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Polyfluorinated oxacalixarenes. Interaction of perfluoro-m-xylene with resorcinol and tetrafluororesorcinol. / Kovtonyuk, Vladimir N.; Gatilov, Yuri V.

In: Journal of Fluorine Chemistry, Vol. 199, 01.07.2017, p. 52-59.

Research output: Contribution to journal › Article › peer-review

Harvard

Kovtonyuk, VN & Gatilov, YV 2017, 'Polyfluorinated oxacalixarenes. Interaction of perfluoro-m-xylene with resorcinol and tetrafluororesorcinol', Journal of Fluorine Chemistry, vol. 199, pp. 52-59. https://doi.org/10.1016/j.jfluchem.2017.04.010

APA

Kovtonyuk, V. N., & Gatilov, Y. V. (2017). Polyfluorinated oxacalixarenes. Interaction of perfluoro-m-xylene with resorcinol and tetrafluororesorcinol. Journal of Fluorine Chemistry, 199, 52-59. https://doi.org/10.1016/j.jfluchem.2017.04.010

Vancouver

Kovtonyuk VN, Gatilov YV. Polyfluorinated oxacalixarenes. Interaction of perfluoro-m-xylene with resorcinol and tetrafluororesorcinol. Journal of Fluorine Chemistry. 2017 Jul 1;199:52-59. doi: 10.1016/j.jfluchem.2017.04.010

Author

Kovtonyuk, Vladimir N. ; Gatilov, Yuri V. / Polyfluorinated oxacalixarenes. Interaction of perfluoro-m-xylene with resorcinol and tetrafluororesorcinol. In: Journal of Fluorine Chemistry. 2017 ; Vol. 199. pp. 52-59.

BibTeX

@article{8a5a70a838ec46249a1c4a0aecd27c96,
title = "Polyfluorinated oxacalixarenes. Interaction of perfluoro-m-xylene with resorcinol and tetrafluororesorcinol",
abstract = "Interaction of perfluoro-m-xylene with tetrafluororesorcinol in Et3N-CH3CN system leads to the formation of perfluorinated tetramethyltetraoxacalix[4]arene with a good yield, while the reaction with resorcinol gives a mixture of macrocycles containing 4, 6 or 8 aromatic rings. The intermediate products in these reactions are perfluoro-3-(2,4-dimethylphenoxy)phenol and 1,3-bis(2,4-bistrifluoromethyltrifluorophenoxy)benzene, respectively. The interaction of the latter with tetrafluororesorcinol leads to the formation of tetraoxacalix[4]arene of ABAC type with a good yield.",
keywords = "Macrocycles, Perfluoro-m-xylene, Polyfluorinated oxacalixarenes, Resorcinol, Tetrafluororesorcinol, X-ray diffraction",
author = "Kovtonyuk, {Vladimir N.} and Gatilov, {Yuri V.}",
year = "2017",
month = jul,
day = "1",
doi = "10.1016/j.jfluchem.2017.04.010",
language = "English",
volume = "199",
pages = "52--59",
journal = "Journal of Fluorine Chemistry",
issn = "0022-1139",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Polyfluorinated oxacalixarenes. Interaction of perfluoro-m-xylene with resorcinol and tetrafluororesorcinol

AU - Kovtonyuk, Vladimir N.

AU - Gatilov, Yuri V.

PY - 2017/7/1

Y1 - 2017/7/1

N2 - Interaction of perfluoro-m-xylene with tetrafluororesorcinol in Et3N-CH3CN system leads to the formation of perfluorinated tetramethyltetraoxacalix[4]arene with a good yield, while the reaction with resorcinol gives a mixture of macrocycles containing 4, 6 or 8 aromatic rings. The intermediate products in these reactions are perfluoro-3-(2,4-dimethylphenoxy)phenol and 1,3-bis(2,4-bistrifluoromethyltrifluorophenoxy)benzene, respectively. The interaction of the latter with tetrafluororesorcinol leads to the formation of tetraoxacalix[4]arene of ABAC type with a good yield.

AB - Interaction of perfluoro-m-xylene with tetrafluororesorcinol in Et3N-CH3CN system leads to the formation of perfluorinated tetramethyltetraoxacalix[4]arene with a good yield, while the reaction with resorcinol gives a mixture of macrocycles containing 4, 6 or 8 aromatic rings. The intermediate products in these reactions are perfluoro-3-(2,4-dimethylphenoxy)phenol and 1,3-bis(2,4-bistrifluoromethyltrifluorophenoxy)benzene, respectively. The interaction of the latter with tetrafluororesorcinol leads to the formation of tetraoxacalix[4]arene of ABAC type with a good yield.

KW - Macrocycles

KW - Perfluoro-m-xylene

KW - Polyfluorinated oxacalixarenes

KW - Resorcinol

KW - Tetrafluororesorcinol

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=85019157812&partnerID=8YFLogxK

U2 - 10.1016/j.jfluchem.2017.04.010

DO - 10.1016/j.jfluchem.2017.04.010

M3 - Article

AN - SCOPUS:85019157812

VL - 199

SP - 52

EP - 59

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

SN - 0022-1139

ER -

ID: 9976874