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Polymeric Copper Oxide : Preparation and Investigation of Its Structure and Optical Properties. / Prosanov, I. Y.; Benassi, E.; Bulina, N. V. et al.

In: Journal of Inorganic and Organometallic Polymers and Materials, Vol. 28, No. 6, 01.11.2018, p. 2328-2335.

Research output: Contribution to journal › Article › peer-review

Harvard

Prosanov, IY, Benassi, E, Bulina, NV, Matvienko, AA, Gerasimov, KB & Sidelnikov, AA 2018, 'Polymeric Copper Oxide: Preparation and Investigation of Its Structure and Optical Properties', Journal of Inorganic and Organometallic Polymers and Materials, vol. 28, no. 6, pp. 2328-2335. https://doi.org/10.1007/s10904-018-0897-5

APA

Prosanov, I. Y., Benassi, E., Bulina, N. V., Matvienko, A. A., Gerasimov, K. B., & Sidelnikov, A. A. (2018). Polymeric Copper Oxide: Preparation and Investigation of Its Structure and Optical Properties. Journal of Inorganic and Organometallic Polymers and Materials, 28(6), 2328-2335. https://doi.org/10.1007/s10904-018-0897-5

Vancouver

Prosanov IY, Benassi E, Bulina NV, Matvienko AA, Gerasimov KB, Sidelnikov AA. Polymeric Copper Oxide: Preparation and Investigation of Its Structure and Optical Properties. Journal of Inorganic and Organometallic Polymers and Materials. 2018 Nov 1;28(6):2328-2335. doi: 10.1007/s10904-018-0897-5

Author

Prosanov, I. Y. ; Benassi, E. ; Bulina, N. V. et al. / Polymeric Copper Oxide : Preparation and Investigation of Its Structure and Optical Properties. In: Journal of Inorganic and Organometallic Polymers and Materials. 2018 ; Vol. 28, No. 6. pp. 2328-2335.

BibTeX

@article{cd0cae74d7b944bf937f624183d14f04,
title = "Polymeric Copper Oxide: Preparation and Investigation of Its Structure and Optical Properties",
abstract = "A complex of polyvinyl alcohol (PVA) with copper hydroxide was used as a precursor to obtain polymeric copper oxide through thermal decomposition. The absence of Cu(OH)2 crystalline phase was observed for the component ratio up to 1 Cu(OH)2 molecular unit to 3 PVA residuals. The formation of crystalline copper oxide was not observed after the dehydration of this material. UV–VIS and IR spectroscopy, and computational modeling were used to study the structure and properties of the obtained materials. A comparison with other similar materials was drawn. It was found that experimental data are in general accordance with the computations based on the polymeric model for copper hydroxide/oxide as a component of hybrid interpolymeric complex with PVA. A distinctive feature observed for polymeric copper oxide is strong broadening of the optical absorption band at 400 nm. It is suggested that this effect is caused by strong electron–phonon interaction, which is also responsible for superconductivity of copper oxide based systems.",
keywords = "CuO, Hybrid interpolymeric complexes, Hybrid materials, Inorganic polymers, Low-dimensional structures, TOTAL ENERGIES, MOLECULAR-ORBITAL METHODS, COMPLEXES, GAUSSIAN-TYPE BASIS, DENSITY, 3RD-ROW ATOMS, SET MODEL CHEMISTRY, POLYVINYL-ALCOHOL, SYSTEMS, CU(OH)(2)",
author = "Prosanov, {I. Y.} and E. Benassi and Bulina, {N. V.} and Matvienko, {A. A.} and Gerasimov, {K. B.} and Sidelnikov, {A. A.}",
year = "2018",
month = nov,
day = "1",
doi = "10.1007/s10904-018-0897-5",
language = "English",
volume = "28",
pages = "2328--2335",
journal = "Journal of Inorganic and Organometallic Polymers and Materials",
issn = "1574-1443",
publisher = "Springer New York",
number = "6",

}

RIS

TY - JOUR

T1 - Polymeric Copper Oxide

T2 - Preparation and Investigation of Its Structure and Optical Properties

AU - Prosanov, I. Y.

AU - Benassi, E.

AU - Bulina, N. V.

AU - Matvienko, A. A.

AU - Gerasimov, K. B.

AU - Sidelnikov, A. A.

PY - 2018/11/1

Y1 - 2018/11/1

N2 - A complex of polyvinyl alcohol (PVA) with copper hydroxide was used as a precursor to obtain polymeric copper oxide through thermal decomposition. The absence of Cu(OH)2 crystalline phase was observed for the component ratio up to 1 Cu(OH)2 molecular unit to 3 PVA residuals. The formation of crystalline copper oxide was not observed after the dehydration of this material. UV–VIS and IR spectroscopy, and computational modeling were used to study the structure and properties of the obtained materials. A comparison with other similar materials was drawn. It was found that experimental data are in general accordance with the computations based on the polymeric model for copper hydroxide/oxide as a component of hybrid interpolymeric complex with PVA. A distinctive feature observed for polymeric copper oxide is strong broadening of the optical absorption band at 400 nm. It is suggested that this effect is caused by strong electron–phonon interaction, which is also responsible for superconductivity of copper oxide based systems.

AB - A complex of polyvinyl alcohol (PVA) with copper hydroxide was used as a precursor to obtain polymeric copper oxide through thermal decomposition. The absence of Cu(OH)2 crystalline phase was observed for the component ratio up to 1 Cu(OH)2 molecular unit to 3 PVA residuals. The formation of crystalline copper oxide was not observed after the dehydration of this material. UV–VIS and IR spectroscopy, and computational modeling were used to study the structure and properties of the obtained materials. A comparison with other similar materials was drawn. It was found that experimental data are in general accordance with the computations based on the polymeric model for copper hydroxide/oxide as a component of hybrid interpolymeric complex with PVA. A distinctive feature observed for polymeric copper oxide is strong broadening of the optical absorption band at 400 nm. It is suggested that this effect is caused by strong electron–phonon interaction, which is also responsible for superconductivity of copper oxide based systems.

KW - CuO

KW - Hybrid interpolymeric complexes

KW - Hybrid materials

KW - Inorganic polymers

KW - Low-dimensional structures

KW - TOTAL ENERGIES

KW - MOLECULAR-ORBITAL METHODS

KW - COMPLEXES

KW - GAUSSIAN-TYPE BASIS

KW - DENSITY

KW - 3RD-ROW ATOMS

KW - SET MODEL CHEMISTRY

KW - POLYVINYL-ALCOHOL

KW - SYSTEMS

KW - CU(OH)(2)

UR - http://www.scopus.com/inward/record.url?scp=85048563518&partnerID=8YFLogxK

U2 - 10.1007/s10904-018-0897-5

DO - 10.1007/s10904-018-0897-5

M3 - Article

AN - SCOPUS:85048563518

VL - 28

SP - 2328

EP - 2335

JO - Journal of Inorganic and Organometallic Polymers and Materials

JF - Journal of Inorganic and Organometallic Polymers and Materials

SN - 1574-1443

IS - 6

ER -

ID: 14047989