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PO23- and AsO3- : Pnictogenide Ligands in the Highly Charged Re4 Cluster Anions [{Re4(PO)3(PO2)}(CN)12]8-, [{Re4As2(AsO)2}(CN)12]8-, and [{Re4(AsO)4}(CN)12]8-. / Pronin, Aleksei S.; Smolentsev, Anton I.; Kozlova, Svetlana G. et al.

In: Inorganic Chemistry, Vol. 58, No. 11, 03.06.2019, p. 7368-7373.

Research output: Contribution to journal › Article › peer-review

Harvard

Pronin, AS, Smolentsev, AI, Kozlova, SG, Novozhilov, IN & Mironov, YV 2019, 'PO23- and AsO3-: Pnictogenide Ligands in the Highly Charged Re4 Cluster Anions [{Re4(PO)3(PO2)}(CN)12]8-, [{Re4As2(AsO)2}(CN)12]8-, and [{Re4(AsO)4}(CN)12]8-', Inorganic Chemistry, vol. 58, no. 11, pp. 7368-7373. https://doi.org/10.1021/acs.inorgchem.9b00520

APA

Pronin, A. S., Smolentsev, A. I., Kozlova, S. G., Novozhilov, I. N., & Mironov, Y. V. (2019). PO23- and AsO3-: Pnictogenide Ligands in the Highly Charged Re4 Cluster Anions [{Re4(PO)3(PO2)}(CN)12]8-, [{Re4As2(AsO)2}(CN)12]8-, and [{Re4(AsO)4}(CN)12]8-. Inorganic Chemistry, 58(11), 7368-7373. https://doi.org/10.1021/acs.inorgchem.9b00520

Vancouver

Pronin AS, Smolentsev AI, Kozlova SG, Novozhilov IN, Mironov YV. PO23- and AsO3-: Pnictogenide Ligands in the Highly Charged Re4 Cluster Anions [{Re4(PO)3(PO2)}(CN)12]8-, [{Re4As2(AsO)2}(CN)12]8-, and [{Re4(AsO)4}(CN)12]8-. Inorganic Chemistry. 2019 Jun 3;58(11):7368-7373. doi: 10.1021/acs.inorgchem.9b00520

Author

Pronin, Aleksei S. ; Smolentsev, Anton I. ; Kozlova, Svetlana G. et al. / PO23- and AsO3- : Pnictogenide Ligands in the Highly Charged Re4 Cluster Anions [{Re4(PO)3(PO2)}(CN)12]8-, [{Re4As2(AsO)2}(CN)12]8-, and [{Re4(AsO)4}(CN)12]8-. In: Inorganic Chemistry. 2019 ; Vol. 58, No. 11. pp. 7368-7373.

BibTeX

@article{aa5664b60f2d430880ad991e29bc5b5b,
title = "PO23- and AsO3-: Pnictogenide Ligands in the Highly Charged Re4 Cluster Anions [{Re4(PO)3(PO2)}(CN)12]8-, [{Re4As2(AsO)2}(CN)12]8-, and [{Re4(AsO)4}(CN)12]8-",
abstract = "New tetrahedral anionic rhenium cluster complexes [{Re4(PO)3(PO2)}(CN)12]8- (1) and [{Re4As2(AsO)2}(CN)12]8- (2) have been synthesized by the reaction of ReI3 with NaCN and Pred or KCN and Asgray, respectively. Compound 2 was further oxidized by aqueous H2O2 to produce the cluster anion [{Re4(AsO)4}(CN)12]8- (3). The anions contain new pnictogen/oxygen-based ligands, PO23- and AsO3-, which were stabilized by the coordination to the triangular faces of the tetrahedral Re4 metallocluster in μ3-mode. All three compounds were crystallized as either sodium or potassium salts, and their crystal structures were determined by single crystal X-ray diffraction analysis.",
keywords = "RHENIUM CLUSTER, CRYSTAL-STRUCTURE, SE, COMPLEXES, TE, MOLYBDENUM, FACILE",
author = "Pronin, {Aleksei S.} and Smolentsev, {Anton I.} and Kozlova, {Svetlana G.} and Novozhilov, {Igor N.} and Mironov, {Yuri V.}",
year = "2019",
month = jun,
day = "3",
doi = "10.1021/acs.inorgchem.9b00520",
language = "English",
volume = "58",
pages = "7368--7373",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "11",

}

RIS

TY - JOUR

T1 - PO23- and AsO3-

T2 - Pnictogenide Ligands in the Highly Charged Re4 Cluster Anions [{Re4(PO)3(PO2)}(CN)12]8-, [{Re4As2(AsO)2}(CN)12]8-, and [{Re4(AsO)4}(CN)12]8-

AU - Pronin, Aleksei S.

AU - Smolentsev, Anton I.

AU - Kozlova, Svetlana G.

AU - Novozhilov, Igor N.

AU - Mironov, Yuri V.

PY - 2019/6/3

Y1 - 2019/6/3

N2 - New tetrahedral anionic rhenium cluster complexes [{Re4(PO)3(PO2)}(CN)12]8- (1) and [{Re4As2(AsO)2}(CN)12]8- (2) have been synthesized by the reaction of ReI3 with NaCN and Pred or KCN and Asgray, respectively. Compound 2 was further oxidized by aqueous H2O2 to produce the cluster anion [{Re4(AsO)4}(CN)12]8- (3). The anions contain new pnictogen/oxygen-based ligands, PO23- and AsO3-, which were stabilized by the coordination to the triangular faces of the tetrahedral Re4 metallocluster in μ3-mode. All three compounds were crystallized as either sodium or potassium salts, and their crystal structures were determined by single crystal X-ray diffraction analysis.

AB - New tetrahedral anionic rhenium cluster complexes [{Re4(PO)3(PO2)}(CN)12]8- (1) and [{Re4As2(AsO)2}(CN)12]8- (2) have been synthesized by the reaction of ReI3 with NaCN and Pred or KCN and Asgray, respectively. Compound 2 was further oxidized by aqueous H2O2 to produce the cluster anion [{Re4(AsO)4}(CN)12]8- (3). The anions contain new pnictogen/oxygen-based ligands, PO23- and AsO3-, which were stabilized by the coordination to the triangular faces of the tetrahedral Re4 metallocluster in μ3-mode. All three compounds were crystallized as either sodium or potassium salts, and their crystal structures were determined by single crystal X-ray diffraction analysis.

KW - RHENIUM CLUSTER

KW - CRYSTAL-STRUCTURE

KW - SE

KW - COMPLEXES

KW - TE

KW - MOLYBDENUM

KW - FACILE

UR - http://www.scopus.com/inward/record.url?scp=85066122357&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.9b00520

DO - 10.1021/acs.inorgchem.9b00520

M3 - Article

C2 - 31094204

AN - SCOPUS:85066122357

VL - 58

SP - 7368

EP - 7373

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 11

ER -

ID: 20341862