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Photochromism in oxalatoniobates. / Shmakova, Alexandra A.; Glebov, Eugeniy M.; Korolev, Valeri V. et al.

In: Dalton Transactions, Vol. 47, No. 7, 21.02.2018, p. 2247-2255.

Research output: Contribution to journal › Article › peer-review

Harvard

Shmakova, AA, Glebov, EM, Korolev, VV, Stass, DV, Benassi, E, Abramov, PA & Sokolov, MN 2018, 'Photochromism in oxalatoniobates', Dalton Transactions, vol. 47, no. 7, pp. 2247-2255. https://doi.org/10.1039/c7dt04077f

APA

Shmakova, A. A., Glebov, E. M., Korolev, V. V., Stass, D. V., Benassi, E., Abramov, P. A., & Sokolov, M. N. (2018). Photochromism in oxalatoniobates. Dalton Transactions, 47(7), 2247-2255. https://doi.org/10.1039/c7dt04077f

Vancouver

Shmakova AA, Glebov EM, Korolev VV, Stass DV, Benassi E, Abramov PA et al. Photochromism in oxalatoniobates. Dalton Transactions. 2018 Feb 21;47(7):2247-2255. doi: 10.1039/c7dt04077f

Author

Shmakova, Alexandra A. ; Glebov, Eugeniy M. ; Korolev, Valeri V. et al. / Photochromism in oxalatoniobates. In: Dalton Transactions. 2018 ; Vol. 47, No. 7. pp. 2247-2255.

BibTeX

@article{4d1c34dc359747f8b801d9b8e4ad80da,
title = "Photochromism in oxalatoniobates",
abstract = "Addition of 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen) or 2-aminopyridine (2-NH2-py) to aqueous solutions of (NH4)[NbO(C2O4)2(H2O)2]·3H2O (Nb-Ox) yields tris-oxalate complexes (bpyH2)(bpyH)[NbO(C2O4)3]·2H2O (1), (phenH)3[NbO(C2O4)3]·3H2O (2), and (2-NH2-pyH)3[NbO(C2O4)3]·2H2O (3), which were characterised by XRD, IR and EA. Bipyridinium salt 1 demonstrates remarkable photoactivity even under irradiation by daylight. The nature of the photoactivity was studied by diffuse reflectance (DR) spectroscopy, ESR and quantum-chemical calculations.",
keywords = "EFFECTIVE CORE POTENTIALS, CRYSTAL-STRUCTURE, MOLECULAR CALCULATIONS, NIOBIUM OXIDE, PHOTOCHEMISTRY, OXALATE, CHEMISTRY, KINETICS, NB2O5, 4,4'-BIPYRIDINE",
author = "Shmakova, {Alexandra A.} and Glebov, {Eugeniy M.} and Korolev, {Valeri V.} and Stass, {Dmitri V.} and Enrico Benassi and Abramov, {Pavel A.} and Sokolov, {Maxim N.}",
note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",
year = "2018",
month = feb,
day = "21",
doi = "10.1039/c7dt04077f",
language = "English",
volume = "47",
pages = "2247--2255",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "7",

}

RIS

TY - JOUR

T1 - Photochromism in oxalatoniobates

AU - Shmakova, Alexandra A.

AU - Glebov, Eugeniy M.

AU - Korolev, Valeri V.

AU - Stass, Dmitri V.

AU - Benassi, Enrico

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

N1 - Publisher Copyright: © 2018 The Royal Society of Chemistry.

PY - 2018/2/21

Y1 - 2018/2/21

N2 - Addition of 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen) or 2-aminopyridine (2-NH2-py) to aqueous solutions of (NH4)[NbO(C2O4)2(H2O)2]·3H2O (Nb-Ox) yields tris-oxalate complexes (bpyH2)(bpyH)[NbO(C2O4)3]·2H2O (1), (phenH)3[NbO(C2O4)3]·3H2O (2), and (2-NH2-pyH)3[NbO(C2O4)3]·2H2O (3), which were characterised by XRD, IR and EA. Bipyridinium salt 1 demonstrates remarkable photoactivity even under irradiation by daylight. The nature of the photoactivity was studied by diffuse reflectance (DR) spectroscopy, ESR and quantum-chemical calculations.

AB - Addition of 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen) or 2-aminopyridine (2-NH2-py) to aqueous solutions of (NH4)[NbO(C2O4)2(H2O)2]·3H2O (Nb-Ox) yields tris-oxalate complexes (bpyH2)(bpyH)[NbO(C2O4)3]·2H2O (1), (phenH)3[NbO(C2O4)3]·3H2O (2), and (2-NH2-pyH)3[NbO(C2O4)3]·2H2O (3), which were characterised by XRD, IR and EA. Bipyridinium salt 1 demonstrates remarkable photoactivity even under irradiation by daylight. The nature of the photoactivity was studied by diffuse reflectance (DR) spectroscopy, ESR and quantum-chemical calculations.

KW - EFFECTIVE CORE POTENTIALS

KW - CRYSTAL-STRUCTURE

KW - MOLECULAR CALCULATIONS

KW - NIOBIUM OXIDE

KW - PHOTOCHEMISTRY

KW - OXALATE

KW - CHEMISTRY

KW - KINETICS

KW - NB2O5

KW - 4,4'-BIPYRIDINE

UR - http://www.scopus.com/inward/record.url?scp=85042103181&partnerID=8YFLogxK

U2 - 10.1039/c7dt04077f

DO - 10.1039/c7dt04077f

M3 - Article

C2 - 29363691

AN - SCOPUS:85042103181

VL - 47

SP - 2247

EP - 2255

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 7

ER -

ID: 10420032