Research output: Contribution to journal › Article › peer-review
Polymorphism of the Double Octa(ε-caprolactam)europium(III) Hexa(isothiocyanato)chromate(III) Complex. / Virovets, A. V.; Peresypkina, E. V.; Cherkasova, E. V. et al.
In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 45, No. 1, 01.01.2019, p. 42-46.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Polymorphism of the Double Octa(ε-caprolactam)europium(III) Hexa(isothiocyanato)chromate(III) Complex
AU - Virovets, A. V.
AU - Peresypkina, E. V.
AU - Cherkasova, E. V.
AU - Cherkasova, T. G.
PY - 2019/1/1
Y1 - 2019/1/1
N2 - Abstract: A new structural polymorph of the compound [Eu(ε-C 6 H 11 NO) 8 ][Cr(NCS) 6 ] was isolated from the solid product mixture obtained in the reaction of EuCl 3 , K 3 [Cr(NCS) 6 ], and ε-caprolactam (ε-C 6 H 11 NO) in aqueous solution. The crystals were triclinic, space group. P1, Z = 2, a = 14.2320(4) Å, b = 14.5298(4) Å, c = 17.0014(5) Å, α = 92.4190(10)°, β = 91.0880(10)°, γ = 108.4850(10)°, V = 3329.39 Å 3 , ρ(calcd.) = 1.454 g/cm 3 , R 1 = 0.0419 (CIF file CCDC no. 1827162).
AB - Abstract: A new structural polymorph of the compound [Eu(ε-C 6 H 11 NO) 8 ][Cr(NCS) 6 ] was isolated from the solid product mixture obtained in the reaction of EuCl 3 , K 3 [Cr(NCS) 6 ], and ε-caprolactam (ε-C 6 H 11 NO) in aqueous solution. The crystals were triclinic, space group. P1, Z = 2, a = 14.2320(4) Å, b = 14.5298(4) Å, c = 17.0014(5) Å, α = 92.4190(10)°, β = 91.0880(10)°, γ = 108.4850(10)°, V = 3329.39 Å 3 , ρ(calcd.) = 1.454 g/cm 3 , R 1 = 0.0419 (CIF file CCDC no. 1827162).
KW - chromium(III)
KW - double complex salt
KW - europium(III)
KW - polymorphism
KW - X-ray diffraction
KW - ε-caprolactam
KW - epsilon-caprolactam
UR - http://www.scopus.com/inward/record.url?scp=85064564789&partnerID=8YFLogxK
U2 - 10.1134/S1070328419010123
DO - 10.1134/S1070328419010123
M3 - Article
AN - SCOPUS:85064564789
VL - 45
SP - 42
EP - 46
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 1
ER -
ID: 19630796