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Polymeric Solids Based on [Re12CS14(μ-O)3(OH)6]6− Cluster and Alkaline Earth Metal Cations. / Gayfulin, Y. M.; Smolentsev, A. I.; Mironov, Y. V.

In: Journal of Cluster Science, Vol. 29, No. 4, 01.07.2018, p. 617-624.

Research output: Contribution to journal › Article › peer-review

Harvard

Gayfulin, YM, Smolentsev, AI & Mironov, YV 2018, 'Polymeric Solids Based on [Re12CS14(μ-O)3(OH)6]6− Cluster and Alkaline Earth Metal Cations', Journal of Cluster Science, vol. 29, no. 4, pp. 617-624. https://doi.org/10.1007/s10876-018-1374-6

APA

Gayfulin, Y. M., Smolentsev, A. I., & Mironov, Y. V. (2018). Polymeric Solids Based on [Re12CS14(μ-O)3(OH)6]6− Cluster and Alkaline Earth Metal Cations. Journal of Cluster Science, 29(4), 617-624. https://doi.org/10.1007/s10876-018-1374-6

Vancouver

Gayfulin YM, Smolentsev AI, Mironov YV. Polymeric Solids Based on [Re12CS14(μ-O)3(OH)6]6− Cluster and Alkaline Earth Metal Cations. Journal of Cluster Science. 2018 Jul 1;29(4):617-624. doi: 10.1007/s10876-018-1374-6

Author

Gayfulin, Y. M. ; Smolentsev, A. I. ; Mironov, Y. V. / Polymeric Solids Based on [Re12CS14(μ-O)3(OH)6]6− Cluster and Alkaline Earth Metal Cations. In: Journal of Cluster Science. 2018 ; Vol. 29, No. 4. pp. 617-624.

BibTeX

@article{80fba6757972410faec849ec827c8017,
title = "Polymeric Solids Based on [Re12CS14(μ-O)3(OH)6]6− Cluster and Alkaline Earth Metal Cations",
abstract = "The first study of the coordination ability of the [Re12CS14(μ-O)3(OH)6]6− cluster anion was carried out using the cations of alkaline earth metals. Three new compounds displaying supramolecular structures were obtained based on Ca2+, Sr2+ and Ba2+ cations. Compounds K4[M(H2O)7][Re12CS14(μ-O)3(OH)6]·15H2O (M = Ca (1), Sr (2)) demonstrate the structures where disordered Ca2+ or Sr2+ aqua complexes, K+ ions and H2O molecules are stabilized in the channels of anionic sub-lattice formed by cluster anions. Very short hydrogen bonds between the terminal OH− ligands of the cluster anions are observed in these structures. Unlike Ca2+ and Sr2+, the Ba2+ cations are coordinated to the terminal OH-groups as well as to the μ-O2− ligands of the cluster anion forming layered polymeric structure of compound [{Ba(H2O)4}{Ba(H2O)5}2{Re12CS14(μ-O)3(OH)6}]·9H2O (3).",
keywords = "Alkaline earth metal, Coordination polymer, Crystal structure, Rhenium cluster, DESIGN, HYDROGEN-BOND, STABILITY, COMPLEXES, COORDINATION, SUBSTITUTION-REACTIONS, CHEMISTRY, RHENIUM CLUSTERS, ORGANIC FRAMEWORKS, UNITS",
author = "Gayfulin, {Y. M.} and Smolentsev, {A. I.} and Mironov, {Y. V.}",
year = "2018",
month = jul,
day = "1",
doi = "10.1007/s10876-018-1374-6",
language = "English",
volume = "29",
pages = "617--624",
journal = "Journal of Cluster Science",
issn = "1040-7278",
publisher = "Springer New York",
number = "4",

}

RIS

TY - JOUR

T1 - Polymeric Solids Based on [Re12CS14(μ-O)3(OH)6]6− Cluster and Alkaline Earth Metal Cations

AU - Gayfulin, Y. M.

AU - Smolentsev, A. I.

AU - Mironov, Y. V.

PY - 2018/7/1

Y1 - 2018/7/1

N2 - The first study of the coordination ability of the [Re12CS14(μ-O)3(OH)6]6− cluster anion was carried out using the cations of alkaline earth metals. Three new compounds displaying supramolecular structures were obtained based on Ca2+, Sr2+ and Ba2+ cations. Compounds K4[M(H2O)7][Re12CS14(μ-O)3(OH)6]·15H2O (M = Ca (1), Sr (2)) demonstrate the structures where disordered Ca2+ or Sr2+ aqua complexes, K+ ions and H2O molecules are stabilized in the channels of anionic sub-lattice formed by cluster anions. Very short hydrogen bonds between the terminal OH− ligands of the cluster anions are observed in these structures. Unlike Ca2+ and Sr2+, the Ba2+ cations are coordinated to the terminal OH-groups as well as to the μ-O2− ligands of the cluster anion forming layered polymeric structure of compound [{Ba(H2O)4}{Ba(H2O)5}2{Re12CS14(μ-O)3(OH)6}]·9H2O (3).

AB - The first study of the coordination ability of the [Re12CS14(μ-O)3(OH)6]6− cluster anion was carried out using the cations of alkaline earth metals. Three new compounds displaying supramolecular structures were obtained based on Ca2+, Sr2+ and Ba2+ cations. Compounds K4[M(H2O)7][Re12CS14(μ-O)3(OH)6]·15H2O (M = Ca (1), Sr (2)) demonstrate the structures where disordered Ca2+ or Sr2+ aqua complexes, K+ ions and H2O molecules are stabilized in the channels of anionic sub-lattice formed by cluster anions. Very short hydrogen bonds between the terminal OH− ligands of the cluster anions are observed in these structures. Unlike Ca2+ and Sr2+, the Ba2+ cations are coordinated to the terminal OH-groups as well as to the μ-O2− ligands of the cluster anion forming layered polymeric structure of compound [{Ba(H2O)4}{Ba(H2O)5}2{Re12CS14(μ-O)3(OH)6}]·9H2O (3).

KW - Alkaline earth metal

KW - Coordination polymer

KW - Crystal structure

KW - Rhenium cluster

KW - DESIGN

KW - HYDROGEN-BOND

KW - STABILITY

KW - COMPLEXES

KW - COORDINATION

KW - SUBSTITUTION-REACTIONS

KW - CHEMISTRY

KW - RHENIUM CLUSTERS

KW - ORGANIC FRAMEWORKS

KW - UNITS

UR - http://www.scopus.com/inward/record.url?scp=85045834828&partnerID=8YFLogxK

U2 - 10.1007/s10876-018-1374-6

DO - 10.1007/s10876-018-1374-6

M3 - Article

AN - SCOPUS:85045834828

VL - 29

SP - 617

EP - 624

JO - Journal of Cluster Science

JF - Journal of Cluster Science

SN - 1040-7278

IS - 4

ER -

ID: 12799108