Research output: Contribution to journal › Article › peer-review
Polyfluorinated tetraoxacalixarenes and bicyclooxacalixarenes. Interaction of pentafluorobenzonitrile with resorcinol, orcinol and tetrafluororesorcinol. / Kovtonyuk, Vladimir N.; Gatilov, Yuri V.; Salnikov, Georgi E. et al.
In: Journal of Fluorine Chemistry, Vol. 222-223, 01.06.2019, p. 59-67.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Polyfluorinated tetraoxacalixarenes and bicyclooxacalixarenes. Interaction of pentafluorobenzonitrile with resorcinol, orcinol and tetrafluororesorcinol
AU - Kovtonyuk, Vladimir N.
AU - Gatilov, Yuri V.
AU - Salnikov, Georgi E.
AU - Amosov, Evgeni V.
PY - 2019/6/1
Y1 - 2019/6/1
N2 - Successive interaction of pentafluorobenzonitrile with resorcinol, orcinol and tetrafluororesorcinol in Et 3 N−CH 3 CN system gives fluorinated tetraoxacalix[4]arenes ABAB and ABAC type in a good yield. Further reaction of obtained products with new additional equivalent of tetrafluororesorcinol or orcinol leads to the formation of the fluorine-containing bicyclooxacalixarenes. The ESI-MS method shows the possibility of fluorinated tetraoxacalixarenes and bicyclooxacalixarenes complexes formation with metal cations.
AB - Successive interaction of pentafluorobenzonitrile with resorcinol, orcinol and tetrafluororesorcinol in Et 3 N−CH 3 CN system gives fluorinated tetraoxacalix[4]arenes ABAB and ABAC type in a good yield. Further reaction of obtained products with new additional equivalent of tetrafluororesorcinol or orcinol leads to the formation of the fluorine-containing bicyclooxacalixarenes. The ESI-MS method shows the possibility of fluorinated tetraoxacalixarenes and bicyclooxacalixarenes complexes formation with metal cations.
KW - Bicyclooxacalixarenes
KW - Pentafluorobenzonitrile
KW - Polyfluorinated oxacalixarenes
KW - Resorcinol
KW - Tetrafluororesorcinol
KW - X-ray diffraction
KW - CAGE
KW - RECOGNITION
KW - VESICLES
KW - 1,3-ALTERNATE
KW - MACROCYCLES
KW - CAVITY
KW - ADSORPTION
KW - GUESTS
KW - ANION-PI INTERACTIONS
KW - ASSEMBLIES
UR - http://www.scopus.com/inward/record.url?scp=85064903806&partnerID=8YFLogxK
U2 - 10.1016/j.jfluchem.2019.04.011
DO - 10.1016/j.jfluchem.2019.04.011
M3 - Article
AN - SCOPUS:85064903806
VL - 222-223
SP - 59
EP - 67
JO - Journal of Fluorine Chemistry
JF - Journal of Fluorine Chemistry
SN - 0022-1139
ER -
ID: 20042982