070072

M3 - Article

VL - 60

SP - 1072

EP - 1079

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 7

ER -

ID: 23291146